1 Guangdong Key Laboratory for Advanced Metallic Materials Processing, South China University of Technology, Guangzhou 510640, Guangdong, China 2 College of Engineering and Technology, Normal College of Zunyi, Zunyi 563006, Guizhou, China 3 Mechanical and Electrical Engineering College, Hainan University, Haikou 570228, Hainan, China
Corrosion behavior of a spark plasma sintered Fe�C20Mn�C11Al�C1.8C�C5Cr alloy in molten aluminum
1 Guangdong Key Laboratory for Advanced Metallic Materials Processing, South China University of Technology, Guangzhou 510640, Guangdong, China 2 College of Engineering and Technology, Normal College of Zunyi, Zunyi 563006, Guizhou, China 3 Mechanical and Electrical Engineering College, Hainan University, Haikou 570228, Hainan, China
ժҪ The corrosion behavior of an Fe�C20Mn�C11Al�C1.8C�C5Cr alloy prepared by spark plasma sintering was investigated via immersion tests in molten aluminum at 750 ��C for 1 and 4 h, respectively, and a hot work steel (AISI H13) was included as a reference. The experimental results show that the corrosion rate of Fe�C20Mn�C11Al�C1.8C�C5Cr alloy is ~ 24% of that of H13 steel, suggesting that Fe�C20Mn�C11Al�C1.8C�C5Cr alloy in molten aluminum possesses better corrosion resistance than H13 steel. Detailed analysis show that j-carbide ((Fe, Mn)3AlCx) and Cr7C3 carbide precipitated in the matrix play a key role in enhancing the corrosion resistance of Fe�C20Mn�C11Al�C1.8C�C5Cr alloy in molten aluminum. Both of them show better corrosion resistance than c-Fe matrix and H13 steel, and can also take on the role of roots in grasping the corrosion product and restrain them from spalling into the molten aluminum.
Abstract��The corrosion behavior of an Fe�C20Mn�C11Al�C1.8C�C5Cr alloy prepared by spark plasma sintering was investigated via immersion tests in molten aluminum at 750 ��C for 1 and 4 h, respectively, and a hot work steel (AISI H13) was included as a reference. The experimental results show that the corrosion rate of Fe�C20Mn�C11Al�C1.8C�C5Cr alloy is ~ 24% of that of H13 steel, suggesting that Fe�C20Mn�C11Al�C1.8C�C5Cr alloy in molten aluminum possesses better corrosion resistance than H13 steel. Detailed analysis show that j-carbide ((Fe, Mn)3AlCx) and Cr7C3 carbide precipitated in the matrix play a key role in enhancing the corrosion resistance of Fe�C20Mn�C11Al�C1.8C�C5Cr alloy in molten aluminum. Both of them show better corrosion resistance than c-Fe matrix and H13 steel, and can also take on the role of roots in grasping the corrosion product and restrain them from spalling into the molten aluminum.
Yan M, Fan Z.Review Durability of materials in molten aluminum alloys[J].Journal of Materials Science, 2001, 36(2):285-295
[2]
Cheng W, Wang C.Study of microstructure and phase evolution of hot-dipped aluminide mild steel during high-temperature diffusion using electron backscatter diffraction[J].Applied Surface Science, 2011, 257(10):4663-4668
[3]
Bouch�� K, Barbier F, Coulet A.Intermetallic compound layer growth between solid iron and molten aluminium[J].Materials Science & Engineering A, 1998, 249(1-2):167-175
[4]
Bouayad A, Gerometta C, Belkebir A, et al.Kinetic interactions between solid iron and molten aluminium[J].Materials Science & Engineering A, 2003, 363(1-2):53-61
[5]
Balloy D, Tissier J C, Giorgi M L, et al.Corrosion Mechanisms of Steel and Cast Iron by Molten Aluminum[J].Metallurgical and Materials Transactions A, 2010, 41(9):2336-2376
[6]
Morris D G, Mu?oz-Morris M A, Requejo L M.New iron�Caluminium alloy with thermally stable coherent intermetallic nanoprecipitates for enhanced high-temperature creep strength[J].Acta Materialia, 2006, 54(9):2335-2341
[7]
Tsay G D, Lin C L, Chao C G, et al.A New Austenitic FeMnAlCrC Alloy with High-Strength, High-Ductility, and Moderate Corrosion Resistance[J].Materials Transactions, 2010, 51(12):2318-2321
[8]
Tuan Y H, Wang C S, Tsai C Y, et al.Corrosion behaviors of austenitic Fe�C30Mn�C7Al�C x Cr�C1C alloys in 3.5% NaCl solution[J]].Materials Chemistry & Physics, 2009, 114(2-3):595-598
[9]
Duh J G, Wang C J.High tempeature oxidation of Fe-31 Mn-9Al-xCr-0.87C alloys (x = 0, 3 and 6)[J].Journal of Materials Science, 1990, 25(1):268-276
[10]
Chong X Y, Jiang Y H, Zhou R, et al.Multialloying effect on thermophysical properties of Cr7C3�\type carbides[J].Journal of the American Ceramic Society. 2017, 100(4):1588-1597
[11]
Chin K G, Lee H J, Kwak J H, et al.Thermodynamic calculation on the stability of (Fe, Mn) 3 AlC carbide in high aluminum steels[J].Journal of Alloys & Compounds, 2010, 505(1):217-223
[12]
Liu J, Chen W, Jiang Z, et al.Microstructure and mechanical properties of an Fe-20Mn-11Al-1.8C-5Cr alloy prepared by powder metallurgy[J].Vacuum. 2017, 137(1):183-190
[13]
Li M C, Chang H, Kao P W, et al.The effect of Mn and Al contents on the solvus of �� phase in austenitic Fe-Mn-Al-C alloys[J].Materials Chemistry & Physics, 1999, 59(1):96-99
[14]
Zhang X, Chen W, Luo H, et al.Corrosion resistance and interfacial morphologies of novel Fe-Cr-Mo-B cast steels in molten aluminum[J].Corrosion Science, 2017, 125(15):20-28
[15]
Lou D C, Akselsen O M, Ons?ien M I, et al.Surface modification of steel and cast iron to improve corrosion resistance in molten aluminium[J].Surface & Coatings Technology, 2006, 100(18-19):5282-5288
[16]
Xu J, Bright M A, Liu X, et al.Liquid Metal Corrosion of 316L Stainless Steel, 410 Stainless Steel, and 1015 Carbon Steel in a Molten Zinc Bath[J].Metallurgical and Materials Transactions A, 2007, 38(11):2727-2736
[17]
Zhang Xianman, Research on the Corrosion-wear Resistance of the Novel Fe-Cr-B Cast Steels and Their Three-dimensional Interconnected ZrO2 Reinforced Metal Matrix Composites in Molten Aluminum, South China University of Technology, Guan g zhou,2015.
[18]
Wang D, Shi Z, Zou L.A liquid aluminum corrosion resistance surface on steel substrate[J]. Applied Surface Science., 2003, 214(1-4):304-311
[19]
Xiao H Q, Chen W P, Liu Z.Corrosion resistance of 91W�C6Ni�C3Fe refractory metal, TiAl compound and iron based alloys in molten aluminum[J].Transactions of Nonferrous Metals Society of China., 2012, 22(9):2320-2326
[20]
Su C W, Lee J W, Wang C S, et al.The effect of hot-dipped aluminum coatings on Fe-8Al-30Mn-0.8C alloy[J].Surface & Coatings Technology., 2008, 202(9):1847-1852
[21]
D. Conne��table,P. Maugis.First principle calculations of the k-Fe3AlC perovskite and ironealuminium intermetallics[J].Intermetallics 16 (2008) 345-352
[22]
Zhang W, Wen J B, Wang X F, et al.AlFe3C0.5 phase in diffusion layers of hot dip aluminized steel[J].Chinese Journal of Nonferrous Metals., 2007, 17(10):1632-1636
[23]
Akdeniz M V, Mekhrabov A O, Yilmaz T.The role of Si addition on the interfacial interaction in Fe-Al diffusion layer[J].Scripta Metallurgica Et Materialia., 1994, 31(12):1723-1728
[24]
Denner S G, Jones R D.Kinetic interactions between aluminiumland iron/steelfor conditions applicable to hot-dip aluminizing[J].Materials Science and Technology, 1977, 4(1):167-174
[25]
Cheng W J, Wang C J.Effect of chromium on the formation of intermetallic phases in hot-dipped aluminide Cr�CMo steels[J].Applied Surface Science., 2013, 277(8):139-145
[26]
Zhang X, Li X, Chen W.Interfacial reactions of duplex stainless steels with molten aluminum [J].Surface & Interface Analysis, 2015, 47(6):648-656
[27]
Akdeniz M V, Mekhrabov A O.The effect of substitutional impurities on the evolution of Fe-Al diffusion layer[J].Acta Materialia, 1998, 46(4):1185-1192