加压技术在高品质特殊钢冶炼和凝固中的作用

朱红春,姜周华,李花兵,张树才,冯 浩,刘福斌

钢铁 ›› 2015, Vol. 50 ›› Issue (11) : 37-44.

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钢铁 ›› 2015, Vol. 50 ›› Issue (11) : 37-44. DOI: 10.13228/j.boyuan.issn0449-749x.20150109
冶金工艺技术

加压技术在高品质特殊钢冶炼和凝固中的作用

  • 朱红春,姜周华,李花兵,张树才,冯 浩,刘福斌
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Effect of pressurization technology on steel-making and solidification of high-grade special steels

  • 朱红春,姜周华,李花兵,张树才,冯 浩,刘福斌
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摘要

加压技术在高品质特殊钢冶炼和凝固方面的研究主要集中在含氮不锈钢,尤其是高氮钢的冶炼制备技术;综述了加压技术在高品质特殊钢制备过程中的作用,如增大易挥发元素(氮、钙、镁等)溶解度及改善凝固组织等作用,并以高氮钢(22Cr-21Ni-7.5Mo-0.6N)为试验钢种,结合Thermo-Calc热力学计算软件探讨了压力对凝固相变过程的影响规律,计算结果表明,当加压至100 MPa后,固液相线温度分别提高了6.60和5.98 K,且改变了奥氏体形成区域大小,增加了固液相变驱动力,减小了临界形核半径,增大了形核速率。随着对易挥发元素作用认识的不断深入,加压技术将在高品质特殊钢的研发和制备过程中发挥至关重要的作用。

Abstract

Presently, the study of pressurization technology in steel-making and solidification of high-grade special steels mainly focuses on the N-alloyed stainless steels, especially for high-nitrogen steels. This article reviewed the role of pressurization technology in steel-making and solidification, such as increasing the solubility of volatile elements (N, Ca, Mg, et al.) and improving solidification structure. In this article, experiments on N-alloyed stainless steel 22Cr-21Ni-7.5Mo-0.6N and thermodynamic computing software Thermo-Calc were combined to analyze the influence of pressure on liquid-solid phase transformation. It showed that the solidus and liquidus temperature were increased by 6.60 and 5.98 K under 100MPa compared with those under 0.1 MPa and austenite region was expanded. Pressurization also increased driving force of liquid-solid phase transformation, decreased critical nucleation radius, accelerated nucleation rate and further refined solidification structure. Along with the deepening understanding of the volatile elements, the application prospects of pressurization technology will be very broad and bright in the manufacture of high-grade special steels.

关键词

加压冶金 / 高品质特殊钢 / 加压凝固 / 含氮不锈钢

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朱红春, 姜周华, 李花兵, . 加压技术在高品质特殊钢冶炼和凝固中的作用[J]. 钢铁, 2015, 50(11): 37-44 https://doi.org/10.13228/j.boyuan.issn0449-749x.20150109
ZHU Hong-Chun, JIANG Zhou-Hua, LI Hua-Bing, et al. Effect of pressurization technology on steel-making and solidification of high-grade special steels[J]. Iron and Steel, 2015, 50(11): 37-44 https://doi.org/10.13228/j.boyuan.issn0449-749x.20150109

参考文献

[1]Paszkowicz W.High-pressure powder X-ray diffraction at the turn of the century[J].Nuclear Instruments and Methods in Physics Research B, 2002, 198(3):142-182
[2]Emmnauel S, Paul F M, Clivia H, et al.Pressure-induced transformations in α- and β-Ge3N4: in situ studies by synchrotron X-ray diffraction[J].Journal of Solid State Chemistry, 2004, 177(1):299-311
[3]曲迎东, 李荣德, 袁晓光, 等.高压作用下合金凝固的研究进展[J].铸造, 2005, 54(6):539-541
[4]Wang W H, Dong C, Shek C H.Bulk metallic glasses[J].Materials Science and Engineering, 2004, 44(2):45-89
[5]Merkel S, Wenk H R, Gi11et P, et al.Deformation of polycrystalline iron up to 30GPa and 1000K[J].Physics of the Earth and Planetary Interiors, 2004, 145(4):239-251
[6]高建卫, 张振忠, 陈传文.高压凝固制备块体金属纳米材料研究现状及发展趋势[J].特种铸造及有色合金, 2004, 年会专刊(年会专刊):159-162
[7]Bridgman P W.The physics of high pressures[M]. London: G. Bell & Sons Ltd, 1949.
[8]张国志, 辛启斌, 王向阳.高压变熔点过冷大体积近快速凝固[J].东北大学学报自然科学版, 1998, 19(5):479-481
[9]李荣德, 黄忠平, 白彦华.高压凝固合金的非平衡组织[J].特种铸造及有色合金, 2003, 24(6):16-17
[10]李荣德, 黄忠平, 白彦华, 等.超高压力对合金非平衡凝固组织和性能的影响[J].铸造, 2003, 52(2):92-94
[11]王振玲, 王宏伟, 魏尊杰, 等.合金高压凝固组织及稳定性[J].中国有色金属学报, 2007, 17(3):383-389
[12]赵忠, 樊自田, 成平, 等.合金消失模铸造振动压力凝固的组织与性能[J].中国有色金属学报, 2010, 20(8):1520-1525
[13]Suarez B, Asensio-Lozano J, Vander-Voort G.Metallographic research of the pressure effect on the final microstructure of eutectic Al-Si Alloys[J].Microscopy and Microanalysis, 2007, 13(2):1030-1031
[14]李花兵, 姜周华, 申明辉, 等.氮气加压熔炼高氮钢技术的研究进展[J].中国冶金, 2006, 16(10):9-13
[15]姜周华, 李花兵, 董艳伍, 等.电渣重熔高氮不锈钢的研究进展[J].钢铁研究学报, 2006, 18(10):1-6
[16]Rashev T.高压冶金的前景(特殊钢—高氮钢)[A]. 2001中国钢铁年会论文集[C]. 北京: 2001, 541-549.
[17]Andreev C, Rashev T.Chromium-manganese stainless steel with nitrogen content up to 2.10wt%[J], 1999, 318:255-260[J].Materials Science Forum, 1999, 318:255-260
[18]Han B, Sujun W.Microstructural evolution of high manganese steel solidified under super high pressure[J].Materials Letters, 2012, 70(1):7-10
[19]Sobczak J J, Drenchev L, Asthana R.Effect of pressure on solidification of metallic materials[J].International Journal of Cast Metals Research, 2012, 25(1):1-14
[20]Gavrilova R, Yotova A, Manolov V, et al.Investigations on the influence of the parameters of solidification process on the structure of high nitrogen steels[J].Journal of the University of Chemical Technology and Metallurgy, 2003, (4):1185-1190
[21]陆利明, 丁伟中, 蒋国昌, 等.高压下的碳-氧平衡[J].钢铁研究学报, 1997, 9(4):9-12
[22]北村信也, 松尾充高, 内藤憲一郎.飛散物が少ない転炉製鋼方法[P]. 日本, 特開平11-323423, 2000
[23]程建雄, 蒋国昌, 陆利明, 等.氧气加压反应器中碳氧反应研究[J].包头钢铁学院学报, 1990, 18(3):246-251
[24]Jiang Z H, Li H B, Chen Z P, et al.The nitrogen solubility in molten stainless steel[J].Steel Research International, 2005, 76(10):740-745
[25]Riboud P, Dette M.碱金属脱硫, 物理化学和炼钢[C]. 北京: 冶金工业出版社, 1984.
[26]章奉山, 阮建波, 刘捷, 等.铁水罐喷吹颗粒镁高效化脱硫的研究[J].炼钢, 2005, 21(3):29-32
[27]Wada H, Pehlke R D.Nitrogen solution and titanium nitride precipitation in liquid Fe-Cr-Ni alloys[J].Metallurgical Trans B, 1977, 8(2):443-450
[28]Wada H, Pehlke R D.Solubility of nitrogen in liquid Fe-Cr-Ni alloys containing manganese and molybdenum[J].Metallurgical Trans B, 1977, 8(4):675-682
[29]Gaye H, Huin D, Riboud P V.Nitrogen alloying of carbon and stainless steels by gas injection[J].Metallurgical and Materials Trans B, 2000, 31(5):905-912
[30]Steinmetz E, Scheller P R.Fundamentals of nitrogen transfer in gas-metal bath systems during nitrogen injectionSteel Research[J].steel research, 1987, 58(7):303-309
[31]Gomersall D W, McLean A, Ward R G.The solubility of nitrogen in liquid iron and liquid iron-carbon alloys[J].Transactions of the Metallurgical Society of AIME, 1968, 242(7):1309-1315
[32]Medovar B I, Saenko V Y, Grigerenko G M, et al.Arc-slag remelting of steels and alloys[M]. Berlin: Cambridge International Science Publishing, 1996, 36-60.
[33]Carosi A, Kleimt B, Paura G, et al.Mastering P-ESR technology for high nitrogen steel grades for high value applications[M]. Luxembourg: Publications Office of the European Union, 2010.
[34]赵喜庆.氮合金化低碳马氏体不锈钢的组织与性能研究[D]. 沈阳: 东北大学, 2009.
[35]鲁海龙.氮强化马氏体不锈钢熔炼工艺及力学性能的研究[D]. 沈阳: 沈阳工业大学, 2006.
[36]马永柱, 秦斌, 陈旭, 等.氮合金化对马氏体不锈钢 回火性能的影响[J].宝钢技术, 2010, 28(2):35-39
[37]Berns H, Lueg J.Corrosion behavior and mechanical properties of martensitic steels containing nitrogen[A].Proceedings of the First International Conference on High Nitrogen Steels—HNS88[C]. France: Lille, 1988, 288.
[38]Saxena S K.Refining reaction of magnesium in steel at steelmaking temperature [A]. Proceedings InternationalSymposium on the Physical Chemistry of Iron and Steelmaking [C]. Conference of Metallurgists: Toronto, 1982, 17-22.
[39]周进华.铁合金[M]. 北京: 冶金工业出版社, 1993, 1-4.
[40]LaCombe L C, Koss M B, Tennenhouse L A, Winsa E A and Glicksman M E.The Clapeyron effect in succinonitrile: applications to crystal growth[J].J. Cryst. Growth, 1998, 194:143-148
[41]Arola R, Wendt J, Kivineva E.Gas porosity defects in duplex stainless steel castings[J].Materials Science Forum, 1999, 318:297-302
[42]李花兵.高氮奥氏体不锈钢的冶炼理论基础及其材料性能研究[D].沈阳: 东北大学, 2008.
[43]Saxena S K.The refining potential of magnesium in steelmaking[A]. The Shenyang Symposium on Injection Metallurgy and Secondary Refining of Steel[C]. Shenyang:China, 1984: 303-313.
[44]Erwin V.Zaretsky. Bearing and gear steels for aerospace application[R]. Cleveland:1990
[45]Sammt K, Sammer J, Geckle J, et al.Development trends of corrosion resistant plastic mould steels[A]. Proceedings of the 6th International tooling Conference[C]. Sweden: Karlstad, 2002, 285-292.
[46]S. Base.Test Process for Manufacturing a Cr-Mo-V Rotor Shaft[A]. Proceeding of Six International Conference on Special Melting[C]. American Vacuum Society, 1979, 773-779.
[47]郭成海, 肖桂兰, 赵春.新型护环钢应用特性研究[J].大电机技术, 1996, 3(4):32-38
[48]李阳.碱土金属合金对钢液脱氧极其夹杂物控制研究[D]. 沈阳: 东北大学, 2003.
[49]Wilson D J, deBarbadillo J J, Snape E.Desulfurization. Deoxidation and sulfide shape control with nickel-magnesium[A]. Electric Furnace proceedings[C]. Iron and Steel Society: Manchester, 1975: 196-200.
[50]邓能运, 杨治立, 张明远.铝镁合金脱氧理论研究[J].重庆工业高等专科学校学报, 2001, 16(2):40-43
[51]Fu J, Yu Y G, Wang A R, et al.Inclusion modification with mg teatment for 35CrNi3MoV steel[J],J[J].Mater. Sci.Technol., 1998, 14(1):53-56
[52]Debarbadjllo J J.Superalloys: Metallurgy and manufacture[A]. Proceedings of the Third International Symposium[C]. Seven Springs PA: USA, 1976, 12-15.
[53]山口重裕, 松宮徹, 小林尚, 等.基超合金の熱間加工性と微量元素の関係[J].铁と钢, 1977, 63(4):324-328
[54]Gong W, Jiang Z H, Zhan D P.Application of Al-Mg alloy in bearing steel[J].Materials Science Forum, 2009, 620:387-390
[55]周德光, 傅杰, 李晶, 等.轴承钢中镁的控制及作用研究[J].钢铁, 2002, 37(7):23-25
[56]孙文山, 桂荣, 罗铭蔚, 等.镁在 钢中的作用[J].兵器材料科学与工程, 1997, 20(4):3-8

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河北省自然科学基金项目;教育部新世纪优秀人才培育项目;河北省自然科学基金项目;中国博士后科学基金资助

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