钒钛磁铁矿碳热钠化还原工艺

张 俊,戴晓天,严定鎏,齐渊洪

钢铁 ›› 2016, Vol. 51 ›› Issue (10) : 6-9.

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钢铁 ›› 2016, Vol. 51 ›› Issue (10) : 6-9. DOI: 10.13228/j.boyuan.issn0449-749x.20160058
原料与炼铁

钒钛磁铁矿碳热钠化还原工艺

  • 张 俊,戴晓天,严定鎏,齐渊洪
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Carbothermal sodium reduction process of vanadium-bearing titanomagnetite

  • 张 俊,戴晓天,严定鎏,齐渊洪
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摘要

为了降低钒钛磁铁矿的还原和熔分温度,提高钛与钒的回收率,采取碳热钠化还原法处理钒钛磁铁矿,研究了钠化剂对钒钛磁铁矿还原以及熔分后钛、钒分布的影响。结果表明,钠化剂能显著改善钒钛磁铁矿的还原性以及磁选和熔分效果,钠化比为1.2时,1 100 ℃还原60 min即可达到90%以上的金属化率,磁选后铁的收得率达到92%以上,铁品位接近80%。1 450 ℃以上的温度熔分后,铁的收得率高于95%,钒在铁水中的分配比为91%,熔分渣水洗后[w(TiO2)]达到56%。

Abstract

In order to reduce the reduction and smelting-separation temperatures of vanadium-bearing titanomagnetite, and improve the recovery rate of Ti and V, the carbothermic reduction in combination with sodium-treatment was studied, and the effects of sodium agent on reduction as well as the distribution of Ti and V after smelting-separation were discussed. The sodium agent significantly improves the reducibility, the magnetic separation as well as the smelting-separation performance of vanadium-bearing titanomagnetite, the metallization ratio reached 90% at 1 100 ℃ for 60 min when the sodium ratio was 1.2, and the fine iron concentrate with a iron grade of 80% as well as iron yield of 92% was obtained after magnetic separation. The iron yield was higher than 95%, and the distribution ratio of V reached 91% when the sample was smelting-separated at 1 450 ℃. Moreover,[w(TiO2)]in slag reached 56% when the smelting-separation slag was washed in water.

关键词

钒钛磁铁矿 / 钠化还原 / 磁选 / 熔分

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张俊. 钒钛磁铁矿碳热钠化还原工艺[J]. 钢铁, 2016, 51(10): 6-9 https://doi.org/10.13228/j.boyuan.issn0449-749x.20160058
ZHANG Jun. Carbothermal sodium reduction process of vanadium-bearing titanomagnetite[J]. Iron and Steel, 2016, 51(10): 6-9 https://doi.org/10.13228/j.boyuan.issn0449-749x.20160058

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