硅镇静钢镁处理后夹杂物的生成及演变行为

张庆松, 闵 义, 许海生, 许久健, 刘承军

钢铁 ›› 2019, Vol. 54 ›› Issue (4) : 37-42.

PDF(1499 KB)
欢迎访问《钢铁》官方网站!今天是 2025年7月30日 星期三
PDF(1499 KB)
钢铁 ›› 2019, Vol. 54 ›› Issue (4) : 37-42. DOI: 10.13228/j.boyuan.issn0449-749x.20180277
炼钢

硅镇静钢镁处理后夹杂物的生成及演变行为

  • 张庆松,    闵    义,    许海生,    许久健,    刘承军
作者信息 +

Effect of magnesium treatment on formation and evolution of inclusion in Si-Mn deoxidized steel

  • 张庆松,    闵    义,    许海生,    许久健,    刘承军
Author information +
文章历史 +

摘要

为扩展镁处理在硅锰脱氧钢体系中的应用,采用高温模拟试验与热力学分析相结合的方法,考察了镁添加量及镁添加顺序对夹杂物生成及演变行为的影响。研究结果表明,Mg-Si-Mn-O钢液体系在1 600 ℃时存在MgO-SiO2-MnO(l)、2MgO·SiO2(s)和MgO(s) 3个热力学稳定区域。镁处理可有效改变SiO2-MnO脱氧产物,低镁加入量(0.000 5%)下生成MgO-SiO2-MnO液相夹杂物,高镁加入量(0.001 9%)下生成MgO固相夹杂物。硅和镁的加入顺序不同导致夹杂物的生成路径也不相同,先硅后镁时夹杂物生成路径为SiO2-MnO(l)→MgO-SiO2-MnO(l),而先镁后硅时夹杂物的演变过程为MgO(s)→MgO-SiO2(s)→MgO-SiO2-MnO(l)。

Abstract

In order to expand the application of magnesium treatment in the Si-Mn killed steel production, the effect of the amount and the order of addition magnesium on the formation and the evolution of inclusion were investigated by the combination of high temperature experiments and thermodynamic calculations. The results showed that the stability diagram of the Mg-Si-Mn-O molten steel at 1 600 ℃ was composed of MgO-SiO2-MnO(l), 2MgO·SiO2(s) and the MgO(s). The deoxidization product of the SiO2-MnO(l) was modified to MgO-SiO2-MnO(l) when the addition amount of magnesium was 0.000 5%. When the addition amount of the magnesium increased to 0.001 9%, MgO(s) phase formed.The formation path of inclusions varied with different orders of addition magnesium. When magnesium was added following the silicon addition, the formation path was SiO2-MnO(l)→MgO-SiO2-MnO(l). While the evolution path was MgO(s)→MgO-SiO2(s)→MgO-SiO2-MnO(l) when magnesium was added before addition silicon.

关键词

镁处理 / 硅锰脱氧 / 非金属夹杂物 / 热力学

Key words

magnesium treatment / Si-Mn deoxidization / inclusion / thermodynamics

图表

引用本文

导出引用
张庆松, 闵 义, 许海生, . 硅镇静钢镁处理后夹杂物的生成及演变行为[J]. 钢铁, 2019, 54(4): 37-42 https://doi.org/10.13228/j.boyuan.issn0449-749x.20180277
ZHANG Qing-song, MIN Yi, XU Hai-sheng, et al. Effect of magnesium treatment on formation and evolution of inclusion in Si-Mn deoxidized steel[J]. Iron and Steel, 2019, 54(4): 37-42 https://doi.org/10.13228/j.boyuan.issn0449-749x.20180277

PDF(1499 KB)

Accesses

Citation

Detail

段落导航
相关文章

/