25 September 2026, Volume 38 Issue 9
    

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    Review
  • MENG Qinghui, LI Zhixin, XIN Tongze, GUO Yixiong, ZHANG Yanlong, GE Yutian, WANG Min
    Journal of Iron and Steel Research. 2026, 38(9): 1307-1319. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260065
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    Converter lining is regarded as a critical structure for guaranteeing safe and stable operation of steelmaking processes. Its service state is directly reflected in converter campaign life, refractory consumption and production safety. During cyclic charging, blowing and tapping operations, the lining is subjected to coupled influences of multiple factors including attack by high-temperature molten slag and liquid steel, mechanical impact and scouring, thermal cycling and structural constraints. Abnormal erosion, cracking and spalling are easily induced in local zones, and burn-through and steel breakout accidents can be triggered under severe conditions. Systematic reviews are conducted on research progress concerning erosion mechanisms, erosion state monitoring and burn-through early warning technologies for converter linings. First, major damage mechanisms of converter linings are summarized from the perspectives of chemical erosion and slag penetration, mechanical impact and abrasion, thermal shock damage and structural stress. Regional and staged characteristics of erosion behaviours in typical zones are analysed, including the slag line zone, trunnion zone, tapping spout, furnace bottom and charging side. Second, influences of multiple factors on lining erosion are elaborated, such as smelting temperature and duration, MgO content, total iron content and basicity of slag, charging schedule and blowing operations. On this basis, fundamental principles, technical characteristics and engineering application status of lining condition monitoring and burn-through early warning approaches are emphatically reviewed, covering infrared thermography, laser thickness measurement, electrical detection, acoustic detection, neural network prediction and multi-source information fusion. Findings from existing investigations indicate that infrared thermography is adopted for continuous on-line monitoring of hot spots on the furnace shell. Laser thickness measurement is employed to quantitatively characterise residual lining thickness and local weak zones. Certain application potentials are demonstrated by electrical detection, acoustic detection and multi-source information fusion methods in continuous perception and improvement of early warning reliability. Nevertheless, popularisation and application of relevant technologies are still restricted by problems such as complicated on-site environments, temporally and spatially discontinuous monitoring data, insufficient cross-campaign adaptability of models and the absence of unified criteria for early warning thresholds. In future, deep integration between lining erosion mechanisms and data-driven models should be strengthened. Promotions should be realised for coordination of multi-source monitoring information, joint characterisation of residual thickness and erosion rate, and construction of a zoned and graded dynamic early warning system. Supports can thereby be provided for predictive maintenance and safe long-service operation of converter linings.
  • Smelting and Working
  • JI Zhiyun, LÜ Jiaming, LI Shaochun, DU Yanqing, FAN Xiaohui, YU Ying, WANG Xiaolong, GAN Min
    Journal of Iron and Steel Research. 2026, 38(9): 1320-1328. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250311
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    Significant carbon emission reduction pressure is imposed on the pre-ironmaking processes at the present stage, and a high carbon reduction potential is possessed by the cold-bonded briquetting process. In response to the dual-carbon goals of the iron and steel industry, the effects of forming moisture, forming linear pressure and iron concentrate type on the green briquette strength and consolidated briquette strength of cold-bonded briquettes are systematically investigated with four typical types of iron concentrates adopted. The evolution laws of microscopic pore structures are characterized via SEM-EDS and mercury intrusion porosimetry, and the influencing mechanisms of cold-state strength are clarified. Within the research scope, the performance of cold-bonded briquettes is obviously improved by reducing forming moisture and increasing forming linear pressure, and the optimal forming moisture and forming linear pressure are determined as 4.5% and 9.80 kN/mm, respectively. The mechanical interlocking force between particles are weakened by the increase of forming moisture, so that the strengths of green briquettes and consolidated briquettes are decreased synchronously. With increasing forming line pressure, particle rearrangement is promoted, the contact area between particles is increased, and the interparticle bonding bridges are strengthened, thereby improving the strength of cold-bonded briquettes. Opposite effects on the strength in the forming stage and consolidation stage are exerted by the particle size of iron concentrates. Higher green briquette strength and lower consolidated briquette strength are obtained with finer average particle size of iron concentrates. Under optimized forming and consolidation parameters, cold-bonded briquettes prepared from four kinds of iron concentrates are enabled to reach the dropping strength of green briquettes no less than 4 times/(0.5 m·P), consolidated briquette strength no less than 2 500 N/P and tumbler strength no less than 85%. All prepared briquettes are qualified to meet the cold-state strength requirements of blast furnace burden, and favorable engineering application prospects are presented.
  • FENG Junsheng, JIAO Yuming, ZHAO Liang, DONG Hui
    Journal of Iron and Steel Research. 2026, 38(9): 1329-1339. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250267
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    A two-stage cooling process coupling vertical cooling and annular recooling is proposed to address the deficiencies of existing sinter waste heat recovery equipment. Flow and heat transfer models inside the two-stage cooling device are established, and the influence laws of parameters including inlet air volume, inlet air temperature, cooling section height and cooling section length on core performance indicators such as waste heat recovery capacity and outlet heat carrier enthalpy-exergy of the device are analyzed emphatically. Simulation results calculated by the constructed numerical model are well consistent with measured experimental data, with a maximum relative error of only 5.83%, and the calculation accuracy and reliability of the model are effectively verified. Bed pressure drop is raised when inlet air volume, inlet air temperature and cooling section height are increased while cooling section length is reduced. Waste heat recovery capacity is elevated with the growth of inlet air volume, cooling section height and cooling section length, and decreased as inlet air temperature rises. The enthalpy-exergy of heat carrier is first increased and then reduced with the rise of inlet air volume, and gradually improved with the enlargement of inlet air temperature, cooling section height and cooling section length.
  • WEI Qingyang, HE Fei, TENG Yu, XIAO Zubin, QU Changle, XIAO Kai, WANG Yaozu, WANG Yutong
    Journal of Iron and Steel Research. 2026, 38(9): 1340-1347. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250329
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    Sinter from the transfer system between the 300 m2 sintering machine and the 1 260 m3 blast furnace at Jianlong Xilin Iron and Steel Co., Ltd. was taken as the research object. Full-process tracking sampling, industrial computed tomography (CT) three-dimensional reconstruction, scanning electron microscopy, and non-standard metallurgical performance tests were employed to systematically analyze the evolution patterns of particle-size distribution, tumbler strength, pore structure, crack propagation, and metallurgical properties of sinter during transfer. The results indicate that sinter particle refinement is induced by repeated high-head falling and mechanical collisions during transfer. The proportion of large-size fractions exceeding 25 mm is significantly reduced, whereas the proportion of the [5,10) mm fraction is gradually increased, and a refinement trend is exhibited by the average particle size. As revealed by industrial CT three-dimensional reconstruction, the internal pores, initially present as tiny and dispersed closed pores, are progressively transformed into interconnected fracture networks. Fracture length and connectivity are markedly increased, structural integrity is continuously deteriorated, and large-area interwoven cracks are formed prior to blast furnace charging. Tumbler strength is locally elevated due to the retention of high-strength large-size sinter fractions. Reducibility is found to decrease first and then increase. Low-temperature reduction degradation index is obviously deteriorated in the middle-to-late stage of transfer, which is attributed to the uniform pore structure formed by medium-size sinter fractions. Gas diffusion conditions can be improved and the reduction degree can be enhanced by such a pore structure.
  • LIU Dehua, SHAO Pin
    Journal of Iron and Steel Research. 2026, 38(9): 1348-1358. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250304
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    Bubble size distribution during ladle bottom argon-blowing directly affects the refining performance. A hybrid VOF-DPM numerical model coupled with bubble collision and coalescence models is established to systematically describe the dynamics of slag-metal interface as well as the motion and evolution behaviours of numerous discrete bubbles. The accuracy of the model is validated by water-model experiments. Further, systematic simulation and analysis are performed to investigate the influences of three key process parameters, namely bottom-blowing flow rate, blowing position and double-hole included angle, on bubble size distribution and slag eye morphology for a 120 t ladle. The results show that bubble coalescence and slag-eye expansion are significantly promoted with the increase of bottom-blowing flow rate. When the flow rate rises from 80 to 400 L/min, the average bubble diameter is increased by 30.1%. The flow-field structure can be optimised by varying the bottom-blowing position. As the bottom-blowing position is shifted from 0.1r(r denotes the ladle bottom radius) to 0.7r, the average bubble diameter is first reduced by 16.4% and then increased by 14.3%, and the slag-eye area is decreased first and increased afterwards. Finer and more dispersed bubble groups are obtained near 0.3r. The interaction between two bubble plumes can be regulated by adjusting the double-hole included angle. As the double-hole included angle increases from 45° to 180°, the average bubble diameter is first reduced by 9.8% and then increased by 7.8%, the slag-eye area decreases first and increases subsequently, and more remarkable variations of bubble size are observed at the ladle top.
  • HE Yibo, SONG Dazhou, LI Yihong, XUE Xilin, HUA Chengjian
    Journal of Iron and Steel Research. 2026, 38(9): 1359-1367. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250296
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    RH refining constitutes a critical procedure in steelmaking processes. The end-point carbon content serves as a vital indicator affecting steel properties. Accurate prediction of end-point carbon content in RH refining is of great significance for optimizing process control and guaranteeing finished product quality. To precisely predict the end-point carbon content, models are established by random forest (RF), linear regression (LR), support vector regression (SVR) and extreme gradient boosting (XGBoost) algorithms combined with recursive feature elimination (RFE). In the selection of feature variables for model training, different from the conventional heatmap method, a dynamic range strategy is proposed. A reasonable interval for the preset number of features is defined, each model within this interval is evaluated through grid search of model hyperparameters, and the model with optimal performance is selected to avoid limitations brought by a single feature quantity. Verification results based on 102 sets of on-site production data demonstrate that the model trained by the SVR algorithm with 18 feature variables screened via RFE achieves the optimal performance in predicting end-point carbon content during RH refining. The mean absolute error and mean squared error reach 1.427×10-6 and 6.626×10-10, respectively. A prediction hit rate of 93.5% is obtained under the precision requirement of ±5×10-6.
  • HUANG Lei, LING Rui, WANG Shimeng, WANG Yong, LIU Chengsong, ZHANG Hua, NI Hongwei
    Journal of Iron and Steel Research. 2026, 38(9): 1368-1381. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250356
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    The behavior of inclusions in 304 stainless steel after calcium modification has been relatively well clarified, yet their evolution during solidification remains insufficiently understood. A systematic investigation was conducted on calcium-modified 304 stainless steel through laboratory experiments and thermodynamic calculations, focusing on the evolution of inclusions throughout solidification. The results indicate that the calcium content in molten steel significantly affects the type and morphology of sulfide precipitation. In low-calcium heats, only MnS precipitates, nucleating either heterogeneously on Al2O3-SiO2-CaO-MgO inclusions or independently from the melt. In high-calcium heats, abundant CaS particles precipitate dispersedly on the surfaces of pre-existing inclusions. After furnace cooling, the Al2O3 fraction in inclusions of high-calcium heats increases significantly, accompanied by a decrease in SiO2 and substantial CaS precipitation. Conversely, in low-calcium heats, theSiO2 fraction increases, the Al2O3 fraction decreases, and MnS predominates. Post-cooling, the inclusion size increases while the number density decreases. Thermodynamic calculations further reveal that with increasing total calcium (T.Ca) content, the precipitation sequence follows: MnS+Ca2Al2SiO7→MnS+Ca2Al2SiO7+Ca2SiO4→MnS+Ca2Al2SiO7+Ca2SiO4+CaS→Ca2SiO4+MnS+CaS. At a fixed T.Ca, an increase in total oxygen (T.O) shifts the sequence to MnS+Ca2Al2SiO7+Ca2SiO4+CaS→MnS+Ca2Al2SiO7+Ca2SiO4→MnS+Ca2Al2SiO7+CaAl4O7+CaAl2Si2O8+Al2O3.
  • PENG Zun, HU Xin, LI Yihong, HUA Chengjian
    Journal of Iron and Steel Research. 2026, 38(9): 1382-1396. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250330
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    As the key equipment in the continuous casting process, the tundish is used to steadily supply molten steel, homogenize the composition and temperature of molten steel, and remove inclusions. Its flow control devices are susceptible to erosion and melting loss induced by scouring of high-temperature molten steel, which further alters the flow field of molten steel. Numerical simulation combined with industrial trials are adopted as research approaches. The service cycle of the tundish is divided into the effective period of flow control devices (0-40 h) and the complete failure period of flow control devices (40 h to tundish shutdown). The influence laws of different pouring point positions on the molten steel flow field inside the tundish at each stage are systematically analyzed, and their effects on molten steel quality and tundish service life are investigated. The obtained results indicate that during the effective period of flow control devices, stable and uniform molten steel flow field can be effectively maintained when the pouring point is arranged at the center of the impact zone. Under this condition, the volume fraction of dead zone reaches the minimum value of 20.17%, and the erosion rate of the impact zone is the lowest at 6.05 mm/h. After the complete melting loss of flow control devices, the distribution of flow field can be optimized when the pouring point is moved backward by 30 mm. The area of vortex region inside the tundish is minimized, the volume fraction of dead zone is reduced to 22.02%, and the erosion rate is decreased by 16.86% compared with the central pouring scheme. Verified by industrial trials, the composite pouring scheme (central pouring is applied during the effective period of flow control devices, and the pouring point of the long nozzle is moved backward by 30 mm in the failure stage) can extend the service life of the tundish to 80.97 h. Meanwhile, the differences in element contents of molten steel among each strand are smaller than those under other pouring modes.
  • FENG Qingxiao, WANG Yuqi, LI Hualong, GUO Tianyang, YANG Zhu, LIANG Xiao
    Journal of Iron and Steel Research. 2026, 38(9): 1397-1405. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260157
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    The sub-rapid solidification and single-pass rolling characteristics of strip casting and rolling endow the product with a distinct microstructure and mechanical properties, markedly different from those of conventional hot-rolled products. A systematic comparison of the microstructure, tensile properties, and plasticity-limiting factors was conducted between commercially produced strip-cast-rolled low-carbon steel and conventional hot-rolled low-carbon steel. The results show that the strip-cast-rolled steel exhibits a fully ferritic structure with a gradient distribution of fine grains (average 28 μm) in the surface layer and coarse grains (average 50 μm) in the center, yielding an overall average grain size of 47 μm. The length fraction of grain-boundary strip-like carbides reaches 62.7%. In contrast, the conventional hot-rolled steel presents a uniform fine ferrite with a small amount of pearlite, an average grain size of 15.6 μm, and a grain-boundary carbide length fraction of only 14.9%. Thermodynamic calculations reveal that the rapid post-rolling cooling in strip-caststeel suppresses pearlite transformation, promoting carbon segregation to grain boundaries and the formation of continuous carbides, whereas the slower cooling in conventional hot rolling allows sufficient precipitation of carbon as pearlite. The elongation values are 31.6% and 39.8% for the strip-cast-rolled and conventional steels, respectively. The inferior plasticity of the strip-cast-rolled steel is primarily attributed to two factors: the poor deformation compatibility of coarse grains, which induces non-uniform deformation and stress concentration even at low strains; and the mismatch in deformability between brittle grain-boundary carbides and the ferrite matrix, making these carbides preferential sites for crack initiation. During deformation, larger grains deform preferentially, concentrating stress at the carbide/ferrite interfaces, where microvoids readily form and propagate into intergranular secondary cracks, with preferential nucleation at grain boundaries of large grains. Owing to its lower carbide content and more uniform microstructure, the conventional hot-rolled steel does not exhibit such preferential cracking in large grains.
  • LIU Yang, ZHANG Jing, KANG Qingfeng, WANG Cunyu, XU Haifeng, ZHANG Xiaofeng, CAO Wenquan
    Journal of Iron and Steel Research. 2026, 38(9): 1406-1417. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260008
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    Using a 5-mm-thick hot-rolled plate as the starting material, specimens were cold-rolled to various reductions (60%, 80%, 90%, 94% and 96%) and subsequently subjected to high-temperature tensile testing at 800 ℃ and 1×10-2 s-1. Scanning electron microscopy, electron backscatter diffraction, and transmission electron microscopy were employed to characterize the microstructure-property evolution, aiming to clarify the effect of cold rolling reduction on the superplasticity of Fe-35Mn-8Al-0.3C low-density steel. The high-temperature tensile results show that all cold-rolled samples (with reductions of 60%-96%) exhibit elongations exceeding 300% under the tested conditions, demonstrating typical superplastic behavior. With increasing reduction, the elongation gradually rises from 341% for the 60% cold-rolled sheet to a maximum of 612.5% for the 94% cold-rolled sheet. Microstructural characterization reveals that Mn redistribution and dynamic recrystallization occur during high-temperature tensile deformation, transforming the initial cold-rolled α+γ dual-phase banded structure into an equiaxed dual-phase structure consisting of Mn-rich β-Mn and γ phases in an interlocked configuration. As the cold rolling reduction increases, the fraction of dynamic recrystallization after high-temperature tension rises from 79.6% to 99%, while the volume fractions of β-Mn and γ phases remain comparable and the grain size stabilizes at 1-2 μm, indicating that the final microstructure is largely independent of the initial reduction. After superplastic deformation, the hard β-Mn phase exhibits a fully recrystallized structure, whereas the soft γ phase retains a high density of dislocations. Based on these findings, a pre-deformation process with a cold rolling reduction of 90%-94% is identified as capable of yielding approximately 600% elongation, and the superplastic deformation mechanism of the low-density steel is proposed to be jointly governed by dislocation slip in the γ phase and grain boundary/phase boundary sliding.
  • Materials Research
  • YAN Xiao, XIE Jiaxuan, WANG Zichun, YAN Bowei, ZHANG Peng
    Journal of Iron and Steel Research. 2026, 38(9): 1418-1428. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260017
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    To explore the feasibility of preparing medium Mn steel with high strength and ductility via intercritical annealing, a 0.3C-6Mn-1.2Si-0.5Cr (mass fraction,%)medium Mn steel was investigated. Scanning electron microscopy, transmission electron microscopy, electron probe X-ray microanalysis, DICTRA diffusion kinetics calculations, and mechanical property tests were combined to systematically study the influence of intercritical annealing temperature on the microstructure and properties of the medium-Mn steel subjected to slow cooling after hot rolling. The results show that the intercritically annealed microstructure consists of martensite, ferrite, and retained austenite. At 600 ℃, retained austenite exhibits a film-like morphology; at 650 ℃, it transforms into a blocky shape; and at 625 ℃, the retained austenite content reaches its maximum, with the mass fraction of carbon peaking at approximately 1.3%. DICTRA calculations indicate that pre-partitioning of Mn in the intercritical region yields a pronounced Mn concentration gradient, which gradually homogenizes with increasing annealing temperature, consistent with EPMA observations. The annealing temperature significantly affects the mechanical properties: tensile strength increases while elongation decreases with rising temperature. At 625 ℃, the yield strength reaches 955 MPa and the product of strength and elongation attains a maximum of 32.54 GPa·%; at 600 ℃, the maximum elongation is 32.31%; and at 650 ℃, the highest tensile strength is 1 281 MPa. The tensile fracture surfaces exhibit ductile features with delamination, comprising both smooth layers and dimple-rich layers; as the annealing temperature increases, the thickness of the smooth layers decreases and the delamination tendency weakens. At 625 ℃, fine and dense dimples appear on the flat smooth fracture surface, with both dimple density and size increasing with temperature.
  • JIANG Chunhui, DENG Xinji, LI Zhaodong, CAO Yanguang, LI Yuan, WEI Wei
    Journal of Iron and Steel Research. 2026, 38(9): 1429-1442. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250345
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    The rapid development of high-pressure common-rail system technology and the continuous increase in injection pressure have created an urgent demand for high-pressure fuel pipe materials with higher strength grades. To address this need, 0.2% Cr (mass fraction) was added to the steel used for 16MnNiV small-diameter seamless steel tubes, and cold-drawn small-diameter seamless steel pipes with an outer diameter of 8 mm and an inner diameter of 3.6 mm were successfully fabricated. The resulting tubes exhibit a tensile strength of 972 MPa, a yield strength of 950 MPa, and an elongation after fracture of 15%. Scanning electron microscopy, electron backscatter diffraction, and transmission electron microscopy were employed to characterize the specimens after cold drawing and subsequent heat treatment. The results show that the addition of 0.2% Cr refines the pearlite interlamellar spacing, shifting its maximum proportion interval from 110-130 nm to 70-90 nm, while also enhancing the stability of pearlite during cold drawing. Combined with Thermo-Calc 2023a thermodynamic calculations and experimental results, the addition of Cr reduces the absolute value of the driving force for precipitation of cementite and VC, thereby suppressing their precipitation and consequently decreasing the desolvation of C. Furthermore, Cr doping into VC to form (V,Cr)C increases the interfacial energy from 0.594 to 0.646 J/m2, which facilitates the refinement of VC particles. Quantitative calculations of the strengthening mechanisms indicate that the dominant contributions from the addition of 0.2% Cr are, in descending order, solid-solution strengthening (204.7 MPa), dislocation strengthening (191.2 MPa), and precipitation strengthening (103.3 MPa).
  • ZHOU Huiling, HAN Yuyang, LI Jingyong, QIAO Yanxin, LU Sheng
    Journal of Iron and Steel Research. 2026, 38(9): 1443-1452. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260014
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    To clarify the influence of stress-relief annealing temperature on the microstructure, mechanical properties, and corrosion behavior in artificial seawater of selective laser melted (SLM) TC4 titanium alloy (SLMed TC4), specimens were vacuum-annealed at 600, 700 and 800 ℃ for 1 h. X-ray diffractometer, electron backscatter diffraction, scanning electron microscope, nanoindentation, Vickers hardness testing, and electrochemical measurements were employed to characterize the microstructure, mechanical response, and passivation behavior. The results show that with increasing annealing temperature, the acicular α′ martensite gradually coarsens and decomposes, and an α+β two-phase structure forms after annealing at 800 ℃. The elastic modulus increases from 102.40 to 133.98 GPa, and the plastic work increases from 1 862.29 to 2 371.29 pJ, whereas the Vickers hardness decreases, indicating that the release of residual stress and microstructural evolution jointly alter the mechanical response. The corrosion current density decreases from 1.43×10-7 to 9.83×10-8 A·cm-2, and the polarization resistance increases from 7.33×105 Ω·cm2 to approximately 7.58×105 Ω·cm2. The specimen annealed at 800 ℃ exhibits the lowest steady-state current density and the largest slope of the Mott-Schottky plot, suggesting a reduced carrier density and enhanced stability of the passive film. Overall, elevating the stress-relief annealing temperature enables synergistic regulation of the phase constitution, microstructural scale, and internal stress state in SLMed TC4, promoting the formation of a more stable and protective passive film, thereby improving its corrosion resistance in artificial seawater.