XIE Xiangxiang, LI Wanming, KANG Runwu, LIU Zefeng, WU Siyuan
In the process of electroslag remelting of rack steel, the consumable electrode will be oxidized at high temperature and short time before inserting into the slag surface. The oxidation products enter the slag pool with the electrode, which leads to the increase of oxygen potential and the burning loss of easily oxidized elements in the molten bath. However, it is difficult to formulate a reasonable deoxidation system due to the unclear oxygen increasing law.Therefore, it is urgent to systematically study the oxidation mechanism of the consumable electrode and establish the electrode oxidation mass gain model. Isothermal oxidation tests were carried out at 900, 1 000, 1 100, 1 200 and 1 300 ℃ in air atmosphere, respectively. The phase composition of the oxide scale was determined by X-ray diffractometer. The cross-sectional microstructure and cross-sectional element distribution of the rack steel were characterized by electron probe microanalysis. The evolution of the surface morphology of the sample, the formation of the precipitated phase and the distribution of the alloying elements were systematically studied. The formation mechanism of the oxidation products was analyzed by combining the oxidation kinetics law and the thermodynamic database, and the role and behavior of the alloying elements in the high temperature oxidation process were discussed. A multi-stage formation mechanism model describing the high temperature short-time oxidation of rack steel was established. Based on the results of isothermal oxidation test and the simulation results of electrode surface temperature field, the mathematical model of oxidation massgain of consumable electrode in electroslag remelting process of rack steel was established. The oxidation mass gain of electrode in a certain period of time was calculated, and the prediction results were verified by industry. The results show that the isothermal oxidation kinetics curve of rack steel in air atmosphere follows the parabolic law, and the activation energy of oxidation of rack steel is 197.17 kJ/mol. The oxide layer of the consumable electrode is mainly composed of Fe2O3, Fe3O4, FeO, SiO2, TiO2, Fe2SiO4 and FeCr2O4. Internal oxidation is more likely to occur at 1 200 ℃, which may be due to the penetration of molten Fe2SiO4 into the matrix and the exfoliation of the outer TiO2, which provide channels for oxygen diffusion. The oxidation mass gain model of rack steel consumable electrode was established, and the quantitative prediction of electrode oxidation amount in different time was realized, which could provide theoretical basis for the development of deoxidation system. In order to verify the accuracy of the oxidation mass gain model, the amount of deoxidizer added was calculated according to the oxidation mass gain model in industrial production. The qualified rate of 80 furnaces was 97.5%. It is of great significance for clarifying the oxygen transport mechanism and formulating the deoxidization system in the electroslag remelting process, and can lay a theoretical foundation for the high-performance preparation of rack steel materials for marine engineering equipment.