25 August 2026, Volume 38 Issue 8
    

  • Select all
    |
  • Journal of Iron and Steel Research. 2026, 38(8): 1051-1051.
    Abstract ( ) Download PDF ( )   Knowledge map   Save
  • GAN Yong
    Journal of Iron and Steel Research. 2026, 38(8): 1052-1052.
    Abstract ( ) Download PDF ( )   Knowledge map   Save
  • Reviews
  • CHEN Yiyang, LIU Haining, WANG Ruizhi, JIANG Xiaofang, ZHONG Honggang, ZHAI Qijie
    Journal of Iron and Steel Research. 2026, 38(8): 1053-1070. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260116
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    With the continued advancement of the dual carbon strategy, the proportion of scrap steel in steelmaking raw materials has been increasing continuously. The presence of residual elements such as Cu, Sn, Sb, and N in scrap steel, and their effects on steel processing, particularly on hottearing susceptibility, have become critical issues restricting the efficient recycling of scrap.The sources and classification of residual elements in scrap steel melting and their behavioral characteristics during the melting process are systematically summarized. On this basis, the major theories of hottear formation are reviewed, and the applicability and limitations of various hottearing prediction criteria are compared. Emphasis is placed on the segregation behavior, precipitation characteristics, and influence mechanisms of four typical residual elements (Cu, Sn, Sb, and N) during steel solidification. Specifically, Cu tends to segregate at grain boundaries to form low-melting-point phases, thereby widening the brittle temperature range. Sn and Sb exhibit a strong tendency for grain-boundary segregation, significantly reducing intergranular cohesion. N alters hottearing susceptibility through the formation of nitrides or by affecting the solidification path. Finally, the current research deficiencies in control strategies for residual elements under high scrap ratios, interactions among multiple elements, and in situ characterization techniques are discussed.
  • WANG Wanlin, YI Shu’an, ZHU Chenyang
    Journal of Iron and Steel Research. 2026, 38(8): 1071-1082. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260140
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Strip casting, as a short-process steel manufacturing technology aligned with China’s dual carbontarget, offers significant advantages in energy conservation and carbon emission reduction. However, the interfacial behavior during sub-rapid solidification in strip casting differs fundamentally from that in conventional continuous casting. This complexity is particularly pronounced in high-value-added advanced steel grades with intricate alloying systems, where interfacial phenomena (deposited film, wetting, and heat transfer) are closely coupled with solidification. Frequent surface cracking has thus become a critical bottleneck restricting its large-scale industrial application.The current research status of interfacial behavior during sub-rapid solidification of molten steel in strip castingis systematically summarized in this review, with emphasis on the influencing mechanisms of specific alloying elements on deposited film formation as well as interfacial wetting and heat transfer. Subsequently, the research progress on surface quality of typical advanced steel grades is reviewed, focusing on the specific surface quality issues encountered in high-strength steels, weathering steels, and other grades with relatively mature industrial development. Finally, future directions for surface quality control in strip casting are prospected. It is proposed that a deeper understanding of the intrinsic links among interfacial behavior, phase transformation, and crack formation, along with synergistic optimization of interfacial and solidification processes, represents the key pathway toward improving surface quality.
  • LIU Tie, JIANG Shan, ZHANG Baoze, MEI Shucheng, PAN Baifu, LI Zhe, LIU Yanxin, WANG Qiang
    Journal of Iron and Steel Research. 2026, 38(8): 1083-1112. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260152
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    A high magnetic field, as an emerging non-contact high-energy physical field, can regulate metal solidification through multiple mechanical, magnetic and energetic effects, including Lorentz force, thermoelectromagnetic force, magnetization force, magnetic torque and magnetocrystalline anisotropy energy, without altering the chemical composition of materials, thus offering a new route for improving solidification structures and material properties. The research progress on solidification behavior and microstructure evolution of metals under high magnetic fields is systematically reviewed. The various magnetic field types and their basic modes of action are introduced, and their effects on fundamental physical properties such as electrical resistivity, wettability, diffusion coefficient, phase transformation temperature and magnetic susceptibility are summarized. From thermodynamic and kinetic perspectives, the regulatory mechanisms of magnetic fields on melt flow, momentum transfer, solute migration and solid/liquid interface stability are analyzed. The influences on composition segregation, solidification morphology, columnar-to-equiaxed transition, grain refinement, crystallographic orientation and second-phase particle morphology are further summarized. Existing studies indicate that various magnetic effects are coupled with temperature, flow, solute and interface evolution fields, and their dominant roles are jointly governed by magnetic field intensity, direction and gradient, temperature gradient, solidification rate and alloy magnetic susceptibility. Finally, it is proposed to establish quantitative criteria for the competition and synergy of multiple magnetic effects, to develop data-driven prediction and high-temperature in-situ characterization techniques under high magnetic fields, and to promote the engineering application of magnetic-field-assisted solidification.
  • Smelting and Working
  • HU Wenguang, CAO Yanfei, WANG Yuqi, LIU Hongwei, FU Paixian, LI Dianzhong
    Journal of Iron and Steel Research. 2026, 38(8): 1113-1124. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260135
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Variable-composition delayed pouring is widely adopted as a key technique for mitigating macrosegregation in large steel ingots. However, its action mechanism and influence rules of process parameters have not been fully clarified. Based on a self-developed numerical model for macrosegregation, systematic analyses are performed on macrosegregation behaviors under various process parameters of delayed pouring. It is demonstrated that the degree of central positive segregation in ingots is gradually reduced with the extension of pouring delay time, increase of composition difference between ladles and rise of riser pouring height. Meanwhile, the composition gradient in the transition zone affected by the process is intensified, and local compositional inhomogeneity is aggravated accordingly. Further analyses reveal that downward liquid flow along the interface is generated at the solidification front during delayed pouring. The transport rules of solutes within the molten pool are altered, and the local distribution of temperature and solutes is rapidly reconstructed. In addition, local remelting at the solidification front is induced by the inflow of high-temperature molten steel with low solute content. For the design of delayed pouring processes, the control effect on central positive segregation, compositional uniformity of the transition zone and stability of the solidification front shall be comprehensively considered. Precise regulation of macrosegregation in large steel ingots can thereby be achieved.
  • SONG Jiaqi, MA Shuo, CUI Henan, CHANG Hai, LI Kangxue, WANG Guolian, WANG Chao, LIU Qing
    Journal of Iron and Steel Research. 2026, 38(8): 1125-1136. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260147
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Flat porous submerged entry nozzles serve as core equipment for high speed thin slab continuous casting. Increasing the number of outlet holes of such nozzles can guarantee molten steel supply, yet it complicates the flow field inside the mold and exerts influences on heat transfer, solidification and solute transport. To reveal the action laws of nozzle structures, a three-dimensional numerical model coupled with fluid flow, heat transfer, solidification, solute transport and constant background magnetic field is established for the thin slab continuous casting process of Q235B steel. The effects of four-hole and five-hole nozzles on flow field, temperature field, shell growth and carbon segregation under different casting speeds are analyzed. It is demonstrated that jet distribution and recirculation structures are remarkably altered by the hole number and spatial layout of nozzles. More outlets and smaller inner cavity volumes are equipped in five-hole nozzles, so stronger multiple jets are generated under identical casting speeds. A peak flow velocity of approximately 1.6 m/s is measured at the position 0.4 m below the meniscus for five-hole nozzles, which exceeds the 0.9 m/s obtained with four-hole nozzles. Lateral flows produced by five-hole nozzles facilitate the delivery of superheated molten steel to the lower mold and narrow faces, high-temperature zones near the nozzles are shrunk, and temperature uniformity in regions close to the narrow mold faces is improved simultaneously. Shell growth is significantly affected by casting speeds. Thinner shells are formed at the mold outlets for both nozzle types with rising casting speeds, and more drastic variations are observed when four-hole nozzles are adopted. Carbon segregation is governed jointly by molten steel flow, heat transport and solute accumulation. Positive segregation zones are formed at solidification fronts under the scouring action of molten steel. The peak segregation positions of five-hole nozzles are gradually shifted downward with increased casting speeds, while peak segregation values are maintained within the range of 1.20—1.22 and barely disturbed by casting speed elevation. In conclusion, the matching of rational porous nozzle structures and high casting speed process parameters contributes to optimized flow field configurations inside molds, stable shell thickness at mold outlets and alleviated central segregation.
  • ZHANG Haijie, HU Jiandong, WANG Wenxue, SHANG Yadan, CAO Shuwei, ZHANG Lifeng
    Journal of Iron and Steel Research. 2026, 38(8): 1137-1148. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260138
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Driven by the advancement of major equipment and energy engineering, the market demand for ultra-large metal castings keeps rising in fields including nuclear power, shipbuilding, wind power, metallurgy and heavy machinery, with stricter standards imposed on their internal quality and mechanical properties. To clarify the solidification mechanism of ultra-large steel ingots, a three-dimensional multiphase solidification model coupling columnar grains, equiaxed grains and liquid phase is adopted to simulate the cooling and solidification behaviors of a 303 t 16Mn steel ingot. Established on a volume-averaged multiphase framework, flow, heat transfer, solute transport and equiaxed grain number density equations are solved within the model. Molten steel flow, equiaxed grain migration, solute redistribution at solid-liquid interfaces and latent heat release induced by solidification phase transformation during ingot solidification are quantified, and predictions for multiphase solidification processes involving columnar and equiaxed grains are realized. The equiaxed grain nucleation mechanism triggered by the fragmentation of high-order dendrite arms is incorporated into the model, and solidification and remelting phenomena occurring during equiaxed grain transport are calculated. Highest cooling rates are detected at the bottom and sidewall regions of the steel ingot, and rapid growth of columnar grains is accelerated accordingly. Massive equiaxed grains are generated via dendrite arm fragmentation near solidification fronts. Dense equiaxed grains sink under gravitational force and accumulate at the ingot bottom. Microstructural transformation from columnar grains to equiaxed grains is facilitated by this mechanism, and an inverted triangular equiaxed grain zone is formed at the ingot bottom. Distinct influences on macrosegregation distribution are exerted by equiaxed grain distribution. Solute-depleted equiaxed grains are concentrated at the ingot bottom, and negative segregation is generated at this position. Molten liquid enriched with solute elements floats continuously throughout solidification, and severe positive segregation is formed along the ingot central axis and adjacent to the top riser. Channel segregation is also predicted to develop near the riser region. The simulated distributions of macrosegregation and solidification microstructures are matched with distribution laws acquired from ingot dissection experiments and previously published experimental data.
  • LI Huirong, WANG Sicong, SUN Ligen, PENG Fei, WANG Bo, ZHU Liguang
    Journal of Iron and Steel Research. 2026, 38(8): 1149-1159. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260137
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    DP590 high-strength dual-phase automotive steel enjoys extensive application. Under increasingly severe service environments, homogeneity defects of rolled products induced by internal quality flaws in cast slabs have become prominent, and continuous casting soft reduction technology serves as an effective technical route to address such issues. Aiming at internal defects including central porosity, central shrinkage cavities and intermediate cracks in continuous casting slabs of DP590 dual-phase automotive steel, numerical simulation and thermal simulation tests are integrated, and thermal states and microstructure evolution laws of cast slabs under various reduction amounts are systematically analyzed to determine the reasonable control range of soft reduction amounts. Results are demonstrated that the effect of soft reduction can be efficiently transmitted to the central zone of cast slabs. When the reduction amount is raised from 0 to 18 mm, the temperature at central nodes of cast slabs is decreased by 0.633 ℃, and the central solidification process is accelerated to a certain extent. Meanwhile, deformation fluctuations at slab centers are increased remarkably, and risks of initiation and propagation of central cracks are elevated accordingly. Through analysis on distribution laws of stress and strain, stress concentrations on slab surfaces are mainly concentrated at corner regions, stress levels on outer arcs are obviously higher than those on inner arcs, and strain values of inner arcs are significantly larger than those of outer arcs. With the increase of reduction amount, overall stresses on both inner and outer arcs of cast slabs are raised synchronously, and strain growth amplitudes of inner arcs are particularly remarkable. Uneven deformation along the slab width direction is therefore triggered, and asymmetric slab broadening is generated. Thermal simulation tests are further verified that solidification microstructures of cast slabs can be effectively refined by soft reduction technology, and obvious influences are exerted on the precipitation behavior of massive ferrite. At the position 1/4 slab thickness away from the inner arc, the optimal uniformity of solidification microstructures is obtained under a reduction amount of 9 mm, and the generation of intermediate cracks in cast slabs can be effectively restrained.
  • YAO Hao, ZHANG Yuexin, WANG Jujin, ZHANG Lifeng
    Journal of Iron and Steel Research. 2026, 38(8): 1160-1174. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260087
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    To address the difficulty in measuring and predicting the spatial distribution of inclusion compositions in continuous casting blooms, a 280 mm×380 mm bloom produced in an industrial steel plant is selected as the research object. The Brody-Fleming segregation equation was coupled with thermodynamic and kinetic models for inclusion composition transformation. The equilibrium partition coefficients of nine elements are calculated using FactSage and fitted as linear functions of liquid fraction. On this basis, a coupled model is established, by which the three-dimensional spatial distributions and dynamic evolution of dissolved element contents in steel and inclusion contents during continuous casting are simultaneously predicted with an improved description of elemental thermodynamic properties. The results show that the model is able to characterize the spatial distribution features of solute elements and inclusion contents during continuous casting with good accuracy. At 27 m below the meniscus, the calculated total sulfur mass fraction in the central region of the continuous casting bloom is approximately 0.007%, the total aluminum mass fraction is about 0.003 8%, and the dissolved aluminum mass fraction reaches roughly 0.002 64%. Owing to the differences in dissolved element contents at different positions in the bloom, the evolution of inclusion compositions also exhibits obvious spatial non-uniformity. At the bloom edge, the calculated inclusion contents are close to the measured results. Within the bloom interior, the calculated contents of Al2O3, CaO, CaS and SiO2 are in good agreement with the measured values, whereas the calculated MnS content in the bloom center is higher than the measured result. Because of the thermodynamic characteristics of MgO, the calculated and measured results are mainly close in magnitude, while differences still exist in their spatial distribution patterns. Overall, the element contents calculated by the model are in good agreement with the experimental measurements.
  • QIU Junhua, JIA Xingyu, TANG Haiyan, DENG Wei, JIN Lun’an, WANG Kaimin, ZHANG Jiaquan
    Journal of Iron and Steel Research. 2026, 38(8): 1175-1188. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260112
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Disqualification in water immersion ultrasonic inspection induced by inclusions frequently occurs for premium bearing steel one-hot rolled rods manufactured via the continuous casting billet one-hot rolling process. The sources and formation mechanisms of such defects are systematically investigated starting from refining and casting processes, and effective control measures based on molten steel flow regulation inside the mold are proposed. Correlative analyses of inspection defect zones on rolled products, inclusion characteristics in molten steel during smelting and continuous casting billets, and chemical compositions of nozzle clogging deposits are performed. Large-sized chain-shaped Mg-Al-(Ca)-O composite inclusions distributed inside rolled rods are identified as the dominant trigger for unqualified water immersion ultrasonic inspection results. Indigenous Al2O3 and MgO-Al2O3 inclusions in molten steel are accumulated on inner walls of the submerged entry nozzle to form clogging deposits during casting. Detached clogging agglomerates fail to achieve sufficient floatation inside the mold, and such inclusions are subsequently inherited from continuous casting billets to finished rolled rods. Insufficient floatation efficiency of separated clogging materials is caused by unreasonable flow field distribution within the mold. Structures of submerged entry nozzles are therefore optimized through a combination of 1:1 physical modeling and numerical simulation. An upward-inclined four-side-hole submerged entry nozzle is developed accordingly. Uniform and active molten steel flow fields inside the mold are generated and the floatation and removal of inclusions are promoted by the designed nozzle without abnormal mold level fluctuation and slag entrapment. After continuous casting with this optimized nozzle, the qualification rate of water immersion ultrasonic inspection for premium bearing steel one-hot rolled rods is raised from 62% to more than 95%.
  • ZHOU Mengcheng, MA Heng, GENG Zeyu, WANG Zhongxue, LIU Changhao, HUANG Xiaoshan, ZHANG Xinfang
    Journal of Iron and Steel Research. 2026, 38(8): 1189-1201. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260154
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    As marine equipment is gradually extended to deep sea and polar cold regions, higher requirements are imposed on low-temperature strong toughness and service reliability of heavy-section offshore engineering steel. To address the critical problems of easily coarsened core microstructure and inferior toughness in heavy steel plates, oxide metallurgy technology that submicron non-metallic inclusions are adopted to induce heterogeneous nucleation of acicular ferrite has become a core approach for optimizing core microstructure and mechanical properties. Nevertheless, collision and agglomeration of various inclusions readily occur during solidification in practical large-section continuous casting, forming large-size harmful particles. Uniform and dispersed distribution of fine inclusions is destroyed by this phenomenon; the steel matrix is also separated, and fatigue cracking is thereby triggered. Dual objectives including removal of large-size harmful inclusions and refinement as well as uniform dispersion of small-size beneficial inclusions cannot be simultaneously achieved by existing chemical modification methods and physical purification processes developed based on Stokes’ law. Aiming at the urgent and unresolved difficulty in homogeneous regulation of inclusions, a novel method is proposed for regulating homogeneous distribution of inclusions during molten steel solidification via pulsed current based on the driving theory of current density gradient, and regulation mechanisms of pulsed current on uniform distribution of inclusions are systematically investigated. Key parameters determining migration efficiency of inclusions are verified to be pulsed current frequency. Severe central inclusion segregation in cast slabs can be eliminated by pulsed current, and uniform and dispersed distribution of non-metallic inclusions over the full cross-section of cast slabs is realized, as further validated by industrial continuous casting trials. Meanwhile, remarkable reductions in average inclusion size and obvious increases in the proportion of fine inclusions are observed after treatment with pulsed current. Local Joule heating effects induced by bypass current in micro-regions at inclusion interfaces are responsible for such variations. Surface energy of inclusions is reduced by the above effects, wettability of molten steel against non-metallic inclusions is improved, thermodynamic barriers for collision and coalescence between inclusions are elevated accordingly, and collision-induced growth of inclusions is suppressed ultimately.
  • WANG Lei, WU Yuhan, QIU Wenjun, LUO Weiwei, ZHANG Tianyu, SUN Meijia, LIU Xiaoming, WANG Qiang
    Journal of Iron and Steel Research. 2026, 38(8): 1202-1211. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260131
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Due to the large cross-sectional dimension and long solidification duration of extra-thick slab, the central segregation cannot be effectively alleviated by conventional external electromagnetic flow control technologies. As a novel electromagnetic flow control method regulating molten steel flow from inside to outside, electromagnetic swirling technology enables effective regulation of the initial flow field inside the mould. Industrial tests of electromagnetic swirling are carried out under the current of 600 A and frequency of 50 Hz for unsteady casting conditions at the last casting heat of a 450 mm extra-thick slab continuous caster in a domestic steel plant. Variation characteristics of molten steel flow patterns inside the mould before and after the application of electromagnetic swirling are investigated via multi-physics coupling numerical simulation. Test results demonstrate that central segregation of extra-thick slabs cast at the last heat can be remarkably improved by electromagnetic swirling technology, and segregation ratings are all restricted within C1.0. Under the effect of electromagnetic swirling, the initial jet flow inside the mould is presented as S-shaped dispersed flow with low velocity, uniform distribution, stable state and shallow impact depth, and erosion on the initially solidified shell can therefore be mitigated.
  • Materials Research
  • WU Qiqi, WANG Xiwei, WANG Tiantian, WANG Li, ZHAO Peng, YANG Shufeng
    Journal of Iron and Steel Research. 2026, 38(8): 1212-1224. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260136
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    To address the issues of segregation and microstructural inhomogeneity in Inconel 718 alloy ingots produced by dual vacuum melting at a domestic enterprise, the melt pool evolution, dendrite characteristics, and elemental segregation during vacuum arc remelting, as well as the dissolution behavior of Laves phase and Nb diffusion kinetics during homogenization, were systematically investigated using finite element numerical simulation, thermodynamic calculation, and microstructural characterization. The results indicate that during vacuum arc remelting, the melt pool morphology changes from an initial shallow flat shape to a stable U-shape; the extension of the mushy zone leads to gradual coarsening of dendrite size from the ingot surface to the center. Nb and Mo exhibit obvious positive segregation in the interdendritic regions, and the ingot shows non-uniform features with deteriorated structure at the top and aggravated segregation at the center, with the maximum Nb segregation coefficient reaching 2.86 in the top-center area. During homogenization, the Laves phase dissolves progressively and the Nb distribution becomes more uniform. Kinetic analysis reveals that the volume fraction of Laves phase decays exponentially with homogenization time. By optimizing the two-step homogenization treatment, the residual segregation index of Nb is reduced from1.00 (as-cast) to 0.14.The optimal homogenization regime was ultimately determined to be 1 160 ℃ for 20 h, followed by heating to1 180 ℃ and holding for 45 h. The established residual segregation index model can provide a theoretical basis for optimizing the homogenization process of Inconel 718 alloy.The final alloy bars exhibit a dense and uniform microstructure without obvious macro-defects, with an average grain size of 8-10.5 grade, and the tensile properties at room and elevated temperatures, stress-rupture properties, and impact toughness all exceed the national standard requirements.
  • CHENG Qianqun, TANG Sifan, WANG Zhe, YAO Man, DONG Wei, WANG Xudong
    Journal of Iron and Steel Research. 2026, 38(8): 1225-1237. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260092
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Micrometer-sized spherical alloy particles hold significant application potential in electronic packaging and semiconductor manufacturing, with their microstructure and performance largely governed by dendrite growth behavior during rapid solidification. A three-dimensional phase-field numerical model coupling heat and mass transfer was established to simulate dendrite growth during the preparation of Al-4.5%Cu (mass fraction) alloy microspheres via the pulsated orifice ejection method. The effects of initial superheat and multi-dendrite competition on dendrite growth behavior were systematically investigated. The simulated secondary dendrite arm spacing (20.76 μm) agreed well with the experimental measurement (21.85 μm), with a relative error of 5.3%, validating the reliability of the model. During solidification, dendrites exhibited circumferential growth characteristics, preferentially spreading along the spherical surface to form a shell layer, followed by inward propagation. The initial superheat significantly influenced dendrite morphology: under single-nucleus conditions, when the superheat exceeded a critical value, a stable temperature gradient developed inside the microsphere, and dendrites grew along the surface, eventually forming a "spherical shell" structure. In multi-nucleus systems, increasing superheat caused dendrite arms to transform from coarse to slender, while radial growth toward the sphere interior was markedly suppressed. The multi-dendrite growth process exhibited an evolution from initial independent growth to later competitive inhibition. The earlier-formed nuclei gained a growth advantage by modifying the local thermal and solute fields, ultimately determining the microstructural distribution characteristics of the microspheres.
  • SONG Saihao, WANG Yingchun, XU Guodong, QIN Hanwei, LIU Haining, ZHONG Honggang, ZHAI Qijie
    Journal of Iron and Steel Research. 2026, 38(8): 1238-1247. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260091
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Surface transverse cracking is a common quality defect during continuous casting of low-carbon microalloyed steel slabs, which severely deteriorates slab quality and production efficiency. A dual-phase-transformation cooling regime applicable to the secondary cooling zone was proposed based on the actual continuous casting process of EH40 steel, and the growth behavior of austenite grains in the slab surface layer under this regime was investigated via thermal simulation experiments. Results indicate that, during the primary phase transformation stage, a higher cooling rate suppresses the precipitation of film-like proeutectoid ferrite along grain boundaries and promotes dispersed intragranular ferrite distribution. During the secondary phase transformation stage, the intragranular ferrite re-transforms into fresh austenite, which partitions the prior austenite grains and consequently refines the grain structure. Compared with the conventional cooling regime, the dual-phase-transformation regime exhibits a marked refinement effect on austenite grains in the slab surface layer. Specifically, the maximum grain size at the starting point of the straightening segment is reduced by approximately 60%, and a reduction of about 50% remains even after air cooling for 3 000 s following the end of continuous casting. Hence, adoption of the dual-phase-transformation cooling regime in slab continuous casting can significantly refine the surface austenite grains of EH40 steel, which is beneficial to reducing the susceptibility to straightening cracking.
  • XU Tao, LI Zizhe, HOU Chenyang, ZHANG Jianlei, SONG Changjiang, ZHAI Qijie
    Journal of Iron and Steel Research. 2026, 38(8): 1248-1259. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260099
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    The influence of Mo content on the precipitation behavior of strengthening phases and mechanical properties in Fe-20Mn-9Al-1.2C-xMo (x=0, 1.0%, 2.0%, 3.0%, 4.0%, mass fraction)low-densitysteels was systematically investigated. These steels were fabricated via a sub-rapid solidification process. The yield strength of the low-densitysteels was found to exhibit a trend of initial decrease followed by an increase with increasing Mo content. Microstructural analysis revealed that Mo addition increased the formation energy of κ-carbides and narrowed their precipitation temperature range, resulting in reduced size and quantity of κ-carbides. Meanwhile, Mo addition promoted the precipitation of Mo2C particles at grain boundaries, which significantly refined the austenite grain size. Notably, the addition of only 0.5%(mass fraction) Mo induced the formation of short-range ordering (SRO) structures in the austenite, and the amount of SRO increased with higher Mo content, effectively enhancing the strength of the austenite matrix. Quantitative strengthening mechanism analysis indicated that the recovery of strength in high-Mo steels mainly originated from the intrinsic strengthening increment provided by SRO structures (approximately 94.8 MPa) and the grain refinement strengthening caused by Mo2C precipitation, both of which compensated effectively for the strength reduction due to the decrease in κ-carbides.
  • XUE Jiaxing, LIANG Lunxing, ZHANG Yuexin, ZHANG Lifeng, YU Hongbin, LIU Zhonghua, CHENG Lin, LI Xudong
    Journal of Iron and Steel Research. 2026, 38(8): 1260-1274. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260086
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    To clarify the effects of cooling rate and titanium content on precipitates and microstructure in titanium-bearing non-oriented silicon steel, 30Y non-oriented silicon steel continuous casting slabs with titanium mass fractions of 0.000 9% and 0.002 5% were investigated. Using high-temperature laser confocal heat treatment, field emission scanning electron microscopy, and electron backscatter diffraction, the precipitate characteristics, grain structure, and texture evolution were analyzed under cooling rates of 1, 10, and 50 ℃/s. The results show that the main precipitates in the specimens are sulfides (MnS, Cu2S) and AlN, with TiN and TiC also present in the high-titanium specimens. Most precipitates are 200-500 nm in size and irregularly distributed. As the cooling rate increases, the total number of precipitates and the sulfide count decrease in both high- and low-titanium specimens. Since titanium promotes precipitate nucleation, the precipitate density in high-titanium specimens is significantly higher than that in low-titanium specimens across all cooling rates, with the highest titanium-rich precipitate count observed under slow cooling, while the AlN content increases slightly with increasing cooling rate.In terms of texture evolution, the low-Ti sample exhibited enrichment of favorable orientations at a cooling rate of 10 ℃/s, while the most favorable orientation was further strengthened at 50 ℃/s. For the high-Ti sample, the area fraction of the favorable {110}<001> texture increased sharply to 35.7% at 50 ℃/s, accompanied by the near-complete elimination of unfavorable orientations, indicating an optimized crystallographic orientation for magnetic properties.These findings indicate that increasing the cooling rate generally enhances favorable magnetic orientations and weakens detrimental ones, and the synergistic regulation of titanium content and cooling rate provides an effective approach for tailoring precipitates and microstructure in titanium-bearing non-oriented silicon steel.
  • LI Yuting, HE Zhiyu, LI Huabing, ZHU Hongchun, YAN Xinbo, WANG Qingyun, WANG Guoqing, LI Jiacheng
    Journal of Iron and Steel Research. 2026, 38(8): 1275-1282. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260128
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Effects of pressurization on physical property parameters and solidification microstructure of ingots produced by electroslag remelting of high-nitrogen stainless steel are systematically investigated, and the mechanisms for the influences of pressurization on secondary dendrite arm spacing and precipitated phases are clarified. Phase diagrams, solidus and liquidus temperatures, density and enthalpy within the pressure range of 0.5-10.0 MPa are calculated by using Thermo-Calc thermodynamic software. Pressurized electroslag remelting experiments are conducted under pressures of 0.5, 1.0 and 1.5 MPa. Results demonstrate that physical property parameters are slightly affected by pressure, and such influences can be neglected in the range of 0.5-1.5 MPa. Secondary dendrite arm spacing at all positions of ingots is remarkably reduced with the increase of pressure, and the value at the edge is decreased from 94.4 to 71.9 μm. Melting rate of electrodes is lowered by pressurization, which leads to a shallower molten pool and an increased temperature gradient. Meanwhile, interfacial heat transfer is optimized and cooling rate is raised, so that dendrite coarsening is inhibited. Two types of carbonitrides, granular M2(C,N) and lamellar M23(C,N)6, are mainly identified as precipitated phases in ingots, and their area fractions are obviously declined as pressure rises. Dendrites are refined by pressurization, which shortens the diffusion distance of solutes and alleviates interdendritic segregation, thereby restricting the growth of precipitated phases. Calculation results of segregation ratio (RS) show that RS values at the center are decreased while those at the edge are increased after pressurization, and the overall RS values approach 1, which indicates that macroscopic segregation is improved.
  • JIAO Yuchu, WANG Weiling, YUE Yingying, SONG Guodong, ZHU Miaoyong
    Journal of Iron and Steel Research. 2026, 38(8): 1283-1295. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260088
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Large-sized TiN inclusions formed during the continuous casting and solidification of 20CrMnTi gear steel are significantly degraded in corrosion resistance of the final product. Reheating is regarded as one of the critical methods to regulate the size and distribution of TiN. Heating tests are performed at different temperatures (900, 1 000 and 1 100 ℃) and holding times (0.5, 1.0, 1.5 and 2.0 h). Electrochemical tests are conducted on specimens taken from different positions of as-cast slabs and reheated samples. With the adoption of an automatic inclusion analysis system and an electrochemical workstation, the evolution rules of TiN inclusions affected by heating processes are revealed, and the action mechanism of TiN on corrosion resistance is clarified. The correlation among heating process, TiN characteristics and corrosion resistance is established. The results show that the solid solution of TiN is effectively promoted with the increase of heating temperature and the extension of holding time within the range of 0.5-1.5 h. The number of TiN particles is reduced, the particle size is refined, and the particle morphology is smoothed. When the holding time is prolonged to 2.0 h, the mismatch between the diffusion rates of titanium and nitrogen elements leads to local solute supersaturation in the matrix, and the secondary precipitation of TiN is induced with a slight increase in the number of particles. Electrochemical test results demonstrate that when the quantity of TiN is decreased and the proportion of large-sized particles is lowered, the polarization resistance of specimens is increased from the order of 104 to 105 kΩ·cm2, and the corrosion resistance is remarkably improved. Through comprehensive evaluation, the optimal heating process is determined as holding at 1 100 ℃ for 1.5 h. Under this condition, the reduction rate of TiN reaches 94.83%, and the polarization resistance is measured as 2.03×105 kΩ·cm2.
  • ZHANG Jiaxian, FAN Lei, LIANG Tian, QU Tianpeng, WANG Deyong
    Journal of Iron and Steel Research. 2026, 38(8): 1296-1306. https://doi.org/10.13228/j.boyuan.issn1001-0963.20260148
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    High-Ti nitrogen-containing 316Ti steel is prone to the formation of coarse TiN inclusions and theirclusters during solidification. The precipitation, growth, and agglomeration evolution behaviors of TiN inclusions were systematically investigated by varying the mass fractions of Ti and N as well as their addition sequences. Scanning electron microscopy combined with ImageJ software was employed to characterize the morphology, count and size distribution of the inclusions. FactSage thermodynamic calculations and a microsegregation model were adopted to theoretically elucidate the effects of Ti and N contents on the thermodynamics and kinetics of TiN precipitation. The results indicate that when the Ti mass fraction increases from 0.2% to 0.6%, the starting precipitation temperature of TiN rises from 1 419 to 1 495 ℃, broadening the liquid-phase precipitation range and facilitating TiN growth at elevated temperatures. When the N mass fraction increases from 0.004% to 0.009%, the starting precipitation temperature rises from 1 421 to 1 505 ℃, the total number of TiN inclusions increases from 21 to 41, the number density increases from 190.9 to 372.7 mm-2, and the proportion of medium- and large-sizedclusters rises from 33.3% to 48.8%. During solidification, once the solid fraction exceeds 0.9, the [Ti]·[N] concentration product in the liquid phase at the solidification front increases sharply, promoting TiN precipitation and agglomeration at the final solidification stage.Compared with nitrogen addition process before alloying, nitrogen addition after alloying reduces the amount of TiN precipitates at the 1 450 ℃ sampling point by 65%,significantly suppressing TiN precipitation in the high-temperature liquid region.