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脱氧制度对电渣重熔304NG不锈钢中夹杂物的影响

Effect of deoxidation process on inclusions in electro-slag remelted 304NG stainless steel

  • 摘要: 为了探究脱氧制度对电渣重熔304NG不锈钢中夹杂物的影响,开展了不同脱氧制度下的渣金平衡实验.结果表明:当使用Al脱氧时,钢中存在高熔点Al2O3和MgO-Al2O3夹杂物,并且随着Al加入量的增大,MgO-Al2O3中MgO含量呈上升趋势,夹杂物更易聚集长大形成团簇状;当使用复合脱氧剂Al+CaSi时,钢中主要是球形的低熔点液态CaO-Al2O3-MgO夹杂,以及核心为MgO-Al2O3,次外层为CaO-Al2O3,最外层为CaS的复合夹杂物.在Al脱氧、CaSi脱氧及Al+CaSi复合脱氧条件下,钢中均未观察到单独的CaS及MnS夹杂物.随着脱氧剂加入量的增大,钢中夹杂物数量明显减少,尺寸显著细化.

     

    Abstract: In order to investigate the influence of deoxidation processes on the inclusions in electroslag remelted304NG stainless steel,slag-metal equilibrium experiments have been conducted under different deoxidation conditions.The results show that when using Al deoxidation,high melting point Al2O3 and MgO-Al2O3 inclusions are present in the steel.With an increase in the amount of added Al,the MgO content in MgO-Al2O3 continuously increases,and the inclusions tend to agglomerate and grow into clusters.When using the composite deoxidizer Al+CaSi,the steel mainly contains spherical low-melting-point liquid CaO-Al2O3-MgO inclusions and MgO-Al2O3 inclusions as the core,with CaO-Al2O3 as thesecondary layer and CaS as the outermost layer.Regardless of under Al,CaSi,or the composite deoxidizer Al+CaSi conditions,no separate CaS inclusions or MnS inclusions are found.Besides,with an increase in the amount of deoxidizer added,the inclusion content in the steel significantly decreased,and the size of the inclusions became finer.

     

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