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选区激光熔化成形体育器械用铝合金的热处理与组织性能

Heat treatment and microstructure properties of selective laser melting aluminum alloy for sports equipment

  • 摘要: 采用扫描电子显微镜、硬度计和拉伸试验机等手段,研究了时效温度(100~400℃)和时效时间(0~24 h)对选区激光熔化(selective laser melting, SLM)成形体育器械用Al-7.8Si-2.58Mg-0.12Zr合金显微组织和力学性能的影响。结果表明,打印态以及100、150、200和300℃时效态SLM成形铝合金的物相都主要由α-Al、Si和Mg2Si相组成;150℃时效态与打印态SLM成形铝合金的显微形貌相似,基体组织中都可见网状和少量颗粒状共晶Si;时效温度升高至200℃及以上时,网状共晶Si组织发生分解,且随着时效温度升高,Si相颗粒会发生粗化与长大、数量减少。时效态SLM成形铝合金的显微硬度随着时效温度升高而先增大后减小,当时效温度为150℃时取得最大值(191.3 HV);时效温度150℃时,SLM成形铝合金的显微硬度会随着时效时间延长而先快速增大。随着时效时间从2 h延长至24 h,时效态SLM成形铝合金的抗拉强度、屈服强度先增后减,时效12 h时取得最大值,这主要与起第二相强化作用的Mg2Si相和Si颗粒存在形式有关。

     

    Abstract: 【Objective】 Selective laser melting(SLM)-fabricated aluminum alloys hold enormous application potential for the manufacture of aluminum alloy sports equipment, yet further refinement and expansion are still required in terms of process optimization, standardization and large-scale application.【Method】 The effects of aging temperature(100-400 ℃) and aging time(0-24 h) on the microstructure and mechanical properties of Al-7.8 Si-2.58 Mg-0.12 Zr alloy for SLM(selective laser melting) forming sports equipment were studied using scanning electron microscopy, hardness tester, and tensile testing machine. 【Result】 The phases of SLM formed aluminum alloys in the as printed and aged states at 100, 150, 200, and 300 ℃ are mainly composed of α-Al, Si and Mg2 Si phases; The microstructure of SLM formed aluminum alloys in the 150 ℃ aged and printed states is similar, with network like and a small amount of granular eutectic Si visible in the matrix structure; When the aging temperature rises to 200 ℃ or above, the network eutectic Si structure decomposes, and as the aging temperature increases, the Si phase particles coarsen, grow, and decrease in quantity. The microhardness of SLM formed aluminum alloy in aging state increases first and then decreases with the increase of aging temperature, and reaches its maximum value(191.3 HV) when the aging temperature is 150 ℃; At an aging temperature of 150 ℃, the microhardness of SLM formed aluminum alloy increases rapidly with the prolongation of aging time. As the aging time is extended from 2 to 24 h, the tensile strength and yield strength of SLM formed aluminum alloy in the aging state first increase and then decrease, reaching their maximum values at 12 h. This is mainly related to the form of Mg2 Si phase and Si particles that play a role in the second phase strengthening. 【Conclusion】 The Al-7.8 Si-2.58 Mg-0.12 Zr alloy for SLM formed sports equipment achieved maximum tensile strength and yield strength at an aging temperature of 150 ℃ and an aging time of 12 h, which increased by 12.21% and 12.81% respectively compared to the printed state. This can provide reference for optimizing the process parameters of SLM formed aluminum alloys and help promote the improvement of mechanical properties and application of Al-7.8 Si-2.58 Mg-0.12 Zr alloy for sports equipment.

     

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