富氢高炉的一维动力学模型验证与预测
Validation and prediction of one-dimensional kinetic model of hydrogen-enriched blast furnace
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摘要: 炼铁工序碳排放量占钢铁行业碳总排放量的70%以上,在“碳达峰”和“碳中和”战略驱动下,高炉富氢低碳转型已成为最主要的研究方向之一,它主要通过风口喷吹氢气或富氢气体,以氢代碳,来减少碳排放。基于高炉运行时的速率方程和控制方程建立高炉喷吹氢气的一维动力学模型,模拟氢气喷吹对冶炼状态的影响,并利用高炉实际运行数据进行验证,得到喷吹不同氢气量时高炉热储备区变化情况以及对不同氢气量间接还原度的影响。结果表明,随着氢气喷吹量的增加,热储备区平均温度由不喷吹时的1 052 K升高至喷吹100 m3/t氢气时的1 243 K,热储备区的上边缘向下移动0.1 m,下边缘向下移动1.5 m,高度增加1.4 m。炉内整体间接还原度有所提升,铁矿石的间接还原度从60.68%增加到70.65%。动力学模型与能质平衡模型的计算结果非常吻合,说明增加氢气喷吹量有利于间接还原发生,整体上还原速率不断加快,对进一步降低高温区直接还原耗碳起到了积极作用。研究结果对低碳高炉的数字化转型具有重要的理论价值,进而可推动钢铁行业低碳转型。氢气制备技术的突破,配合数字化模型来优化喷吹参数,富氢高炉工艺有望成为向“氢冶金”过渡时期的核心路径。Abstract: The carbon emissions from ironmaking process account for more than 70% of the steel industry. Driven by the "carbon peak" and "carbon neutrality", the hydrogen-enriched blast furnace(BF) has become a dominant research interest. Hydrogen or hydrogen-enriched gas is injected through the tuyere to replace partial carbon with hydrogen, so as to reduce carbon emissions. The one-dimensional kinetic model of hydrogen-enriched blast furnace was established based on the rate equations and control equations of blast furnace operation, and the effect of hydrogen injection on smelting behavior was simulated, while the industrial data of blast furnace were used to validate, and the influences of hydrogen injection rate on indirect reduction degree and the thermal reserve zone (TRZ) were investigated. It shows that with the increase of hydrogen injection rate, the average temperature in the TRZ increases from 1 052 K (without hydrogen injection) to 1 243 K (with hydrogen injection of 100 m3/t). Meanwhile, the upper and lower boundaries of TRZ moves down by 0.1 m and 1.5 m, respectively. Totally, the height of TRZ increases 1.4 m. The overall indirect reduction degree in the blast furnace is improved from 60.68% to 70.65%. The calculation results from the one-dimensional kinetic model and the energy-material balance model are in good agreement with each other, increasing the amount of hydrogen injection is conducive to the indirect reduction. On the whole, the reduction rate accelerates, further reducing the carbon consumption of direct reduction in the high temperature region. The result has vital theoretical value for digitization of the low-carbon blast furnace, further promoting the low-carbon transformation of steel industry. With the breakthrough of hydrogen preparation technology and the optimization of injection parameters with digital model, hydrogen-enriched BF process is expected to become the core path in the period of transition to "hydrogen metallurgy".
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