投审稿入口

热成形钢的研究进展:强韧化,抗氧化与抗氢脆

Progress of press hardening steels: strengthening and toughening, oxidation resistance and hydrogen embrittlement resistance

  • 摘要: 随着汽车工业对材料轻量化与安全性要求的不断提高,热成形钢因其优异的力学性能和良好的成形性已广泛应用于汽车关键结构件中。然而,当前热成形钢仍面临3大关键挑战,一是强度和韧性的协同优化问题,二是成形后表面的氧化问题,三是氢致脆性开裂问题,这制约了热成形钢进一步的推广应用。为应对上述挑战,近年来众多研究围绕合金成分设计与工艺优化两大技术路径展开深入探索。在强韧化方面,热成形淬火-配分钢和中锰钢等新体系通过调控残留奥氏体含量与分布,其强塑积提升至20 GPa·%以上,并显著改善了材料的韧性。在抗氧化方面,除经典的表面镀层技术外,新型的铬-硅合金化无镀层热成形钢也被开发出来;同时,快速加热和预氧化处理等新工艺也被证明可有效减轻成形过程中的表面氧化问题。在抗氢脆方面,许多研究致力于阐明氢与镀层、晶界、析出物和残留奥氏体等的相互作用机制,通过微合金化添加铌、钛等元素,细化组织并在钢中形成氢陷阱,降低可扩散氢含量。本文系统性综述了近期在热成形钢强韧化、抗氧化和抗氢脆3方面的研究进展,并重点从合金成分设计和工艺优化2大技术路径展开讨论。随着人工智能技术在材料成分设计与工艺参数优化中的应用逐步深入,以及厚规格热成形钢在结构件领域需求的增长,未来热成形钢将朝着多性能协同、智能化研发的方向持续发展。

     

    Abstract: With the increasing demand for lightweighting and safety in the automotive industry, press hardening steels have been widely used in key structural components of automobiles due to their excellent mechanical properties and formability. However, press hardening steels still face three key challenges at present. They are the trade-off between strength and toughness, surface oxidation after forming, and the hydrogen embrittlement. These challenges restrict the further promotion and application of press hardening steels. To address these challenges, numerous researchers have delved deeply into two major technical paths in recent years, alloy composition design and process optimization. In terms of strengthening and toughening, new techniques such as press hardening-quenching and partitioning steels and medium manganese steels have achieved a product of strength and ductility exceeding 20 GPa·% by regulating the content and distribution of retained austenite, and significantly improved the toughness at the same time. Regarding oxidation resistance, in addition to conventional surface coatings, Cr-Si alloyed uncoated press hardening steels have made a breakthrough. Meanwhile, new processes such as rapid heating and pre-oxidation have also been proven to effectively alleviate surface oxidation during the forming process. Concerning hydrogen embrittlement resistance, researchers have dedicated to clarifying the interaction mechanism between hydrogen and coatings, grain boundaries, precipitates, and retained austenite, etc. By adding microalloying elements such as Nb and Ti, the microstructure is refined and hydrogen traps are induced to reduce the content of diffusible hydrogen. This paper systematically reviews the recent progress in strengthening and toughening, oxidation resistance and hydrogen embrittlement resistance of press hardening steels, focusing on alloy composition design and process optimization. With the development of artificial intelligence and the increasing demand for heavy-gauge press hardening steels, press hardening steels will continue to advance in the direction of multi-performance collaboration as well as intelligent research and development in the future.

     

/

返回文章
返回