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焦炭结构演变对高炉透气性的影响分析及验证

Analysis and verification of impact of coke structure evolution on blast furnace permeability

  • 摘要: 焦炭作为高炉内唯一的骨架支柱,其劣化行为对高炉透气性有十分重要的影响。本文针对3种不同的工业焦炭,分别采用扫描电子显微镜-能谱仪(scanning electron microscopy-energy dispersive spectrometer,SEM-EDS)、压汞法及高温溶损-转鼓等试验方法和多孔介质理论分析了焦炭微观气孔结构演变及粒度的降解分布特征,量化了焦炭高温劣化的非均匀性,并进一步探讨了其与高炉透气性的潜在关联,最后通过空隙度及压差模拟试验验证了焦炭劣化非均匀性与高炉透气性的关系。结果表明,焦炭溶损后气孔壁被消耗、原先封闭的部分气孔逐渐开放,并促使微小孔隙相互贯通形成大孔,气孔数量明显增多,这一结构变化降低了反应气体向焦炭孔内的扩散阻力,导致气体浓度梯度逐渐减小、劣化非均匀性降低;由于初始孔结构特性不同,3种不同焦炭在溶损过程中的相对浓度梯度呈现Coke C>Coke B>Coke A的规律,浓度梯度越大,溶损反应越集中于焦炭表层,即焦炭劣化非均匀性越严重,因此,Coke C的劣化非均匀性最强,而Coke A的溶损过程更为均匀,对高炉透气性有利,这与Coke A在高炉实践生产中使用效果最佳完全相符;此外,压差和透气性模拟试验结果表明,透气性指数与焦炭反应后强度和劣化非均匀性指标之间均存在显著的统计相关性,这进一步验证了焦炭溶损的非均匀性对高炉透气性的重要影响。研究结果为通过焦化工艺合理调控焦炭气孔结构从而精准提升焦炭质量、保障高炉稳定运行提供了重要依据。

     

    Abstract: As the sole skeletal support in blast furnaces, the degradation behavior of coke exerts a crucial influence on blast furnace permeability. Three types of industrial cokes were selected as research objects. The evolutionary characteristics of coke microporous structure and the degradation distribution characteristics of particle size were analyzed via scanning electron microscopy-energy dispersive spectrometer (SEM-EDS), mercury intrusion porosimetry, high-temperature carbon loss-drum test and other experimental methods, combined with porous media theory. The heterogeneity of high-temperature coke degradation was quantified, and its potential correlation with blast furnace permeability was further explored. Finally, the relationship between coke degradation heterogeneity and blast furnace permeability was verified through porosity and pressure difference simulation tests.The results show that after the carbon loss reaction, the pore walls of coke are eroded, some originally closed pores are gradually opened, and the interconnection of micropores facilitates the formation of macropores, leading to a significant increase in the number of pores. This structural change reduces the diffusion resistance of reactive gas into coke pores, resulting in a gradual decrease in the gas concentration gradient and a reduction in degradation heterogeneity. Due to differences in initial pore structure characteristics, the relative concentration gradients of the three cokes during the carbon loss process follow the order of Coke C>Coke B>Coke A. A higher concentration gradient leads to a more concentrated carbon loss reaction on the coke surface, i.e., more severe coke degradation heterogeneity. Thus, Coke C exhibits the strongest degradation heterogeneity, while the carbon loss process of Coke A is more uniform, which is beneficial to blast furnace permeability. This finding is fully consistent with the optimal application performance of Coke A in actual blast furnace production. In addition, the results of pressure difference and permeability simulation tests indicate that there are significant statistical correlations between the permeability index and both the post-reaction coke strength and the degradation heterogeneity index, which further verifies the important influence of coke carbon loss heterogeneity on blast furnace permeability.The research results provide an important theoretical basis for the rational regulation of coke pore structure via coking processes, thereby accurately improving coke quality and ensuring the stable operation of blast furnaces.

     

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