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高炉喷吹焦炉煤气对煤粉燃烧及冶炼过程的影响

Effect of coke oven gas injection on pulverized coal combustion and metallurgical process in a blast furnace

  • 摘要: 高炉(blast furnace,BF)富氢喷吹是实现低碳冶金的关键技术路径,但现有数学模型常将煤粉燃烧率简化为定值,忽略富氢气体与煤粉混合喷吹时的竞争燃烧效应,导致对冶炼指标及碳排放的评估存在偏差。为准确评估喷吹焦炉煤气(coke oven gas,COG)对高炉冶炼的影响,本研究首先通过高温燃烧模拟试验,测定不同喷吹量下的煤粉燃烧率,并耦合高炉富氢喷吹数学模型,系统分析煤粉燃烧率变化对焦比、置换比、直接还原度、理论燃烧温度及碳排放等参数的影响规律。研究结果表明,随着焦炉煤气喷吹量从0增加至60 m3/t,煤粉燃烧率因竞争燃烧效应由72.0%降低至64.2%。受煤粉燃烧放热减少及氢还原反应吸热的影响,焦炭置换比呈加速下降趋势,由喷吹10 m3/t时的0.45降低至喷吹60 m3/t时的0.40。尽管如此,喷吹焦炉煤气仍能够改善冶炼指标,使直接还原度由0.454降低至0.387,焦比由377.5 kg/t降低至353.5 kg/t。在热制度方面,大规模喷吹焦炉煤气导致理论燃烧温度由2 207.7 ℃降低至2 085.7 ℃,炉顶煤气温度由197.37 ℃升高至213.87 ℃。为维持炉缸与炉顶热平衡稳定,构建出富氧率与喷吹量的协同操作窗口,在60 m3/t 喷吹量下需将富氧率调控为5.70%~13.19%。碳排放量化评估显示,富氢气体的间接还原作用在高炉碳减排过程中占据主导地位,竞争燃烧对碳减排的影响较小,由焦炉煤气化学还原作用带来的碳减排为31.2 kg/t,而因竞争燃烧造成的碳排放增加仅为0.5 kg/t。

     

    Abstract: Hydrogen-rich gas injection into the blast furnace (BF) is a key technological pathway for achieving low-carbon metallurgy. However, existing mathematical models often simplify the pulverized coal combustion rate as a constant value, neglecting the competitive combustion effect between the hydrogen-rich gas and pulverized coal during co-injection. This leads to deviations in the evaluation of smelting indices and carbon emissions. To accurately assess the impact of coke oven gas (COG) injection on the BF process, this study first determined the pulverized coal combustion rates under different injection volumes via high-temperature combustion simulation experiments. By coupling these experimental data with a hydrogen-rich blast furnace mathematical model, the effects of combustion rate variations on the coke ratio, coke replacement ratio, direct reduction degree, theoretical combustion temperature, and carbon emissions were systematically analyzed. The results indicate that as the COG injection volume increases from 0 to 60 m3/t, the pulverized coal combustion rate decreases from 72.0% to 64.2%. Constrained by the reduced heat release from coal combustion and the endothermic nature of the hydrogen reduction reaction, the coke replacement ratio shows an accelerated downward trend, dropping from 0.45 at 10 m3/t to 0.40 at 60 m3/t. Nevertheless, COG injection effectively improves smelting indices, reducing the direct reduction degree from 0.454 to 0.387 and the coke ratio from 377.5 kg/t to 353.5 kg/t. Regarding the thermal regime, large-scale COG injection causes the theoretical combustion temperature to decrease from 2 207.7 ℃ to 2 085.7 ℃, while the top gas temperature rises from 197.37 ℃ to 213.87 ℃. To maintain stable thermal equilibrium in the hearth and shaft, a coordinated operation window for the oxygen enrichment rate and injection volume was established. Under an injection volume of 60 m3/t, the oxygen enrichment rate must be adjusted to the range of 5.70%-13.19%. Quantitative evaluation of carbon emissions reveals that the indirect reduction effect of hydrogen-rich gas plays a dominant role in carbon reduction, while the impact of competitive combustion is minor. The carbon reduction attributed to the chemical reduction effect of COG is 31.2 kg/t, whereas the increase in carbon emissions caused by competitive combustion is only 0.5 kg/t.

     

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