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铬含量对Ni-Co系超高强船体钢组织和性能的影响

Effect of Cr content on microstructure and properties of Ni-Co ultra-high strength hull steel

  • 摘要: 合适的铬(Cr)含量可以使Ni-Co系超高强船体钢获得良好的强韧匹配,但其强韧化机制尚未明晰。本文通过扫描电镜(scanning electron microscope,SEM)、X射线衍射(X-ray diffraction,XRD)、物理化学相分析和透射电镜(transmission electron microscope,TEM)等方法,结合室温拉伸和低温冲击试验,研究了铬含量对Ni-Co系超高强船体钢微观组织、第二相析出行为和力学性能的影响。组织分析结果表明,试验钢的微观组织为回火马氏体和少量逆转变奥氏体。随铬含量的增加,试验钢的Ms(马氏体转变开始温度)点降低,奥氏体稳定性提升,且其含量增多。相分析和TEM结果表明,Ni-Co系钢中析出相主要为M2C相。铬含量对于第二相的尺寸具有较大影响。当铬质量分数为2%时(2Cr),M2C相与基体间的错配度低,使钢析出了大量尺寸小于5 nm的M2C相。当铬质量分数为3%时(3Cr),钢中发现较多尺寸超过200 nm的M2C相,表明其发生了明显的粗化。力学测试结果表明,1Cr(铬质量分数为1%)、2Cr和3Cr钢的屈服强度分别为1 317、1 258、1 137 MPa。铬的添加会降低碳在基体中的固溶度,促进纳米M2C相的析出。随铬含量的增加,固溶强化增量的降低超过了析出强化增量的提升,使钢的屈服强度逐渐减小。1Cr、2Cr和3Cr钢的-84 ℃冲击功分别为6、42、49 J。铬能改善Ni-Co系钢的低温韧性,一方面是因为钢中逆转变奥氏体的增加,对裂纹扩展的钝化作用增强;另一方面是由于铬含量的增加促进了与基体共格的纳米M2C相的析出,降低了应变累积与应力集中,有效抑制了裂纹萌生。此外,2Cr钢中较多的纳米M2C相和一定含量的奥氏体,使其具有良好的强韧性。

     

    Abstract: An appropriate Cr content can enable Ni-Co based ultra-high strength hull steel to achieve a good strength-toughness combination, but its strengthening and toughening mechanisms have not yet been fully elucidated. This study investigated the effects of Cr content on the microstructure,secondary phase precipitation behavior,and mechanical properties of Ni-Co based ultra-high strength hull steel using techniques including scanning electron microscope(SEM),X-ray diffraction(XRD),physical-chemical phase analysis,and transmission electron microscope(TEM),combined with room-temperature tensile and low-temperature impact tests. Microstructural analysis indicated that the microstructure of the test steel consists of tempered martensite and a small amount of reversed austenite. As the Cr content increased,the martensite start temperature(Ms) of the steel decreased,austenite stability improved, and its volume fraction increased. Phase analysis and TEM results reveals that the main precipitates in the Ni-Co steel are M₂C phases,and the Cr content has a significant impact on the size of the secondary phases. At 2%Cr,the low lattice mismatch between the M₂C phase and the matrix promotes the precipitation of a large number of M₂C phases smaller than 5 nm. At 3%Cr,numerous M₂C phases larger than 200 nm are observed,indicating significant coarsening. Mechanical test results demonstrate that the yield strengths of the 1Cr,2Cr,and 3Cr steels are 1 317,1 258, and 1 137 MPa,respectively. The addition of Cr reduces the solid solubility of C in the matrix,promoting the precipitation of nano-sized M₂C phases. With increasing Cr content,the decrease in the solid solution strengthening increment exceeds the increase in the precipitation strengthening increment,resulting in a gradual reduction in yield strength. The impact energies at -84 ℃ for the 1Cr,2Cr,and 3Cr steels are 6,42,and 49 J,respectively. Cr improves the low-temperature toughness of the Ni-Co steel primarily due to the increased reversed austenite content,which enhances crack blunting,and also because Cr promotes the precipitation of coherent nano-sized M₂C phases with the matrix, which reduces strain accumulation and stress concentration, thereby effectively suppressing crack initiation. The 2Cr steel,with its abundant nano-sized M₂C phases and a certain amount of austenite,exhibits a good combination of strength and toughness.

     

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