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增材制造合金钢耐腐蚀性研究进展

Research progress on the corrosion resistance of additive manufacturing alloy steels

  • 摘要: 增材制造技术以其优异的设计自由度和极高的材料利用率,已成为制备复杂结构合金钢的关键手段。然而,该技术固有的非平衡凝固特性(高冷却速率与强温度梯度)易诱发冶金缺陷和残余应力,显著影响成形件的致密度与成分均匀性,成形质量不良对增材制造合金钢的耐腐蚀性能有不利影响。本文系统回顾了金属增材制造技术的特点,综述了近年通过工艺窗口优化、合金成分设计及热处理制度改善孔隙率、显微组织和残余应力,从而延缓腐蚀进程的国内外研究进展。工艺参量直接影响冶金缺陷的类型与分布,锁定合适的工艺参量能减少孔隙缺陷,增强合金钢抗点蚀能力;通过原位合金化引入氮、铬、铜及稀土元素,能调控腐蚀产物形态并提升钝化膜稳定性来减缓腐蚀进程,从而提升耐腐蚀性;后热处理则有助于改善显微组织并释放残余应力,通过促进成分均匀性和调控碳化物分布进一步提升耐腐蚀性。本文指出了当前增材制造耐蚀合金钢领域面临的核心挑战,强调未来研究应聚焦于梳理“工艺-成分-组织-性能”之间的内在关联,建立跨尺度材料数据库与标准化评价准则,为发展高性能增材制造耐蚀合金钢提供理论依据与设计指导。

     

    Abstract: Additive manufacturing, owning to its excellent design freedom and extremely high material utilization, has become a key strategy to produce complex alloy steels. However, the non-equilibrium solidification characteristics (rapid cooling rate and strong temperature gradients), induces metallurgical defects and residual stress, which severely impacts the density and compositional uniformity of the components. Poor quality adversely affects the corrosion resistance of additive manufacturing alloy steel. This paper systematically reviews the characteristics of metal additive manufacturing and summarizes research progress related delaying corrosion process via process parameter optimization, chemical composition design, and heat treatment control to improve porosity, microstructure, and residual stress. Different process parameters directly influence the metallurgical defects. The porosity defects are avoided by adjusting process parameters, which improve pitting corrosion resistance of alloy steels. Introducing nitrogen, chromium, copper, and rare earth elements through in-situ alloying regulates corrosion product and enhances passivation film stability, thereby delaying corrosion process and improving corrosion resistance. Heat treatment improves microstructure and releases residual stresses, further enhancing corrosion resistance by promoting compositional uniformity and controlling carbide distribution. In this paper, the core challenges in the corrosion resistant of additive manufacturing alloy steels are pointed out. The relationships among "process-composition-microstructure-property" should be clarified. The multi-scale databases and standardized evaluation criteria should be established. This paper provides theoretical foundations and design guidance for developing additive manufacturing alloy steels with excellent corrosion resistant.

     

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