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钢铁流程碳链循环冶金研究及技术路线构建

Exploration and construction of carbon-loop technical route for low-carbon iron and steel processes

  • 摘要: 钢铁流程的CO2排放总量大、排放源分散,随排烟气温度波动大、CO2体积分数低、污染物组分复杂,多重因素导致钢铁流程中CO2捕集难度较大。对于钢铁行业拥有的10亿t级CO2总量,不仅是碳捕集存在困难,后续的CO2处置也是钢铁降碳亟待解决的难题。本文揭示了碳素流在钢铁冶炼过程中承担的燃料、还原剂、原料、工艺骨架多维功能属性及价态转换规律,分析了目前国内外碳捕集、利用及封存(carbon capture, utilization and storage,CCUS)技术的研发及应用现状,并结合中国未来产能布局、氢冶金发展的预测,创新性地提出了在极致减少碳的一次消耗的前提下,基于绿能驱动CO2转化循环利用的碳链循环的冶金技术理论观点,即将末端排放的CO2分离,在绿能作用下转化为还原介质,然后返回铁还原工序利用,部分替代源头的碳输入,实现低碳冶金的过程。本文重点构建了极限焦比下的CO2转化循环利用高炉能质流模型,并指出这是值得重视的基于中国资源禀赋及钢铁产业结构特征,适合钢铁产业走向碳中和的发展路径。

     

    Abstract: The steel industry emits a large amount of CO2 with dispersed emission sources. The flue gas containing CO2 has characteristics of temperature fluctuations, low CO2 volume fraction and complex pollutants, and this increases the difficulty in CO2 capture. For a total CO2 volume on the order of one billion tons, not only carbon capture but also the subsequent CO2 disposal remains a challenging issue that urgently needs to be addressed in steel decarbonization. This paper elaborated on the carbon flow pathways, the functional roles that carbon plays, i.e., fuel, reductant, and raw material, and the conversion reactions within the steel making process. Analysis and review were made on carbon capture,utilization and storage(CCUS) development and application at home and abroad in the steel industry. With overall consideration of the steel capacity projection, process structure trend and H2 direct reduced iron prospect, this paper proposed an innovative carbon-loop technical route for iron and steel metallurgy. It was given in the premise of reducing primary carbon sources and on the basis of green-power-driven CO2 conversion, the route works as follows, separating of CO2 at the terminal end, converting CO2 into reducing component by green power and recirculating into iron-reducing process. In this manner CO2-converted component replaced a portion of the primary carbon input, so that to realize the low carbon smelting process. The main point focuses on the building of mass and energy flow model for the blast furnace under extreme coke ratio condition, and we believe it is worthy of attention as carbon neutral pathway for China's steel industry on account of China resource endowment and steel industrial pattern.

     

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