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高炉喷吹生物质炭对冶炼参数及经济环境效益的影响分析

Analysis of effect of biochar injection in blast furnace on smelting parameters as well as economic and environmental benefits

  • 摘要: 钢铁工业正面临着极其迫切的脱碳任务,而生物质炭作为一种具有“碳中和”属性的可再生燃料,可推进高炉炼铁的深度脱碳。为探究高炉喷吹生物质炭的效果及经济效益,本文构建了考虑不同燃料理化特性及炉内反应分配的全炉能质平衡模型,对比分析了木块炭(Biochar A)与玉米秸秆炭(Biochar B)在0~40%喷吹比例下的冶炼参数变化及碳减排与经济性,并在0~20%喷吹比例下开展工业试验。模型结果表明,生物质炭的理化特性影响高炉热状态及燃料指标。随着喷吹比例增加至40%,喷吹Biochar A使高炉燃料比由509 kg/t降低至504 kg/t,理论燃烧温度由2 172 ℃升高至2 208 ℃,全炉热损失所占比例由5.92%降低至4.79%,且煤气利用率有所提升。而喷吹Biochar B能使理论燃烧温度升高至2 186 ℃,但会导致燃料比增加至516 kg/t,煤气利用率出现微降。工业试验结果显示,在10%~20%喷吹比例及短期运行条件下,高炉运行参数整体处于可接受范围内,燃料比维持在509~511 kg/t内,顶温、透气性指数、铁水温度及炉内气流分布(W)、炉况稳定性(Z)、气流均匀性(K)值均处于正常波动区间。在碳减排与经济性方面,基于模型边界及生物质炭“碳中性”假设,当喷吹比例为40%时,化石源CO2排放量最高由1 318 kg/t降低至1 252 kg/t,实现净减排66 kg/t,燃料成本(不含碳税折算)从839.11元/t升高至881.26元/t。引入碳税情景分析发现,当生物质炭价格为1.5 元/kg时,碳税最低为吨CO2 173.31 元可确保经济性。当碳税为吨CO2 0 元时,生物质采购价格最高为1.326 元/kg可确保经济性。

     

    Abstract: The steel industry faces an extremely urgent task of decarbonization. Biochar, as a renewable fuel with carbon neutral properties, can promote deep decarbonization in blast furnace ironmaking. To investigate the effectiveness and economic benefits of biochar injection in blast furnaces, this study developed a full furnace energy and mass balance model that considered the physicochemical properties of different fuels and the distribution of reactions within the furnace. The model compared and analyzed the changes in smelting parameters, carbon emission reduction, and economic performance when injecting wood chip biochar (Biochar A) and corn stalk biochar (Biochar B) at injection ratios ranging from 0 to 40%. Industrial trials were also conducted at injection ratios of 0 to 20%. The model results indicate that the physicochemical properties of biochar affect the thermal state of the blast furnace and fuel performance. As the injection ratio increases to 40%, injecting Biochar A reduces the fuel rate from 509 kg/t to 504 kg/t, increases the theoretical combustion temperature from 2 172 ℃ to 2 208 ℃, decreases the proportion of total furnace heat loss from 5.92% to 4.79%, and improves the gas utilization rate. Injecting Biochar B raises the theoretical combustion temperature to 2 186 ℃ but increases the fuel rate to 516 kg/t and causes a slight decrease in the gas utilization rate. The industrial trial results show that under short term operation with a injection of 10% to 20%, the blast furnace operating parameters remain within an acceptable range. The fuel rate is maintained between 509 kg/t and 511 kg/t, and parameters such as top temperature, permeability index, hot metal temperature, and the gas flow distribution in furnace (W), furnace condition stability (Z), and gas flow uniformity (K) values all fluctuate within normal ranges. In terms of carbon emission reduction and economic performance, based on the model boundaries and the carbon neutral assumption for biochar, at the injection ratio of 40%, fossil derived CO2 emissions are reduced from 1 318 kg/t to 1 252 kg/t, achieving a net reduction of 66 kg/t. The fuel cost (excluding carbon tax) increases from 839.11 yuan/t to 881.26 yuan/t. A scenario analysis incorporating a carbon tax reveals that when the price of biochar is 1.5 yuan/kg, a minimum carbon tax of 173.31 yuan/t (CO2) can ensure economic viability. When the carbon tax is 0 yuan/t (CO2), a maximum biochar purchase price of 1.326 yuan/kg can ensure economic viability.

     

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