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钢铁铸余渣返生产资源化利用研究进展

Research progress on resource utilization of steel casting residue in recycling to production process

  • 摘要: 针对炼钢与连铸过程中产生的铸余渣,本文系统梳理了其返回生产流程实现资源化利用的相关研究进展与工业实践,总结了铸余渣的来源、成分特征及其在不同炼钢工序中的回用方式与效果。综合分析表明,铸余渣整体以CaO-Al2O3-SiO2体系为主,具有较高碱度与一定冶金活性,可作为二次资源用于炼钢造渣及精炼过程。其中,热态铸余渣凭借其显热和熔融状态,更适宜直接返回转炉及精炼工序,有助于缩短成渣时间、降低石灰与白云石等熔剂消耗,并改善终渣结构。冷态尾渣经破碎、磁选及成分均化处理后,可稳定用于转炉、钢包精炼炉(ladle furnace,LF)、真空循环脱气精炼炉(Ruhrstahl-Heraeus degasser,RH)及中间包,替代部分造渣剂或覆盖剂,延续其冶金功能。总体而言,铸余渣返生产利用能在不明显增加能耗的前提下,实现熔剂节约、金属回收与间接减碳等综合效益。然而,其进一步推广应用仍面临成分波动大、冷态尾渣预处理工艺复杂以及跨工序适配性不足等问题。未来需通过源头分类、在线成分检测与分级回用等技术体系的完善,推动铸余渣在钢铁生产中的规模化与高效化资源利用。

     

    Abstract: For the casting residual slag generated during the steelmaking and continuous casting processes, this paper systematically reviews the relevant research progress and industrial practices of its recycling into the production processes for resource utilization, and summarizes the source, compositional characteristics of casting residual slag as well as its recycling methods and application effects in different steelmaking procedures. Comprehensive analysis shows that casting residual slag is dominated by the CaO-Al2O3-SiO2 system, featuring high basicity and certain metallurgical activity, thus being applicable as a secondary resource in steelmaking slag formation and refining processes. Among them, hot casting residual slag, by virtue of its sensible heat and molten state, is more suitable for direct recycling to converters and refining processes. This contributes to shortening the slag formation time, reducing the consumption of fluxes such as lime and dolomite, and improving the final slag structure. After undergoing crushing, magnetic separation and composition homogenization treatment, cold tailing slag can be stably applied in converters, ladle furnace, Ruhrstahl-Heraeus degasser and tundishes, replacing part of the slag-forming agents or covering agents and extending its metallurgical functions. In general, the recycling of casting residual slag into production processes can achieve comprehensive benefits such as flux saving, metal recovery and indirect carbon reduction without a significant increase in energy consumption. However, its further promotion and application are still confronted with challenges including large composition fluctuation, complex pretreatment processes for cold tailing slag and insufficient cross-process adaptability. In the future, it is necessary to improve the technical system consisting of source classification, on-line composition detection and graded recycling, so as to promote the large-scale and high-efficiency resource utilization of casting residual slag in iron and steel production.

     

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