投审稿入口

富氢气基还原条件下块矿低温还原粉化行为及机制

Low-temperature reduction disintegration behavior and mechanism of lump ore under hydrogen-rich gas-based reduction conditions

  • 摘要: 针对富氢气基还原过程中块矿配用可能引发的低温还原粉化(low-temperature reduction disintegration,LTD)问题,本文系统研究了还原温度(450~600 ℃)和还原气氛φ(H2)/φ(H2+CO)为0.6~1.0(体积分数比)对某典型铁矿块矿低温还原粉化行为的影响,并结合失重率、还原度、X射线衍射(X-ray diffraction,XRD)和显微结构表征揭示其粉化机制。结果表明,还原温度是控制块矿低温还原粉化行为的主导因素。在450~600 ℃内,随着还原温度升高,块矿失重率和还原度逐渐增加,但低温还原粉化性能显著恶化。以φ(H2)/φ(H2+CO)=0.6气氛为例,当温度由450 ℃升高至600 ℃时,LTD>6.3(低温还原粉化试验后粒径大于6.30 mm的试样质量占总质量的比例)由75.56%降低至20.16%,而恶性粉化指标LTD<0.5(低温还原粉化试验后粒径小于0.50 mm的试样质量占总质量的比例)由5.08%增加至23.05%。提高还原气体中H2比例可促进还原反应进行,并可能缩短赤铁矿与磁铁矿长期共存所导致的应力积累阶段,从而在一定程度上改善块矿粉化性能。微观结构分析表明,块矿结构致密、孔隙率低,赤铁矿向磁铁矿转变过程中产生的体积应力难以及时释放,导致裂纹沿晶界、孔隙和原生缺陷扩展。550 ℃下的动态演化结果进一步表明,块矿低温还原粉化过程可分为边缘优先还原、相变界面向内推进和裂纹贯通3个阶段。块矿低温粉化的本质源于致密基体限制了还原气向深部均匀渗透,形成了非均匀推进的相变前沿;相变诱导的应力集中与裂纹向心贯通,是导致块矿整体顺向开裂和结构失稳的因果机制。本研究可为富氢还原条件下块矿合理配用及炉料结构优化提供理论依据。

     

    Abstract: To address the potential issue of low-temperature reduction disintegration (LTD) caused by the use of lump ore in hydrogen rich gas-based reduction processes, this study systematically investigated the effects of reduction temperature (450-600 ℃) and reducing atmosphere φ(H2)/φ(H2+CO) is 0.6-1.0 on the low temperature reduction disintegration behavior of a typical iron ore lump. The disintegration mechanism was revealed by combining weight loss rate, reduction degree, X-ray diffraction (XRD), and microstructural characterization. The results show that the reduction temperature is the dominant factor controlling the low temperature reduction disintegration behavior of lump ore. Within the range of 450-600 ℃, as the reduction temperature increases, the weight loss rate and reduction degree of lump ore gradually increase, but the low temperature reduction disintegration performance significantly deteriorates. Taking the atmosphere with φ(H2)/φ(H2+CO)=0.6 as an example, when the temperature increases from 450 ℃ to 600 ℃, the LTD>6.3 index (the mass fraction of particles larger than 6.30 mm after the low temperature reduction disintegration test) decreases from 75.56% to 20.16%, while the severe disintegration index LTD<0.5 (the mass fraction of particles smaller than 0.50 mm after the test) sharply increases from 5.08% to 23.05%. Increasing the H2 proportion in the reducing gas promotes the reduction reaction and may shorten the stress accumulation stage caused by the prolonged coexistence of hematite and magnetite, thereby improving the disintegration performance of lump ore to a certain extent. Microstructural analysis indicates that the lump ore has a dense structure and low porosity, so the volumetric stress generated during the transformation from hematite to magnetite is difficult to release in time, leading to crack propagation along grain boundaries, pores, and pre existing defects. Dynamic evolution results at 550 ℃ further reveal that the low temperature reduction disintegration process of the lump ore can be divided into three stages, preferential reduction at the edge, inward advancement of the phase transformation interface, and crack penetration. The essence of low temperature reduction disintegration of lump ore lies in the dense matrix limiting the uniform penetration of reducing gas into the deep part, forming a non uniformly advancing phase transformation front. The stress concentration induced by phase transformation and the inward penetration of cracks constitute the fundamental causal mechanism leading to overall aligned cracking and structural instability of the lump ore. This study provides a theoretical basis for the rational use of lump ore and the optimization of burden structure under hydrogen rich reduction conditions.

     

/

返回文章
返回