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生物质重整高炉煤气制备合成气热力学分析

Thermodynamic analysis of syngas production from biomass-reformed blast furnace gas

  • 摘要: 高炉煤气(blast furnace gas, BFG)是钢铁长流程工艺中CO2排放的核心载体。为破解“双碳”目标下的降碳难题,本文提出生物质协同重整BFG新工艺,通过将CO2定向还原为CO,实现体系深度固碳与合成气热值的大幅提升。借助HSC Chemistry软件构建了重整过程热力学平衡模型,系统考察了气化温度、n(C)/n(CO2)(两者物质的量比)及系统压力对气化性能的影响。基于计算和能量衡算获得的工艺参数,确定了重整过程最佳效率。结果表明,适度提升气化温度与n(C)/n(CO2)可显著增强合成气质量,但参数过载将导致热损耗激增及转化效率受限,而体系压力的升高则对合成气产率起抑制作用。综合评估得出,在温度1 000 ℃、n(C)/n(CO2)=10∶3和压力0.1 MPa最佳条件下,体系的碳转化率与合成气产率均高达99%,产出合成气的高位热值达209.80 MJ/kmol,较原始高炉煤气提升了2.41倍。进一步的经济效益分析表明,每吨生物质与1 767.36 m3高炉煤气重整可产出3 314.55 m3的高热值合成气,能创造出5 668.59元的价值,展现出显著的工业应用潜力与经济可行性。本研究开发的生物质与高炉煤气协同重整技术,为钢铁企业副产气的高效、高值化利用及减污降碳提供了重要的理论支撑与工程借鉴。

     

    Abstract: Blast furnace gas (BFG) is the core carrier of CO2 emissions in the long steel production. To solve the carbon reduction problem under the "dual carbon" goals, this paper proposed a new process of biomass co-reforming BFG, which realized deep carbon fixation in the system and significant increase in the calorific value of syngas by directed the reduction of CO2 to CO. This paper used HSC Chemistry software to build a thermodynamic equilibrium model of the reforming process and systematically investigated the effects of gasification temperature, n(C)/n(CO2)(molar ratio), and system pressure on gasification performance. Based on the process parameters obtained from calculation and energy balance, the optimal efficiency of the reforming process was determined. The results show that moderately increasing the gasification temperature and n(C)/n(CO2) ratio can significantly improve the quality of syngas, but excessively elevating these operating parameters will lead to a sharp increase in heat loss and limited conversion efficiency, while increasing the system pressure has inhibitory effect on the syngas yield. Comprehensive evaluation shows that under the optimal conditions of 1 000 ℃, n(C)/n(CO2)= 10∶3, and 0.1 MPa, the carbon conversion rate and syngas yield of the system are both as high as 99%, and the higher heating value (HHV) of the produced syngas reaches 209.80 MJ/kmol, which is 2.41 times higher than that of the original blast furnace gas. Further economic benefit analysis shows that for every ton of biomass co-reformed with 1 767.36 m3 of blast furnace gas, 3 314.55 m3 of high-calorific value syngas can be produced, creating a value of 5 668.59 yuan, demonstrating significant industrial application potential and economic feasibility. The biomass and blast furnace gas co-reforming technology developed in this study provides important theoretical support and engineering reference for the efficient and high-value utilization of by-product gases in steel enterprises and for pollution reduction and carbon emission reduction.

     

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