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不同碱度高纯铁精矿球团富氢还原行为及其性能调控

Hydrogen-rich reduction behavior and performance regulation of high-purity iron concentrate pellets with different basicities

  • 摘要: 为了研究不同碱度高纯铁精矿球团富氢还原行为,并揭示液相性质对其还原膨胀的影响机制,本文采用微观结构表征及定量分析相结合的手段,系统研究了不同碱度(R为0.07~1.00)高纯铁精矿球团的微观结构演变规律及其富氢还原行为,并重点揭示了液相性质对不同碱度球团还原膨胀性能的影响机制。结果表明,随着球团碱度提升,球团内液相量逐渐增多,液相中钙、铁组分含量升高;在模拟希尔(Hojalata Y Lamina, HYL)法富氢气体条件下,不同球团还原度指数呈先降后升趋势,而还原膨胀指数呈相反变化趋势,在0.4~0.8碱度范围内,氧化球团还原过程中发生异常膨胀。低碱度(R=0.07)时,焙烧球团内液相生成量少,还原条件下金属铁以层状致密生长为主;中碱度(R=0.60)时,还原过程中玻璃相与铁氧化物发生动态“溶解-沉淀”行为,诱导形成多孔结构及丘状铁形貌,导致异常膨胀;高碱度(R=1.00)时,球团内液相量显著增加,冷却后形成连续玻璃相骨架,有效抑制了球团还原膨胀。在0.6碱度条件下,通过适当提高球团中SiO2和CaO含量,球团还原膨胀指数由48.92%显著降低至7.38%。通过调控不同碱度铁矿球团内液相成分和含量,可以显著改善球团还原膨胀性能,为高性能铁矿氧化球团的制备提供理论依据和技术支撑。

     

    Abstract: To investigate the hydrogen-rich reduction behavior of high-purity iron concentrate pellets with different basicities and to reveal the influence mechanism of liquid phase properties on reduction swelling, this study combined microstructural characterization with quantitative analysis to systematically examine the microstructure evolution and hydrogen-rich reduction behavior of high-purity iron concentrate pellets at different basicities (R=0.07-1.0). The mechanism by which liquid phase properties affect the reduction swelling performance of pellets with different basicities was emphatically revealed. The results show that as the pellet basicity increases, the amount of liquid phase within the pellets gradually increases, and the contents of Ca and Fe components in the liquid phase rise. Under simulated HYL(Hojalata Y Lamina) hydrogen-rich gas conditions, the reducibility index of different pellets first decreases and then increases, while the reduction swelling index shows the opposite trend. Abnormal swelling occurs during the reduction of roasted pellets in the basicity range of 0.4-0.8. At low basicity (R=0.07), the amount of liquid phase formed in the roasted pellets is small, and under reducing conditions, metallic iron primarily grows in a dense layered manner. At medium basicity (R=0.60), the dynamic "dissolution-precipitation" behavior occurred between the glass phase and iron oxides during reduction induces the formation of a porous structure and mound-like iron morphology, leading to abnormal swelling. At high basicity (R=1.00), the amount of liquid phase in the pellets increases significantly, forming a continuous glass phase skeleton after cooling, which effectively suppresses the reduction swelling of pellets. Under the condition of basicity of 0.6, by appropriately increasing the SiO2 and CaO contents in the pellets, the reduction swelling index significantly decreases from 48.92% to 7.38%. By controlling the composition and content of the liquid phase in iron ore pellets with different basicities, the reduction swelling performance of pellets can be significantly improved, providing a theoretical and technical basis for the preparation of high-performance iron oxide pellets.

     

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