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高碱金属烧结机头灰资源化利用研究进展与展望

Resource-oriented utilization of high-alkali metal sintering machine head dust: advances and outlook

  • 摘要: 烧结机头灰是钢铁冶金过程中产生的主要固体废弃物之一,其成分以铁为主,同时含有钾、钠、铅、氯等多种杂质元素。这些杂质来源各异,主要以氯盐形式团聚或附着于铁氧化物颗粒表面。目前,烧结机头灰处理已形成“水浸脱除碱金属-富铁渣返回烧结”耦合“浸出液净化脱杂-蒸发结晶提盐”的主流程,辅以物理选矿等手段提升富铁渣品质的综合回收工艺,并在部分钢铁企业获得应用。随着钢铁行业深化供给侧结构性改革,企业对碱金属深度脱除、流程简化、效益提升提出了更高要求。本文以烧结机头灰溯源为起点,在分析其物理化学特征的基础上,揭示了铁及关键杂质组分的形成与迁移转化规律,并据此归纳了现有回收工艺及创新改进方向。针对当前处理工艺存在的普适性差、流程冗长、回收效益低等瓶颈问题,提出了“靶向调控-分质处理-精细回收”的综合处置策略,以期为同类冶金粉尘的高效高值资源化利用提供理论依据与技术参考。

     

    Abstract: Sintering machine head dust is one of the major solid wastes generated during iron and steel metallurgical processes. Its composition is dominated by iron, while also containing various impurity elements such as potassium, sodium, lead, and chlorine. These impurities originate from diverse sources and predominantly exist in the form of chloride salts agglomerated on or adhered to the surface of iron oxide particles. Currently, the treatment of sintering machine head dust has evolved into an integrated recovery process system centered on a combined flowsheet of "water leaching for alkali metal removal-returning iron-rich residue to sintering" and "leachate purification for impurity removal-evaporative crystallization for alkali metal salt recovery", supplemented by physical beneficiation and other methods to improve the quality of iron-rich residue. This comprehensive recovery process has been applied in some iron and steel enterprises. With the deepening of supply-side structural reform in the steel industry, enterprises have raised higher demands for the thorough removal of alkali metals, process simplification, and benefit enhancement. This paper starts with the source tracing of sintering machine head dust, followed by analysis of its physicochemical characteristics, elucidation of the formation, migration and conversion mechanisms of iron and key impurity components, and accordingly summarizes the existing recovery processes and innovative improvement directions. In response to the bottleneck issues commonly encountered in current treatment processes, such as poor universality, lengthy process, and valuable-component loss, a comprehensive strategy of "targeted regulation-quality-based treatment-refined recycling" is proposed. It is expected to offer a theoretical basis and technical references for efficient and high-value resource-oriented utilization of similar ferrous metallurgical dusts.

     

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