投审稿入口

颗粒级配对Si3N4/Si2N2O-SiC材料抗热震性能的影响

Effect ofparticle size distribution on thermal shock resistance of Si3N4/Si2N2O-SiC composites

  • 摘要: 为满足隧道窑快烧工艺对碳化硅推板高抗热震性要求,本研究探究了粗颗粒碳化硅(SiC)含量对氮化物结合SiC材料微观结构与热机械性能的影响。在固定SiC总含量的前提下,制备了粗颗粒(3~5 mm)SiC系列试样(质量分数分别为0、5%、10%和15%)。采用X射线衍射、压汞法、三点弯曲法、单边切口梁法及热膨胀仪等手段,系统表征了样品的物相组成、孔隙结构、抗折强度、弹性模量、断裂韧性及线膨胀系数。同时,通过在1 350 ℃下水冷循环5次后材料的抗折强度与弹性模量保持率定量评价材料的抗热震性能。结果表明,粗SiC颗粒含量显著影响氮化物结合相的生成与材料微观结构。当粗颗粒质量分数为5%时,有助于形成合理的孔径分布和连续的氮化物网络;而质量分数达到或超过10%时,则会抑制氮化反应,导致结构劣化。含5%(质量分数)粗SiC的样品表现出最优的综合性能,其热震后残余抗折强度最高(67 MPa),抗折强度保持率和弹性模量保持率分别为16%和24.8%。该样品同时具有较低的线膨胀系数(4.1×10-6-1)和较高的断裂韧性(6.38 MPa·m1/2)。因此认为,引入5%(质量分数)的粗SiC颗粒可实现材料强度与韧性的最优匹配,其抗热震性的提升归因于低线膨胀系数、高断裂韧性及粗颗粒引发的裂纹钉扎效应的协同作用。

     

    Abstract: To meet the high thermal shock resistance requirements of silicon carbide (SiC) pusher plates used in rapid-firing tunnel kilns,the effect of coarse SiC particle content on the microstructure and thermomechanical properties of nitride-bonded SiC composites was investigated. Under a fixed total SiC content, specimens with varying mass fractions (0, 5%, 10% and 15%) of coarse SiC particles (3-5 mm) were prepared. The phase composition, pore structure, flexural strength, elastic modulus, fracture toughness and thermal expansion coefficient were systematically characterized using X-ray diffraction, mercury intrusion porosimetry, three-point bending tests, the single-edge notched beam method and dilatometry. Thermal shock resistance was quantitatively evaluated by measuring the retention rates of flexural strength and elastic modulus after five thermal cycles (water quenching from 1 350 ℃ to room temperature). The results indicated that the coarse SiC particle content significantly influenced the formation of the nitride bonding phase and the resulting microstructure. An optimal content of mass fraction of 5% coarse particles promoted a favorable pore size distribution and a continuous nitride network, whereas excessive coarse particle mass fraction (≥10%) inhibited the nitridation reaction, leading to microstructural degradation. The specimen containing 5%(mass fraction) coarse SiC exhibited the best overall performance, with the highest residual flexural strength (67 MPa) after thermal shock and retention rates of flexural strength and elastic modulus of 16% and 24.8%, respectively. This specimen also demonstrated a low thermal expansion coefficient (4.1×10-6-1) and high fracture toughness (6.38 MPa·m1/2). It was concluded that the incorporation of 5%(mass fraction) coarse SiC particles achieved an optimal balance between strength and toughness. The enhanced thermal shock resistance was attributed to the synergistic effects of a low thermal expansion coefficient, high fracture toughness and effective crack pinning by the coarse particles.

     

/

返回文章
返回