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养护时间对水合氧化铝结合浇注料强度的影响

Effect of curing time on strength of hydratable alumina bonded castables

  • 摘要: 为探明水合氧化铝结合浇注料的最短有效养护时间,本文研究了在温度为20 ℃、相对湿度为40%时不同养护时间(4、6、12、18、24、48、72 h)对水合氧化铝结合刚玉质浇注料脱模强度和干燥强度的影响。结果表明,在养护前期(4~18 h),水合氧化铝水化程度增加,相互交叉的网络状水化产物勃母石(β-AlOOH)和拜耳石(β-Al(OH)3)含量显著增加,使脱模强度持续提高,养护时间为18 h时即可满足工业脱模强度要求;当养护时间从18 h延长到72 h,水合氧化铝水化产物在其颗粒表面渐渐形成了致密覆盖层,使得水合氧化铝与水的接触面积变小,抑制了水化反应继续发生,延长养护时间对水化进程的促进作用很小,水化产物形貌无变化,其数量仅微量增加,脱模强度变化不大。水合氧化铝结合浇注料经不同时间养护后,再经过110 ℃干燥24 h,养护阶段未水化的水合氧化铝进一步水化,同时水化程度低的水合氧化铝在干燥过程中发生了更大程度的再水化,使得干燥后水化程度最大化,水化产物量区别不大,显微形貌相同,导致干燥强度变化不大。因此,水合氧化铝结合浇注料养护18 h达到脱模强度后直接进干燥工序,可提高生产效率。

     

    Abstract: To investigate the shortest effective curing time of hydratable alumina-bonded castables, the effect of curing duration (4, 6, 12, 18, 24, 48 and 72 h) on the demoulding and drying strengths of the castables at 20 ℃ and 40% was studied. The results show that, during the early curing stage (4-18 h), the hydration degree of hydratable alumina increases. The amount of interlaced network-like hydration products boehmite (β-AlOOH) and bayerite (β-Al(OH)3) also increases significantly. As a result, the demoulding strength rises continuously, meeting the industrial demoulding strength requirement after 18 h.When the curing time is prolonged from 18 h to 72 h, the newly formed hydration products gradually create a dense covering layer on the surfaces of hydratable alumina particles. This reduces the contact area between hydratable alumina and water, thereby inhibiting further hydration reaction. Therefore, additional curing time contributes little to promoting the hydration process. The morphology of the hydration products remains unchanged, and their amount increases only slightly. Thus, the demoulding strength of castables changes little. After different curing time, the castables were dried at 110 ℃ for 24 h. During drying, the unhydrated hydratable alumina from the curing stage undergoes further hydration. Moreover, the hydratable alumina with lower hydration degree undergoes greater rehydration during drying, maximizing the hydration degree after drying. The amounts of hydration products show little difference. Their micro-morphologies are also identical. Therefore, the drying strength of castables cured for different time changes little.Hence, after curing for 18 h to reach the demoulding strength, hydratable alumina-bonded castables can be directly transferred to the drying process to improve production efficiency.

     

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