投审稿入口

微量Cr对16 MnNiV小口径无缝钢管组织性能的影响机制

Influence mechanism of trace chromium on microstructure and properties of 16MnNiV small-diameter seamless steel pipes

  • 摘要: 高压共轨系统技术的快速发展与喷射压力的持续提升,对更高强度等级的高压油管材料提出了迫切需求。为此,在16MnNiV小口径无缝钢管用钢中添加质量分数为0.2%的Cr元素,成功制备出外径8 mm、内径3.6 mm的冷拔小口径无缝钢管,其抗拉强度为972 MPa,屈服强度为950 MPa,断后伸长率为15%。采用扫描电镜(SEM)、电子背散射衍射(EBSD)及透射电镜(TEM)对冷拔及热处理后的试样进行表征。结果表明,添加质量分数为0.2%的Cr元素细化了珠光体片层间距,其最大比例区间由110~130 nm缩小至70~90 nm,同时提高了冷拔过程中珠光体的稳定性。结合Thermo-Calc 2023a热力学计算与试验结果,Cr的添加降低了渗碳体及VC相析出驱动力的绝对值,抑制了二者析出,进而减少了C元素的脱溶。此外,Cr加入VC形成(V,Cr)C,使界面能从0.594 J/m2增至0.646 J/m2,有利于VC颗粒细化。强化机制定量计算表明,添加质量分数为0.2% Cr元素的主要强化贡献依次为固溶强化(204.7 MPa)、位错强化(191.2 MPa)和沉淀强化(103.3 MPa)。

     

    Abstract: The rapid development of high-pressure common-rail system technology and the continuous increase in injection pressure have created an urgent demand for high-pressure fuel pipe materials with higher strength grades. To address this need, 0.2% Cr (mass fraction) was added to the steel used for 16MnNiV small-diameter seamless steel tubes, and cold-drawn small-diameter seamless steel pipes with an outer diameter of 8 mm and an inner diameter of 3.6 mm were successfully fabricated. The resulting tubes exhibit a tensile strength of 972 MPa, a yield strength of 950 MPa, and an elongation after fracture of 15%. Scanning electron microscopy, electron backscatter diffraction, and transmission electron microscopy were employed to characterize the specimens after cold drawing and subsequent heat treatment. The results show that the addition of 0.2% Cr refines the pearlite interlamellar spacing, shifting its maximum proportion interval from 110-130 nm to 70-90 nm, while also enhancing the stability of pearlite during cold drawing. Combined with Thermo-Calc 2023a thermodynamic calculations and experimental results, the addition of Cr reduces the absolute value of the driving force for precipitation of cementite and VC, thereby suppressing their precipitation and consequently decreasing the desolvation of C. Furthermore, Cr doping into VC to form (V,Cr)C increases the interfacial energy from 0.594 to 0.646 J/m2, which facilitates the refinement of VC particles. Quantitative calculations of the strengthening mechanisms indicate that the dominant contributions from the addition of 0.2% Cr are, in descending order, solid-solution strengthening (204.7 MPa), dislocation strengthening (191.2 MPa), and precipitation strengthening (103.3 MPa).

     

/

返回文章
返回