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镍基化学复合镀研究进展

Research progress in nickel-based chemical composite plating

  • 摘要: 近年来,化学镀技术在多种基材表面构建复合镀层的研究日益增多,尤其是镍基复合镀层,因其在力学、电学、磁学及光学性能方面的显著提升,成为材料表面工程领域的研究热点。与传统的纯金属或合金镀层相比,复合镀层通过引入微米级或纳米级的增强颗粒,可以显著改善基体材料的综合性能,从而被广泛应用于航空航天、汽车、电子、机械及其他工业领域。镍基复合镀层通常采用化学镀方法,借助自催化还原反应将金属、合金或纳米颗粒沉积于基材表面。此类镀层不仅能够提高耐腐蚀性、耐磨性及抗氧化性,还能在一定程度上改善材料的抗冲蚀性及自润滑性能。本文系统综述了近年来在镍基化学复合镀方面的研究进展,重点探讨了镍基复合镀层的沉积机制、制备工艺及其性能特点,特别是纳米颗粒在复合镀层中的作用机理。同时,还展望了镍基复合镀层在未来功能化方向的发展趋势,探讨了该技术在高性能表面涂层、绿色制造及新兴技术中的应用潜力。研究表明,随着纳米技术的发展,镍基复合镀层在多个领域中具备了广泛的应用前景,特别是在要求高耐磨、耐腐蚀及自润滑的领域,镍基复合镀层将发挥更大的作用。

     

    Abstract: In recent years, research on constructing composite coatings on the surface of various substrates by electroless plating technology has been increasing day by day. Nickel-based composite coatings, in particular, have become a research hotspot in the field of material surface engineering due to their significant improvements in mechanical, electrical, magnetic and optical properties. Compared with traditional pure metal or alloy coatings, composite coatings can significantly improve the comprehensive properties of matrix materials by introducing micro-scale or nano-scale reinforced particles, which were widely used in aerospace, automotive, electronics, machinery and other industrial fields. Nickel-based composite coatings are usually prepared by electroless plating method, in which metals, alloys or nano-particles are deposited on the substrate surface through autocatalytic reduction reaction. Such coatings can not only improve corrosion resistance, wear resistance and oxidation resistance, but also enhance the erosion resistance and self-lubricating properties of materials to a certain extent. This paper systematically reviews the recent research progress in nickel-based electroless composite plating, focusing on the deposition mechanism, preparation process and performance characteristics of nickel-based composite coatings, especially the action mechanism of nano-particles in composite coatings. Meanwhile, the future development trend of nickel-based composite coatings in the functional direction is prospected, and the application potential of this technology in high-performance surface coatings, green manufacturing and emerging technologies is discussed. Research shows that with the development of nanotechnology, nickel-based composite coatings have broad application prospects in many fields, and will play a more important role especially in the fields requiring high wear resistance, corrosion resistance and self-lubrication.

     

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