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冷轧热镀锌板表面线状缺陷成因分析

Analysis of the causes of linear surface defects on cold-rolled hot-dip galvanized steel sheets

  • 摘要: 针对某热镀锌产线出现的表面线状缺陷,采用光学显微镜(OM)、扫描电镜(SEM)及能谱仪(EDS)系统地研究了缺陷在热镀锌板、脱锌基板和冷硬板中的微观形貌及化学成分,明确了其产生原因。结果表明:线状缺陷的形成原因可归结为炼钢工序遗传的氧化物夹杂。在轧制过程中,随着金属基体发生塑性变形,夹杂物逐渐靠近带钢表面。在带钢拉应力和轧制压应力的共同作用下,夹杂物周围的基体发生破裂,形成微裂纹。这些微裂纹扩展并延伸至带钢表面,导致部分夹杂物裸露于表面。裸露的夹杂物和破裂处的粗糙表面,一方面影响锌液在凝固前的正常回流,造成锌液滞留与局部增厚,另一方面为锌液凝固提供额外的形核点,造成局部细小锌结晶的形成。这种微观结构的不均匀性会改变产品表面对光线的反射作用,进而在宏观表面形成可见的线状缺陷。通过降低转炉终点氧含量、延长精炼软吹时间等改进措施,提高了钢水纯净度,并将B类、D类粗系夹杂物评级控制在1.5级以下,薄规格冷轧产品的原料内部夹杂物控制在1.0级以下,冷轧产品夹杂缺陷发生率由2.05%降至0.6%。

     

    Abstract: In view of the surface linear defects in a hot-dip galvanizing production line, the microscopic morphology and chemical composition of the defects in hot-dip galvanized sheets, dezincification substrates and cold-hard plates were systematically studied by optical microscopy(OM), scanning electron microscope(SEM) and energy dispersive spectrometer(EDS), and the causes were clarified. The results show that the cause of linear defects can be attributed to the inherited oxide inclusions in the steelmaking process. During the rolling process, as the metal matrix undergoes plastic deformation, the inclusions gradually approach the surface of the strip. Under the combined action of strip tensile stress and rolling compressive stress, the matrix around the inclusion cracks, forming microcracks. These microcracks propagate and extend to the strip surface, resulting in some inclusions being exposed to the surface. On the one hand, the exposed inclusions and the rough surface of the fractured place affect the normal reflux of the molten zinc before solidification, resulting in the retention and local thickening of the molten zinc, and on the other hand, provide additional nucleation points for the solidification of the molten zinc, resulting in the formation of local fine zinc crystals. This inhomogeneity of the microstructure can alter the light reflection properties of the product surface, resulting in visible linear defects on the macroscopic surface. Through improvement measures such as reducing the oxygen content at the end of the converter and extending the refining soft blowing time, the purity of the molten steel was improved, and the grades of Class B and Class D coarse inclusions were controlled below 1.5 grade(the internal inclusions of thin cold-rolled products were controlled below grade 1.0), so that the incidence of inclusion defects in cold-rolled products was reduced from 2.05% to 0.6%.

     

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