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RE6(Fe,Ga)14相对RE-Fe-Ga-B烧结磁体抗腐蚀性能的影响规律

Effect of the RE6(Fe,Ga)14 intergranular phase on the corrosion resistance of RE-Fe-B sintered magnets

  • 摘要: 四方型RE6(Fe,Ga)14相作为“高Ga低B”永磁材料中的特征晶界相,有效提高了无重稀土钕铁硼烧结磁体的矫顽力,但该相对磁体抗腐蚀性能的影响仍缺乏研究。通过调控Nd-Dy-Fe-Ga-B磁体中Ga和B元素含量,制备了2种不同晶界相组成的烧结磁体,对比了二者磁性能及抗腐蚀性能的差异,并重点分析了RE6(Fe,Ga)14晶界相的腐蚀行为。研究发现,在w(Ga)=0.5%,w(B)=0.9%的回火态磁体中形成大量的RE6(Fe,Ga)14晶界相,相较于传统富稀土晶界相为主的w(Ga)=0.1%,w(B)=1.0%磁体来说,前者拥有更高的矫顽力及更强的抗腐蚀性能。原位腐蚀观察进一步证实,RE6(Fe,Ga)14相可有效减缓烧结磁体晶界的腐蚀进程,为高综合服役性能的烧结钕铁硼磁体设计提供了重要参考。

     

    Abstract: As the characteristic grain boundary phase of the “Ga-rich/B-poor” Nd-Fe-B sintered permanent magnets, the tetragonal RE6(Fe,Ga)14 intergranular phase enhances the coercivity via enhanced decoupling capability to isolate the adjacent RE2Fe14B matrix phase, hence attracting widespread research attention. However, the influence of RE6(Fe,Ga)14 phase on the corrosion resistance still remains unexplored. In this work, two Nd-Dy-Fe-Ga-B sintered magnets dominated by different intergranular phases were prepared and compared by adjusting the Ga and B contents. Compared to the magnet with w(Ga)=0.1% and w(B)=1% dominated by the conventional RE-rich intergranular phase, a substantial amount of RE6(Fe,Ga)14 intergranular phase was introduced in the annealed magnet with w(Ga)=0.5% and w(B)=0.9%, yielding higher coercivity and corrosion resistance. In-situ corrosion experiments further confirmed that the RE6(Fe,Ga)14 intergranular phase effectively mitigates the corrosion process, offering a promising pathway for simultaneously improved magnetic and anti-corrosion performance of RE-Fe-B sintered magnets.

     

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