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低温固化树脂基导电铜浆的制备及性能

Preparation and properties of low temperature curing resin-based conductive copper paste

  • 摘要: 以酚醛树脂和环氧树脂为基体,铜粉为导电填料,通过磁力搅拌和低温固化制备了两种树脂基固化导电铜浆,并探究了固化工艺参数及铜粉含量对其导电性能的影响。实验结果表明,酚醛树脂基固化导电铜浆(PF-Cu)和环氧树脂基固化导电铜浆(EP-Cu)的最佳固化条件分别为180℃/60 min和250℃/150 min,其电阻率分别可达到11.4×10-4、2.14×10-4Ω·cm。铜粉含量显著影响固化导电铜浆的导电性能。EP-Cu因更高固化收缩率表现出更优导电性,铜粉质量分数70%渗流阈值时电阻率为2.18×10-3Ω·cm。微观形貌分析表明,EP-Cu更易通过固化收缩促进铜颗粒紧密接触,形成稳定的导电通路。本研究为低成本、高性能低温导电浆料的开发提供了理论和实验依据。

     

    Abstract: Through magnetic stirring and low-temperature curing,two types of resin-based cured conductive copper pastes were fabricated using phenolic resin and epoxy resin as matrices with copper powder as conductive filler. The effects of curing parameters and copper powder content on their electrical conductivity were systematically investigated. Experimental results demonstrate that the optimal curing conditions for phenolic resin-based copper paste(PF-Cu) and epoxy resin-based copper paste(EP-Cu) are 180 ℃ for 60 min and 250 ℃ for 150 min,respectively,achieving resistivities of 11. 4 × 10-4Ω·cm and 2. 14 × 10-4Ω·cm. Due to its higher curing shrinkage,copper powder content significantly influences the electrical conductivity,with EP-Cu exhibiting superior conductivity. When the mass fraction of copper powder is 70%,the resistivity is 2. 18 × 10-3Ω·cm. Microstructural analysis reveals that EP-Cu facilitates tighter copper particle contacts through curing-induced shrinkage,forming stable conductive pathways. This study provides theoretical and experimental foundations for developing cost-effective,high-performance conductive pastes with low-temperature processing requirements.

     

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