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TiC-W-Mo增强富铁镍基耐磨合金涂层的组织与性能

Microstructure and properties of TiC-W-Mo reinforced Fe-Ni based wear resistant alloy coating

  • 摘要: 为增强富铁镍基合金涂层的性能,采用等离子熔覆(PTA)技术,在45钢表面上制备了FeNi、FeNi/TiC和FeNiWMo/TiC 3种富铁镍基耐磨合金涂层,并针对涂层的物相、显微组织、显微硬度和磨损性能等特征展开分析。熔覆结果表明,3种涂层与母材均具有良好的冶金结合。涂层物相组成主要为γ-(Ni,Fe)、M23C6、M7C3和TiC,加入W和Mo元素后,涂层的相结构并未改变。在FeNi/TiC涂层中,TiC未完全熔化尺寸粗大,少量初生TiC会在γ-(Ni,Fe)相的晶界处发生团聚。FeNiWMo/TiC涂层中TiC尺寸明显细化,碎片状TiC明显增多,初生TiC分布更均匀,W和Mo元素主要富集在TiC周围,阻止TiC的长大和偏聚。FeNi涂层的平均硬度为588HV0.5,而FeNi/TiC涂层的硬度达到了1 032HV0.5,说明TiC的加入使涂层的硬度有较大的提升,但是其耐磨性却有所降低。FeNiWMo/TiC涂层硬度达到了1 085HV0.5,其耐磨性是FeNi涂层的9.6倍,FeNiWMo/TiC涂层摩擦磨损过程中也表现出更优异的性能。

     

    Abstract: To enhance the performance of iron-rich nickel based alloy coatings,the plasma cladding(PTA) technique was employed to fabricate iron-rich nickel-based wear resistant alloy coatings,namely FeNi,FeNi/TiC,and FeNiWMo/TiC,on 45 steel substrates. The phase composition,microstructure,microhardness,and wear resistance of the coatings were systematically investigated. The results revealed that all three coatings exhibited excellent metallurgical bonding with the substrate. The primary phases identified in the coatings were γ-(Ni,Fe),M23C6,M7 C3 and TiC. Notably,the incorporation of W and Mo did not alter the phase structure of the coatings. In the FeNi/TiC coating,TiC particles were predominantly large due to incomplete melting,with some primary TiC agglomerating at the grain boundaries of the γ-(Ni,Fe) phase. In contrast,the FeNiWMo/TiC coating displayed a significant refinement in TiC size,with a marked increase in fragmented TiC particles and a more uniform distribution of primary TiC. The W and Mo elements were found to be enriched around TiC,effectively inhibiting its growth and segregation. The average microhardness of the FeNi coating was measured at 588 HV0. 5,while the FeNi/TiC coating exhi-bited a substantial increase to 1 032 HV0. 5,demonstrating the significant hardening effect of TiC,but its wear resistance is reduced. In comparison,the FeNiWMo/TiC coating achieved a hardness of 1085 HV0. 5and exhibited a wear resistance 9. 6 times higher than that of the FeNi coating,underscoring its superior performance in friction and wear applications.

     

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