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氢环境对L245管线钢氢脆特性的影响

Effect of hydrogen environment on hydrogen embrittlement characteristics of L245 pipeline steel

  • 摘要: 研究氢气环境对L245管线钢力学性能、疲劳裂纹扩展速率、断裂韧性及氢脆机制的影响。研究结果表明,随着环境中氢气浓度的增加,L245钢的伸长率和断面收缩率显著降低,氢脆敏感性增大,抗拉强度和屈服强度无明显变化;含氢环境显著降低钢的裂纹扩展门槛值,提升裂纹扩展速率对应力强度因子范围的敏感度;氢气浓度增加使钢的断裂韧性逐渐降低、脆性增加。微观裂纹扩展规律显示,未充氢试样主要呈穿晶开裂,充氢试样呈穿晶与沿晶混合开裂,且裂纹扩展方向与拉伸方向约呈90°。氢脆机制分析表明,氢气分子先通过物理吸附附着于钢表面,在铁原子催化下解离成氢原子,以间隙扩散方式渗入钢中,在铁素体等晶粒处聚集,或在晶界、位错等缺陷处偏聚,使裂纹扩展方式从单一穿晶转变为穿晶与沿晶混合开裂。低氢浓度(小于10%)时,裂纹主要在铁素体晶粒内部扩展,表现为穿晶断裂;高氢浓度(大于20%)时,氢原子在晶界处显著偏聚,削弱晶界强度,提高裂纹沿晶界扩展比例。

     

    Abstract: Investigated the effect of hydrogen environment on the mechanical properties, fatigue crack growth rate, fracture toughness, and hydrogen embrittlement mechanism of L245 pipeline steel. The results show that with the increase of hydrogen concentration in the environment, the elongation and reduction of area of L245 steel decrease significantly, the hydrogen embrittlement sensitivity increases, while the tensile strength and yield strength remained almost unchanged. Hydrogen environment significantly reduces the crack growth threshold of the steel and increases the sensitivity of crack growth rate to the stress intensity factor range. The increase in hydrogen concentration gradually reduces the fracture toughness of the steel and increases its brittleness. The microscopic crack growth patterns showed that cracks in the non-hydrogen-charged specimens mainly exhibit transgranular cracking, while those in the hydrogen-charged specimens showe a mixture of transgranular and intergranular crac-king, with the crack growth direction at approximately 90° to the tensile direction. The analysis of hydrogen embrittlement mechanism shows that hydrogen molecules first physically adsorb onto the steel surface and dissociate into hydrogen atoms under the catalysis of iron atoms, which then diffuse into the steel matrix in an interstitial manner. These hydrogen atoms tend to aggregate at ferrite grains or segregate at grain boundaries and dislocations, changing the crack growth mode from single transgranular cracking to a mixture of transgranular and intergranular cracking. At low hydrogen concentration (less than 10%), cracks mainly propagate within ferrite grains, showing transgranular fracture.At high hydrogen concentration (greater than 20%), hydrogen atoms significantly segregate at grain boundaries, weakening the grain boundary strength and increasing the proportion of cracks propagating along grain boundaries.

     

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