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某锂云母浮选尾矿中石英及长石综合回收试验研究

Experimental Study on Comprehensive Recovery of Quartz and Feldspar From a Lepidolite Flotation Tailings

  • 摘要: 为实现锂云母浮选尾矿中石英与长石的绿色高效综合回收,本研究以江西某锂云母浮选尾矿为对象,系统开展工艺矿物学分析与无氟弱酸浮选试验。工艺矿物学分析表明,该尾矿SiO2含量为77.1%,Na2O+K2O含量为6.9%,其中石英、钠长石和钾长石占比分别为35.3%、44.5%和17.8%,石英与长石总占比超过97%,具备较高的综合回收价值。浮选试验结果表明,采用自主研发的阳离子捕收剂WIT-1,在磨矿细度为-0.074 mm占50%、矿浆pH值为4.5、WIT-1用量2.4 kg/t、六偏磷酸钠用量2.2 kg/t的条件下,经1粗7扫反浮选流程,可获得SiO2品位为99.8%的高纯石英产品,以及Na2O+K2O品位高于9%的长石产品。该方法有效避免了传统氢氟酸活化法和强酸性浮选法带来的设备腐蚀与环境污染问题,为锂云母浮选尾矿的绿色高效利用提供了可行的技术路径。

     

    Abstract: To achieve the green and efficient comprehensive recovery of quartz and feldspar from lepidolite flotation tailings,this study systematically conducted process mineralogical analysis and fluorine-free weak-acid flotation tests on a lepidolite flotation tailing sample from Jiangxi Province. Process mineralogical analysis shows that the tailings contain 77. 1% SiO2 and 6. 9% Na2O+K2O,with quartz,albite,and potassium feldspar accounting for 35. 3%,44. 5%,and 17. 8%,respectively. The total proportion of quartz and feldspar exceeds 97%,indicating high comprehensive recovery value. Flotation test results demonstrate that using the self-developed cationic collector WIT-1 under the conditions of a grinding fineness of-0. 074 mm accounting for 50%,pulp pH of 4. 5,WIT-1 dosage of 2. 4 kg/t,and sodium hexametaphosphate dosage of 2. 2 kg/t,a one-stage rougher and seven-stage scavenger reverse flotation circuit can yield a high-purity quartz product with a SiO2 grade of 99. 8% and a feldspar product with a Na2O+K2O grade exceeding 9%. This method effectively avoids the equipment corrosion and environmental pollution issues associated with traditional hydrofluoric acid activation and strong-acid flotation methods,providing a feasible technical pathway for the green and efficient utilization of lepidolite flotation tailings.

     

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