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高氧含量钢对尖晶石-碳质塞棒棒头侵蚀机理及优化

Erosion mechanism and optimization of spinel-carbon shopper rod in high-oxygen steel casting

  • 摘要: 在连铸过程中,塞棒作为控制中间包钢水流入结晶器的关键部件,其性能直接影响中包和结晶器钢水液位的稳定性以及中包钢水流量的控制。尖晶石-碳质耐火材料因其优异的化学稳定性和抗钢水侵蚀性,被广泛应用于塞棒棒头中。然而,某钢厂浇铸部分钢种钢水氧含量过高,塞棒棒头出现了严重的侵蚀现象,甚至影响了正常的流量控制。为了改善这一情况,通过对使用后塞棒棒头的分析,发现钢中的氧含量、钙含量以及塞棒头的致密程度是影响侵蚀的关键因素。基于这些发现,对塞棒棒头中镁铝尖晶石、鳞片石墨和SiC含量进行了优化研究,以提高其机械性能、热震抗性、抗氧化性和抗侵蚀能力。其中样品A3相较于对照样品A0,保证抗热震性前提下,高温强度提高了2.9 MPa(约30%),抗氧化性提高了约35%。

     

    Abstract: In the continuous casting process, the stopper rod plays a pivotal role in regulating the flow of molten steel from the tundish into the mold. Its performance has a direct impact on the stability of the molten steel levels in both the tundish and the mold, as well as the control of the flow rate from the tundish. Spinel-carbon refractory materials are extensively utilized for the stopper rod owing to their superior chemical stability and resistance to molten steel erosion. However, when casting certain steel grades with excessively high oxygen content, severe erosion was observed on the stopper rod, which even compromised normal flow control. To address this situation, an analysis of the used stopper rod was conducted, revealing that the oxygen content and calcium content in the steel, along with the density of the stopper rod, are crucial factors influencing erosion. Based on these findings, an optimization study was carried out to adjust the contents of spinel, flake graphite, and SiC in the stopper rod, aiming to enhance its mechanical properties, thermal shock resistance, oxidation resistance, and erosion resistance. Among the samples, A3 exhibited superior performance compared to the control sample A0. Under the condition of maintaining excellent thermal shock resistance, the high-temperature strength of sample A3 increased by 2.9 MPa(approximately 30%), and its oxidation resistance improved by approximately 35%. During steel plant trials, the optimized screw head A3 demonstrated remarkable application performance. Compared with the original screw head, it significantly enhanced the erosion resistance during the casting of high-oxygen steel grades.

     

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