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废弃镁质涂料在炼钢中再生利用技术研究

Recycling and reuse technology of waste magnesia-based coating in steelmaking

  • 摘要: 将用后中间包镁质涂料回收后经加工处理制成轻烧镁球,研究了用后中间包镁质涂料的再生利用技术。通过对制成的轻烧镁球的性能检测分析以及实验室试验和现场试验表明:用后中间包镁质涂料未烧结部分经回收、加工处理后制成轻烧镁球,其理化性能符合转炉炉料指标要求,形成的炉渣中MgO含量比白云石配镁造渣形成的炉渣要高,炉渣碱度也略高。制成的轻烧镁球可向炉渣中提供更多的MgO,配镁造渣效果较好,完全可以代替轻烧白云石等作为转炉终渣改质剂用于转炉配镁造渣工艺和溅渣护炉工艺,能够充分抑制炉衬中的MgO向炉渣中溶解扩散,起到保护炉衬的作用。另外,用后中间包镁质涂料制成的轻烧镁球成渣速度快,与白云石造渣工艺相比成渣速度约提前1~2 min。用后中间包镁质涂料作为炉料在转炉炼钢中具有较高的再生利用价值。

     

    Abstract: The used magnesia-based coating of the tundish was recycled and processed to make light-burned magnesia balls, and the recycling and utilization technology of the used magnesia-based coating of the tundish was studied. Through the performance testing and analysis of the prepared light-burned magnesia balls, as well as laboratory experiments and field tests, it was shown that the unsintered part of the used magnesia-based coating of the tundish, after being recycled and processed to make light-burned magnesia balls, had physical and chemical properties meet the requirements of the converter charge index. The MgO content in the formed slag is higher than that in the slag formed by using dolomite for magnesia burdening, and the basicity of the slag was also slightly higher. The prepared light-burned magnesia balls could provide more MgO to the slag, and the effect of mixing magnesia to make slag was better. It could completely replace caustic calcined dolomite, etc. as a converter final slag modification agent and be used in the converter magnesia burdening and slag making process and the slag splashing furnace protection process. It could fully inhibit the dissolution and diffusion of MgO in the furnace lining into the slag, playing a role in protecting the furnace lining. In addition, the light-burned magnesia balls made from the used magnesia-based coating of the tundish had a fast slag formation speed. Compared with the dolomite slag making process, the slag formation speed was about 1 to 2 minutes earlier. The used magnesia-based coating of the tundish had a high recycling and utilization value as a charge in converter steelmaking.

     

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