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安全稳定型连铸中间包塞棒材质、结构与表层涂料优化

Optimization of material, structure and surface coating of safe and stable stopper rod in continuous casting tundish

  • 摘要: 为减少连铸中间包塞棒使用过程中的断裂与异常侵蚀现象,提高连铸生产的安全性与稳定性,从内部结构、化学成分、物相组成、常温和高温物理性能方面对2种常用板坯中间包塞棒进行了对比分析。结果表明:HN-1塞棒采用磷酸盐结合的刚玉-莫来石防粘结涂料、结合紧密的防氧化涂料以及MgAl2O4-C棒头材质,为塞棒提供了优异的抗氧化、抗侵蚀性能,而渣线采用的低ZrO2的Al2O3-C材质降低了渣线的抗侵蚀性能,引起使用过程渣线的断裂;HY-1塞棒渣线采用Al2O3-C复合MgO-C结构为塞棒渣线提供良好的抗侵蚀性能,而防氧化涂料的成分设计及塞棒基体的抗氧化性不足导致塞棒棒身内部均匀的氧化。通过HN-1塞棒渣线材质的优化及HY-1塞棒釉料成分和基体抗氧化性的调整后,低碳钢中间包连浇炉数由22炉提高达到27~32炉,使连铸生产的安全性与稳定性得到了保障。

     

    Abstract: In order to mitigate fracture and abnormal erosion of stopper rods in continuous casting tundishes and thereby enhance production safety and stability, a comparative analysis was conducted on two commonly used slab tundish stopper rods. The study examined their internal structure, chemical composition, phase constitution, and physical properties at both room and high temperatures. The results indicate that the HN-1 stopper rod, featuring a phosphate-bonded corundum-mullite anti-adhesion coating, a tightly adherent anti-oxidation coating, and a MgAl2O4-C head material, demonstrates excellent oxidation and erosion resistance. However, its slag line, composed of a low-ZrO2 Al2O3-C material, exhibits reduced erosion resistance, leading to fracture during operation. In contrast, the HY-1 stopper rod employs an Al2O3-C/MgO-C composite structure in its slag line, providing superior erosion resistance. Nevertheless, the composition design of its anti-oxidation coating and the inadequate oxidation resistance of the rod body result in uniform internal oxidation of the stopper rod. Through optimization of the slag line material for the HN-1 rod and adjustments to the glaze composition and matrix oxidation resistance for the HY-1 rod, the sequence length for continuous casting of low-carbon steel was increased from 22 heats to 27-32 heats. These improvements effectively ensured the safety and stability of the continuous casting process.

     

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