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活性氧化铝微粉对Al2O3-C耐火材料性能的影响

Effect of reactive alumina micro-powder on properties of Al2O3-C refractory

  • 摘要: 以高铝矾土熟料为主要原料,鳞片石墨为碳源,金属硅和碳化硅为添加剂,酚醛树脂作为结合剂,加入不同比例活性氧化铝微粉制成Al2O3-C材料。按相关标准测定造粒料的粒度分布、堆积密度、流动性,以及Al2O3-C材料的常温抗折强度、显气孔率、体积密度、加热永久线变化、高温抗折强度、热膨胀性、抗热震性。研究了活性氧化铝微粉对以高铝矾土熟料为主要原料、石墨质量分数为23%、连铸3大件用Al2O3-C耐火材料性能的影响。结果发现:随着活性氧化铝微粉加入量的增加Al2O3-C造粒料的造粒效果和流动性先变好后变差。Al2O3-C耐火材料中引入活性氧化铝微粉可以降低试样的显气孔率,提高试样的体积密度、常温抗折强度、高温抗折强度。经1 100℃和1 600℃热处理,试样皆出现不同程度的收缩,试样的线收缩率随着活性氧化铝微粉加入量的增加而逐渐增大。随着活性氧化铝微粉加入量的增加,以高铝矾土熟料为主要原料的Al2O3-C耐火材料的热膨胀系数逐渐增加,抗热震性逐渐变差。

     

    Abstract: Al2O3-C materials were prepared using high-alumina bauxite clinker as the primary raw material, flake graphite as the carbon source, metallic silicon and silicon carbide as additives, and phenolic resin as the binder, with varying proportions of reactive alumina micropowder incorporated. The particle size distribution, bulk density, and flowability of the granulated feedstock, along with the cold modulus of rupture, apparent porosity, bulk density, permanent linear change after heating, hot modulus of rupture, thermal expansion, and thermal shock resistance of the Al2O3-C materials, were measured in accordance with relevant standards. This study investigated the effect of reactive alumina micropowder addition on the properties of Al2O3-C refractories for the three major continuous casting components, based on a formulation with high-alumina bauxite clinker as the main raw material and the mass fraction of graphite is 23%. The results indicated that with increasing reactive alumina micropowder content, the granulation quality and flowability of the Al2O3-C granules first improved and then deteriorated. Incorporating reactive alumina micropowder into the Al2O3-C refractories reduced the apparent porosity and enhanced the bulk density, cold modulus of rupture, and hot modulus of rupture. Following heat treatment at 1 100 ℃ and 1 600 ℃, all samples exhibited varying degrees of shrinkage, with the linear shrinkage increasing progressively as the reactive alumina micropowder content increased. Moreover, with higher additions of reactive alumina micropowder, the thermal expansion coefficient of the high-alumina bauxite clinker-based Al2O3-C refractories gradually increased, while their thermal shock resistance progressively deteriorated.

     

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