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连铸中间包塞棒用功能MgO-C耐火材料研究进展

Research progress on functional MgO-C refractories for stopper rods in continuous casting tundishes

  • 摘要: 中间包塞棒作为连铸工艺中的关键功能耐火材料,其性能直接影响连铸生产的连续性、钢液洁净度及最终产品质量。传统Al2O3-C质塞棒在浇铸钙处理钢、高锰钢及高氧钢时面临化学侵蚀、碳氧化及高温强度不足等技术瓶颈。本文分析了MgO-C耐火材料作为替代方案的性能优势,重点探讨其抗钢液侵蚀机制,其对钢液洁净度及抗热震性能的影响。研究表明,MgO-C材料因MgO的高熔点及与钢液组分的低反应性,可抑制低熔点相的形成;其表面形成的致密MgO反应层可有效阻隔钢液渗透;石墨组分赋予材料优异的抗热震性和高温结构稳定性。此外,MgO-C材料通过吸附Al2O3、SiO2等夹杂物及抑制增碳行为,有助于提升钢液洁净度。然而,无碳化需求与高性能协同、长尺寸塞棒结构的可靠性及成本控制仍是其工业化应用的挑战。未来需通过多尺度模拟、复合设计与工艺优化,推动MgO-C塞棒材料在高效连铸中的广泛应用。

     

    Abstract: As a critical functional refractory component in continuous casting, the tundish stopper rod directly influences process continuity, molten steel cleanliness, and final product quality. Traditional Al2O3-C stopper rods face technical limitations—including chemical erosion, carbon oxidation, and insufficient high-temperature strength—when casting calcium-treated steels, high-manganese steels, and high-oxygen steels. This paper examines the performance advantages of MgO-C refractories as an alternative, focusing on their erosion-resistance mechanism and its effects on steel cleanliness and thermal shock resistance. Studies indicate that MgO-C materials inhibit the formation of low-melting-point phases due to the high melting point and low reactivity of MgO with steel components; a dense MgO reaction layer formed on the surface effectively blocks molten steel penetration; and the graphite component provides excellent thermal shock resistance and high-temperature structural stability. Furthermore, MgO-C materials help improve steel cleanliness by adsorbing inclusions such as Al2O3 and SiO2 and mitigating carbon pickup. However, challenges remain for industrial application, including balancing carbon-free requirements with high performance, ensuring reliability in long-sized stopper rod structures, and controlling costs. Future efforts should promote wider adoption of MgO-C stopper rods in efficient continuous casting through multi-scale simulation, composite design, and process optimization.

     

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