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静磁场对00 Ni18Co8Mo5TiAl马氏体时效钢夹杂物演变规律的影响

Influence of static magnetic field on evolution behavior of non-metallic inclusion in a 00 Ni18Co8Mo5TiAl maraging steel

  • 摘要: 马氏体时效钢作为典型的超高强度钢,其力学性能易受到夹杂物的影响。本文以00 Ni18Co8Mo5TiAl钢为研究对象,提出在钢液保温过程外部施加恒稳静磁场,以磁阻尼效应调控熔体流动并促进夹杂物聚集与去除。通过工业取样与重熔实验对比,对不同条件下夹杂物的类型、尺寸及数量分布进行了系统研究。研究结果表明:工业样品中夹杂物主要为TiN、TiS以及少量Al2O3和复合夹杂物,其中TiN数量密度约为230个/mm2,平均粒径为0.67μm;TiS数量密度约为220个/mm2,平均粒径为0.9μm。重熔实验结果显示,施加磁场相比于未施加磁场,样品中夹杂物数量密度由139个/mm2降至96个/mm2,而平均粒径由1.01μm增大至1.57μm,其中TiS的数量显著减少。磁场作用下,样品表面Al2O3富集更为明显。机理分析表明,静磁场通过抑制熔体对流,稳定气-液界面,延长金属与气氛的作用时间,从而增强了夹杂物的脱除能力;同时磁阻尼效应抑制了溶质扩散,减少了TiS的形核,并促进了奥斯特瓦尔德熟化过程,导致夹杂物数量减少而粒径增大。理论计算进一步表明,TiS与Ti4C2S2均可在钢液中稳定析出,但当S质量分数低于0.002%时,TiS的析出受到显著抑制。

     

    Abstract: Maraging steel,as a representative ultra-high-strength steel,is highly sensitive to the influence of nonmetallic inclusions on its mechanical properties.In this study,00 Ni18Co8Mo5TiAl steel was selected as the material,and a steady static magnetic field was applied outside the insulated melt to regulate melt flow via the magnetic damping effect and thereby promote the aggregation and removal of inclusions.Systematic investigations on the types,sizes,and number densities of inclusions under different conditions were performed through the industrial sampling and remelting experiments.The obtained results show that the inclusions in industrial samples were mainly TiN and TiS with a small amount of Al2O3 and complex inclusions.Among the inclusions,TiN exhibited a number density of approximately 230 mm-2 with an average size of 0.67μm,while TiS had a number density of about 220 mm-2 and an average size of 0.9μm.Remelting experiments revealed that,compared with samples without magnetic field application,the inclusion number density decreases from 139 mm-2 to 96 mm-2,whereas the average size increases from 1.01μm to 1.57μm,with a significant reduction in TiS inclusions.Furthermore,Al2O3 enrichment on the surface becomes to be more pronounced under the magnetic field application.Mechanism analysis indicates that the static magnetic field suppresses melt convection,stabilizes the gas-liquid interface,and prolongs the interaction time between the melt and the atmosphere,thereby enhancing the removal of Al.Meanwhile,the magnetic damping effect restrains solute diffusion,reduces TiS nucleation,and facilitates the Ostwald ripening process.This leads to a decrease in inclusion number density but an increase in size.Theoretical calculations further indicate that both TiS and Ti4C2S2 can stably precipitate in molten steel;however,when the sulfur content is below 0.002%,the precipitation of TiS is significantly suppressed.

     

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