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钨含量对N36锆合金燃料棒密封焊接区显微组织及腐蚀行为的影响

Effect of Tungsten Content on Microstructure and Corrosion Behavior of Seal Welding Zone of N36 Zirconium Alloy Fuel Rod

  • 摘要: 锆合金具有低的热中子吸收截面、良好的耐蚀性能和力学性能等优点,常用于制作压水堆核燃料棒包壳和端塞。在燃料棒的制造过程中,需采用钨极氩弧焊将锆合金包壳和端塞进行密封焊接,但密封焊接区可能会因钨含量超标而性能降低。为明确密封焊接区钨含量对N36锆合金燃料棒上端塞显微组织和腐蚀行为的影响,采用X射线荧光光谱仪、金相显微镜和扫描电子显微镜,研究了未经焊接、焊接后钨含量合格和超标的上端塞的钨含量、显微组织和微区成分;并在400℃/10.3 MPa过热蒸汽中对燃料棒进行了72和336 h的腐蚀试验。结果表明:未经焊接、焊接后钨含量合格和超标的上端塞钨含量分别为175、183、379 cps(推荐判别阈值为235.22 cps);密封焊接区晶粒尺寸约为150μm,远大于未焊接上端塞的4μm; 3种上端塞均无钨夹杂物,腐蚀后均形成了均匀致密且厚度符合要求的氧化膜,说明钨含量超标对N36锆合金燃料棒上端塞焊接密封区的短期腐蚀行为无明显影响。

     

    Abstract: Zirconium alloy has the advantages of low thermal neutron absorption crosssection,good corrosion resistance and mechanical properties,and is often used to make cladding and end plugs of nuclear fuel rods in pressurized water reactor. In the manufacturing of fuel rod,zirconium alloy claddings and end plugs need to be seal-welded by gas tungsten arc welding(GTAW),however,the performance of the seal welding zone of fuel rod may deteriorate due to excessive tungsten content. To clarify the effect of tungsten content in the seal welding zone on the microstructure and corrosion behavior of the top end plugs of N36 zirconium alloy fuel rods,the tungsten content,microstructure and micro-area composition of the unwelded top end plugs,as well as welded ones with qualified and excessive tungsten content,were investigated by X-ray fluorescence spectrograph,metallographic microscope and scanning electron microscope. The fuel rods were subjected to corrosion test for 72 and 336 h in a superheated steam at 400 ℃ with a pressure of 10. 3 MPa. The results showed that(a) the tungsten contents of the top end plugs of unwelded and welded fuel rods with qualified and excessive tungsten content were 175,183,and 379 cps,respectively(recommended threshold being 235. 22 cps);(b) the grain sizes were 150 μm in the seal welding zone of top end plug of the welded fuel rod and nearly 4 μm in the top end plug of unwelded fuel rod;and(c) the top end plugs of three fuel rods were all free from tungsten inclusion,and uniform dense oxide film with acceptable thickness formed on them after corrosion test,indicating that the excessive tungsten content has no significant adverse effect on short-term corrosion behavior of the seal welding zone of top end plugs of N36 zirconium alloy fuel rod.

     

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