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拉伸形变对高锰奥氏体钢超低温冲击韧性的影响机理

Effect of tensile deformation on cryogenic impact toughness of high manganese austenitic steel

  • 摘要: 冷加工是制备液化天然气(LNG)储罐的关键工艺,但冷变形会显著降低高锰奥氏体钢的-196℃低温冲击韧性,其潜在机理尚不明确。本文采用室温预拉伸形变量分别为0、10%、20%和30%的高锰奥氏体钢试样,通过-196℃夏比冲击试验,结合SEM和EBSD技术,深入探讨了拉伸形变对该钢低温冲击韧性的影响规律及内在机理。结果表明,随着拉伸形变量由0增至30%,高锰奥氏体钢的-196℃冲击吸收功自(143±3)J降至(63±6)J;其中,裂纹扩展能(Ep)的下降量占总冲击吸收功降幅的58.4%,是导致冲击韧性恶化的主控因素。微观分析显示,Ep与冲击前预存的形变孪晶比例及位错密度呈显著的负相关,这是由“动态Hall-Petch”效应主导的。预拉伸引入的大量形变孪晶一方面提高了后续超低温冲击时机械孪晶形成的临界应力,抑制了材料的塑性变形;另一方面加剧了冲击加载过程中的高密度位错塞积,诱发了单一的准解理断裂模式,为裂纹扩展提供了快速通道,最终导致材料的超低温抗裂纹扩展能力大幅减弱。

     

    Abstract: Cold working is a critical manufacturing process for liquefied natural gas(LNG)storage tanks. However,cold deformation significantly deteriorates the cryogenic impact toughness of high-manganese austenitic steel at -196 ℃,and its underlying mechanism remains unclear. In this study,high-manganese austenitic steel specimens with pre-deformation levels of 0,10%,20%,and 30% were prepared via room-temperature tensile testing. Through Charpy impact tests at -196 ℃,combined with SEM and EBSD techniques,the effects and intrinsic mechanisms of tensile deformation on the cryogenic impact toughness of the steel were comprehensively investigated. The results indicate that as the tensile deformation increases from 0% to 30%,the impact absorbed energy of the high-manganese austenitic steel at -196 ℃ decreases from(143±3)J to(63±6)J. Notably,the reduction in crack propagation energy(Ep)accounts for 58.4% of the total decrease in impact absorbed energy,serving as the dominant factor responsible for the deterioration of impact toughness. Microstructural analysis reveals that Ep exhibits a significant negative correlation with the proportion of pre-existing deformation twins and the dislocation density prior to impact,which is governed by the “dynamic Hall-Petch” effect. On the one hand,the extensive deformation twins introduced by pre-stretching elevate the critical stress required for mechanical twinning during subsequent cryogenic impact,thereby suppressing the plastic deformation of the material. On the other hand,they exacerbate high-density dislocation pile-ups during impact loading and induce a single quasi-cleavage fracture mode. This fracture mode provides a rapid pathway for crack propagation,ultimately leading to a substantial deterioration in the cryogenic crack propagation resistance of the material.

     

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