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铁酸钇涂层的制备及热反射性能研究

Preparation and thermal reflectance properties of yttrium ferrite coatings

  • 摘要: 以传统固相反应法合成的铁酸钇(YFeO3)粉体为功能颜料、水性丙烯酸乳液为基料,引入不同分散剂制备YFeO3水基料浆,并通过优化料浆组成制备太阳热反射功能涂层。研究了分散剂种类及固含量对YFeO3料浆分散稳定性、流变性和触变性的影响,以及涂层的近红外反射性能。结果表明:在1 300℃下可制得单相正交结构YFeO3粉体,其近红外反射性能较好,最大反射率为97.72%;YFeO3水基料浆呈明显的剪切变稀特征,随着固含量增加,料浆黏度和剪切应力增大,触变性能改善;以70%固含量料浆制备的YFeO3涂层近红外太阳反射率达到46.64%。研究结果表明,YFeO3可作为近红外反射型颜料应用于太阳热反射隔热涂层。

     

    Abstract: YFeO3 powder synthesized by the conventional solid-state reaction method was used as the functional pigment,and a waterborne acrylic emulsion was used as the binder to prepare YFeO3 aqueous slurries with different dispersants. Solar heat-reflective coatings were fabricated by optimizing the slurry composition. The effects of dispersant type and solid content on the dispersion stability,rheological behavior,and thixotropic properties of the YFeO3 slurries,as well as the near-infrared reflective properties of the coatings,were investigated. The results show that single-phase orthorhombic YFeO3 powder can be obtained at 1 300 ℃ by the conventional solid-state reaction method,and the as-prepared powder exhibits good near-infrared reflectance,with a maximum reflectance of 97.72%. The YFeO3 aqueous slurry shows an obvious shear-thinning behavior.With increasing solid content,the viscosity and shear stress of the slurry increase,and the thixotropic property is improved.The near-infrared solar reflectance of the YFeO3 coating prepared from the slurry with a solid content of 70% reaches 46.64%.These results indicate that YFeO3 can be used as a near-infrared reflective pigment for solar heat-reflective thermal-insulation coatings.

     

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