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钛及铌-钛微合金化托盘式集装箱用钢的连续冷却相变行为

Continuous cooling transformation behavior of titanium and niobium-titanium microalloyed steel for pallet container

  • 摘要: 开展Ti及Nb-Ti微合金化托盘式集装箱用钢连续冷却相变行为研究,对推动该类钢材工业化应用、提升托盘集装箱装备质量具有重要意义。采用膨胀法并结合金相-显微硬度法,用热力模拟试验机测定了Ti与Nb-Ti微合金化托盘式集装箱用钢在不同冷却速率下的组织相变行为,绘制了两种试验钢的动态连续冷却转变(CCT)曲线,分析了其连续相变规律。结果表明,随着冷速升高,两种试验钢组织均向贝氏体转变,硬度呈上升趋势;Nb-Ti试验钢因析出Nb(C,N)和Ti(C,N)等粒子,钉扎晶界细化晶粒,推迟了贝氏体转变,并在较高冷速下会出现马氏体组织。结合组织与析出物分析可知,在冷速为0.2~1 ℃/s时晶粒细化主导硬度;冷速为2~10 ℃/s时两者硬度差距较小;冷速为20~50 ℃/s时,Nb-Ti试验钢凭借晶粒细化、马氏体相变及沉淀强化,硬度达330HV 5,显著高于Ti试验钢的290HV 5。此外,Nb-Ti试验钢CCT曲线新增马氏体转变区,相变温度与临界冷速更优,证明Nb可有效提升钢的组织致密性与硬度。

     

    Abstract: The research on the continuous cooling transformation behavior of Ti and Nb-Ti microalloyed steel for pallet container is of great significance for promoting the industrial application of this type of steel and improving the quality of pallet container equipment. The microstructure phase transformation behavior of Ti and Nb-Ti microalloyed steel for pallet container at different cooling rates was determined by dilatometric method combined with metallographic-microhardness method using thermal simulation testing machine. The dynamic continuous cooling transformation (CCT) curves of the two test steels were drawn, and the continuous phase transformation rules were analyzed. The results showed that the microstructure of both test steels transformed to bainite and the hardness increased with the increase of cooling rate. Due to the precipitation of particles such as Nb(C,N) and Ti(C,N), Nb-Ti test steel pinched the grain boundaries and refined the grains, delaying the bainite transformation and resulting in the appearance of martensite at higher cooling rates. Combined with the analysis of microstructure and precipitates, it indicated that when the cooling rate was 0.2-1 ℃/s, grain refinement dominated the hardness; when the cooling rate was 2-10 ℃/s, the hardness difference between the two test steels was small; when the cooling rate was 20-50 ℃/s, the hardness of Nb-Ti test steel reached 330HV 5 due to grain refinement, martensite transformation and precipitation strengthening, which was significantly higher than that of Ti test steel (290HV 5). In addition, the CCT curve of Nb-Ti test steel had a new martensite transformation zone, and the phase transformation temperature and critical cooling rate were better, which proved that Nb could effectively improve the microstructure density and hardness of steel.

     

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