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铀基核燃料芯块中元素含量分析研究进展

Research progress on elemental content analysis of uranium-based nuclear fuel pellet

  • 摘要: 铀基核燃料芯块中各元素含量的准确、快速分析对于核燃料的质量控制至关重要。本文从样品前处理、基体分离以及成分测定3个方面综述了近年来铀基核燃料芯块中主量金属、微痕量金属及非金属杂质元素含量的分析方法。样品前处理方法主要包括酸溶解法、微波消解法和直接压片法;基体分离方法主要包括萃淋法、萃取分离法、液-固相分离法及高温水解法(PH);成分测定方法主要包括滴定法、X射线荧光光谱法(XRF)、电感耦合等离子体发射光谱法(ICP-OES/AES)、电感耦合等离子体质谱法(ICP-MS)、脉冲熔融热导法、离子色谱法、氧化灼烧法、分光光度法以及离子选择电极法等。实验中可根据不同类型核燃料芯块的分析需求,选择适合的单一或联用技术。此外,文章对铀基核燃料芯块的元素含量分析的未来发展进行了展望。

     

    Abstract: Accurate and rapid analysis of element content in uranium-based nuclear fuel pellet is crucial for the quality control of nuclear fuel.In this paper,the analysis methods for major metals,micro-trace metals and non-metallic impurity elements in uranium-based nuclear fuel pellet in recent years are reviewed from 3 aspects,including sample pretreatment,matrix separation and composition determination.The sample pretreatment methods mainly include acid dissolution,microwave digestion and direct pressed pellet.The matrix separation methods mainly include levextraction,extraction separation,liquid-solid phase separation method and high-temperature hydrolysis(PH).The composition determination methods mainly include titration,X-ray fluorescence spectrometry(XRF),inductively coupled plasma optical emission spectrometry(ICP-OES/AES),inductively coupled plasma mass spectrometry(ICP-MS),pulse melting thermal conductivity method,ion chromatography,oxidative combustion method,spectrophotometry and ion selective electrode method,etc.In tests,appropriate independent or combined analytical technologies can be selected according to the analysis requirements of different types of nuclear fuel pellets.Furthermore,the future development of elemental content analysis for uranium-based nuclear fuel pellets is prospected.

     

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