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焦炉荒煤气焦油催化重整实验研究

Experimental study on catalytic reforming of tar in coke oven raw gas

  • 摘要: 焦炉荒煤气中焦油的催化重整脱除转化对于提高焦炉荒煤气的能量利用率和物质利用率具有重要意义。文章以焦炉荒煤气焦油为研究对象,研究了催化重整温度、氧气添加量、水蒸气添加量以及催化剂对荒煤气焦油催化重整效果的影响,并分析了催化重整机理。结果表明,适当提高催化重整温度,有利于焦油催化裂解生成H2、CH4等小分子气体;加入适量氧气和水蒸气,可与焦油蒸汽以及焦油裂解产生的残炭和小分子气体发生部分氧化反应,对于调整荒煤气的成分,增加荒煤气的热值有重要作用;助剂CeO2的添加,可以提高催化剂的活性,促进焦油的催化裂解重整。在催化重整温度为850℃,氧气添加量为0.06,水蒸气添加量为3.6的条件下,添加5%CeO2助剂的镍基催化剂,荒煤气焦油的裂解率可达48.42%。此时,气体产物中H2、CH4、CO和CnHm的体积分数分别为37.39%、13.05%、11.38%和2.02%。

     

    Abstract: The removal and conversion of tar in coke oven raw gas through catalytic reforming is of great significance for improving the energy and material utilization efficiency of COG. This paper takes the tar in coke oven gas as the research object and investigates the effects of catalytic reforming temperature, oxygen addition, steam-to-carbon ratio, and catalysts on the catalytic reforming of tar in coke oven raw gas. The mechanism of catalytic reforming is also analyzed. The results show that moderately increasing the catalytic reforming temperature is conducive to the catalytic cracking of tar to generate small-molecule gases such as H2 and CH4. The addition of appropriate amounts of oxygen and steam can initiate partial oxidation reactions with tar vapor, residual carbon from tar cracking, and small-molecule gases, which are important for adjusting the composition of coke oven raw gas and increasing its calorific value. The addition of CeO2 as a promoter can enhance the activity of the catalyst and promote the catalytic cracking and reforming of tar. Under the conditions of a catalytic reforming temperature of 850 ℃, an oxygen-to-fuel ratio of 0.06, and a steam-to-carbon ratio of 3.6, using a nickel-based catalyst with 5% CeO2 as a promoter, the cracking rate of tar in COG can reach 48.42%. At this point, the volume fractions of H2, CH4, CO, and CnHm in the gas product are 37.39%, 13.05%, 11.38%, and 2.02%.

     

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