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轧钢加热炉NOx生成机理研究及控制措施

Study on the formation mechanisms and control measures of NOx in reheating furnaces of rolling mills

  • 摘要: 随着钢铁行业对工业炉窑烟气排放标准的不断提高,多项针对轧钢加热炉烟气NOx超低排放浓度的标准陆续出台,由2020年前的300 mg/m3逐步降至50 mg/m3(基准氧含量8%)。控制NOx的过程中会造成加热炉运行效率降低,导致热轧产能受限。本文研究了轧钢加热炉NOx的生成机理及控制措施,采用仿真模拟方式研究了分级燃烧对NOx形成的影响,并通过试验分析了氧浓度对NOx实际产生值和折算值的影响,同时根据加热炉的运行特点,分析了SNCR高温脱硝在加热炉应用的可行性。结果表明,通过强化分级燃烧、控制燃烧气氛、炉温限幅优化等技术,能够将NOx排放浓度由200 mg/m3降至100 mg/m3以下;应用SNCR高温脱硝技术,可将NOx排放浓度由100 mg/m3降至50 mg/m3以下。

     

    Abstract: With increasingly rigorous emission standards for industrial furnaces in the steel industry, multiple standards targeting ultra-low NOx emissions from reheating furnaces for rolling mills have been introduced successively. The permissible NOx concentration limit has been gradually reduced from 300 mg/m3(before 2020) to 50 mg/m3(at 8% O2 reference). However, the process of controlling NOx often leads to reduced operational efficiency of the furnace, thereby limiting the production capacity of hot rolling.This paper focuses on the formation mechanisms and control measures of NOx in reheating furnaces for rolling mills. The influence of staged combustion on NOx formation was studied through simulation, and experiments were conducted to analyze the impact of oxygen concentration on both measured and converted NOx values. Furthermore, the feasibility of applying SNCR high-temperature denitration technology in reheating furnaces was examined based on their operational characteristics.The results show that by enhancing staged combustion, optimizing the combustion atmosphere, and implementing furnace temperature limitation measures, NOx emissions can be reduced from about 200 mg/m3 to below 100 mg/m3. Moreover, the application of SNCR high-temperature denitration technology can further lower NOx emissions from around 100 mg/m3 to below 50 mg/m3.

     

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