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热镀铝硅带钢表面白点缺陷原因分析及改进措施

Cause analysis and improvement measures for surface white spot defects of hot-dip Al-Si coated strip

  • 摘要: 针对某企业生产的热镀铝硅IF钢带钢在沿海地区客户的加工使用过程中表面出现白点缺陷的问题,采用扫描电镜(SEM)及能谱仪(EDS)对白点缺陷、正常部位表面和截面微观形貌及成分进行了分析,发现白点缺陷部位O、C元素含量较高,以及含有正常部位不存在的Cl元素。分析认为,这主要是由于带钢镀层表面钝化膜过厚引起钝化膜产生龟裂裂纹,使沿海地区含盐湿热气候中的Cl-通过裂纹扩散,使镀层产生电化学腐蚀而导致白点缺陷。为此,提出了相应的改进措施,即通过减小带钢表面粗糙度、稀释钝化液浓度、降低钝化速度等方式来减少残留钝化液,从而抑制钝化膜裂纹产生,最终消除了镀层表面白点缺陷。

     

    Abstract: In response to the issue of white spot defects appearing on the surface of hot-dip Al-Si IF steel strips during processing and use by customers in coastal areas, scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) were employed to analyze the surface and cross-sectional micromorphology and composition of the white spot defects and normal areas. The results indicated that the defective areas exhibited higher concentrations of O and C elements, along with the presence of Cl elements, which were absent in normal areas. The analysis suggests that the primary cause was excessive thickness of the passivation film on the strip coating surface, leading to the formation of cracks. In the salty and humid coastal climate, Cl- diffused through these cracks, inducing electrochemical corrosion of the coating and resulting in white spot defects. Accordingly, corresponding improvement measures were proposed, including reducing the surface roughness of the strip, diluting the concentration of the passivation solution, and decreasing the passivation speed. These measures aimed to minimize residual passivation solution, hereby reducing the thickness of the passivation film to reduce cracks in the passivation film, and ultimately eliminate white spot defects on the coating surface.

     

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