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表面特性与微观组织对4J36因瓦合金FMM成孔质量的影响机制

Influence mechanism of surface characteristics and microstructure on the pore quality of Invar 36 alloy FMM

  • 摘要: 4J36因瓦合金极薄带作为精细金属掩模板(FMM)的关键材料,其微孔结构质量直接决定有源矩阵驱动型(OLED)显示屏的像素精度与显示性能。本文系统研究了不同处理工艺对4J36因瓦合金极薄带基板、实板与孔板的表面形貌、微观组织及力学性能的影响规律。研究结果表明,退火处理会改变4J36因瓦合金极薄带表面的轧制纹理与表面粗糙度,这些特征在后续腐蚀减薄过程中会被继承并凸显,对最终成孔起决定性作用。与高温退火相比,低温去应力退火能有效降低基板粗糙度,获得最佳表面质量,因此低温去应力退火是实现均匀成孔的理想工艺。微观上,提高回复组织占比,增强(111)和(220)晶面择优取向,以及提升A织构组分含量均有利于促进孔结构的均匀成形。退火处理在维持4J36因瓦合金抗拉强度基本不变的同时,显著降低了屈服强度并提高了伸长率,尤其低温退火在提升材料塑性方面表现更优。本文从表面特性与微观组织角度,揭示了FMM成孔质量的影响机制,为从工艺源头调控材料性能、抑制蚀刻异常、提升FMM产品合格率提供了理论依据与工艺优化路径。

     

    Abstract: Invar 36 alloy ultra-thin strips, as a key material for fine metal masks (FMM), directly determine the pixel precision and display performance of orgarlic light-emitting diode,(OLED) screens through the quality of the micro-hole structures. This paper systematically studies the influence of different processing techniques on the surface morphology, microstructure and mechanical properties of the base plate, solid plate and hole plate of invar 36 alloy ultra-thin strips. The research results show that annealing treatment will change the rolling texture and surface roughness of the invar 36 alloy ultra-thin strip surface, and these features will be inherited and highlighted in the subsequent corrosion thinning process, playing a decisive role in the final hole formation. Compared with high-temperature annealing, low-temperature stress relief annealing can effectively reduce the roughness of the base plate and achieve the best surface quality. Low-temperature stress is an ideal process for achieving uniform hole formation. Microscopically, increasing the proportion of recrystallized structure, enhancing the preferred orientation of (111) and (220) crystal planes, and increasing the content of A texture components are conducive to promoting the uniform formation of hole structures. Annealing treatment maintains the tensile strength basically unchanged while significantly reducing the yield strength and increasing the strain rate, especially low-temperature annealing performs better in improving the plasticity of the material. This paper reveals the influence mechanism of FMM hole formation quality from the perspectives of surface characteristics and microstructure, providing a theoretical basis and process optimization path for controlling material properties from the process source, suppressing etching anomalies, and improving the qualification rate of FMM products.

     

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