高碳马氏体不锈钢热轧缺陷机理及控制研究
Study on mechanism and control of hot rolling defects for high carbon martensitic stainless steel
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摘要: 针对高碳马氏体不锈钢70Cr13Mo在热轧过程中易出现边裂、孔洞等缺陷的问题,对4个批次70Cr13Mo钢液的化学成分及热轧生产过程进行排查,采用扫描电镜、EDS能谱分析等手段对连铸板坯低倍组织,缺陷试样微观组织、碳化物分布等进行分析。结果表明,粗轧机进出口封水设备老化、冷却水泄漏,造成板带边部冷却速率增大、强度陡增;同时,二次碳化物沿晶界提前大量析出,显著降低基体塑性,是热轧板带产生边裂缺陷的主要原因;此外,组织中产生大量(Ti,V)N及其复合夹杂物,易成为裂纹源,这也是缺陷产生的另一主要因素。通过严控粗轧封水设备工况、优化原料配比并严控含钛废钢入炉冶炼等整改措施,成功将热轧缺陷发生率降至0。该研究有效提升了70Cr13Mo钢成品成材率,也为高碳马氏体不锈钢热轧缺陷防控提供了理论依据和实践指导。Abstract: Aiming at the defects such as edge cracking and voids readily occurring during hot rolling of high-carbon martensitic stainless steel 70Cr13Mo, the chemical compositions of molten steel from four batches of 70Cr13Mo and the hot-rolling production process were investigated. Scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and other testing methods were adopted to analyze the macrostructure of continuous-casting slabs, the microstructure of defect specimens, and carbide distribution. The results show that the aging of water-sealing equipment at the entry and exit of the roughing mill and cooling-water leakage lead to an increased cooling rate and sharp rise in strength at the strip edge. Meanwhile, massive premature precipitation of secondary carbides along grain boundaries significantly reduces the matrix plasticity, which serves as the primary cause for edge cracking of hot-rolled strips. In addition, a large number of (Ti,V)N and its composite inclusions formed in the microstructure tend to act as crack initiation sites, constituting another major factor for defect generation. By adopting rectification measures including strict control over the working condition of roughing-mill water-sealing equipment, optimization of raw-material proportioning, and stringent restriction of titanium-containing scrap steel charged into the furnace for smelting, the occurrence rate of hot-rolling defects has been successfully reduced to zero. This study effectively improves the finished-product yield of 70Cr13Mo steel, and provides theoretical basis and practical guidance for the prevention and control of hot-rolling defects of high-carbon martensitic stainless steel.
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