气体元素对45钢连铸坯表面针孔缺陷形成的影响
Influence of gaseous elements on formation of surface pinholes in continuous casting slab of 45 steel
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摘要: 本文以45钢连铸坯为研究对象, 旨在探讨钢水中气体元素对其表面针孔缺陷形成的影响机制。通过分析连铸坯表面针孔特征、中间包钢水气体含量与针孔数量和深度的关系, 并结合气体分压理论计算, 系统研究了气体元素对针孔缺陷形成的影响。结果表明, 针孔在铸坯表面分布不均, 深度方向呈通道型、皮下空腔型、皮下链状及独立分布型等多种形貌。针孔数量及最大深度与氧含量呈正相关, 全氧质量分数不低于0.003%时, 针孔数量超过100个, 针孔深度范围为1.5~4.5 mm; 氢质量分数为0.000 3%时, 针孔数达280个, 且随氢含量增加呈上升趋势, 但与最大深度无关; 氮含量则与针孔参数无显著关联。理论计算表明, 在忽略溶解度变化与偏析、设定气泡逸出温度为液相线温度的条件下, 活度氧体积分数为0.004%时, 分压达101 325.00 Pa, 氢体积分数为0.001%时氢分压达17 225.25 Pa, 氮体积分数为0.009%时氮分压达4 053 Pa, 气体元素对应含量对气泡形成的影响程度为氧>氢>氮。考虑偏析后, 随着偏析的进行达到101 325.00 Pa CO分压所需活度氧含量降低。研究表明, 除原始气体含量外, 凝固过程中气体元素及碳元素偏析与溶解度变化也是气泡形成的关键影响因素。Abstract: This study focuses on continuous casting slab of 45 steel, aiming to explore the influence mechanism of gaseous elements in molten steel on the formation of surface pinhole defects. The influence of gaseous elements on pinhole defect formation was systematically studied by analyzing the characteristics of surface pinholes in continuous casting billets, the relationship between gas content in tundish molten steel and pinhole quantity and depth, and combining with calculations based on gas partial pressure theory. The results indicate that pinholes are unevenly distributed on the cast slab surface and exhibit various morphologies in the depth direction, including channel type, subcutaneous cavity type, subcutaneous chain type, and isolated distribution type. The number of pinholes and their maximum depth are positively correlated with oxygen content. When the mass fraction of total oxygen is no less than 0.003%, the number of pinholes exceeds 100, with depths ranging from 1.5 mm to 4.5 mm. At the mass fraction of hydrogen of 0.000 3%, the number of pinholes reaches 280, showing an upward trend with the increase of hydrogen content but no correlation with the maximum depth. Nitrogen content has no significant correlation with pinhole parameters. Theoretical calculations show that under the conditions of ignoring changes in solubility and setting the bubble escape temperature as the liquidus temperature, the partial pressure reaches 101 325.00 Pa when the volume fraction of active oxygen is 0.004%, 17 225.25 Pa when the volume fraction of hydrogen is 0.001% and 4 053 Pa when the volume fraction of nitrogen is 0.009%. The degree of influence of gaseous elements on bubble formation follows the order of oxygen > hydrogen > nitrogen. After considering segregation, the active oxygen content required to reach a partial pressure of 101 325.00 Pa decreases as segregation proceeds. The research demonstrates that in addition to the original gas content, the segregation and solubility changes of gaseous and carbon elements during the solidification process are also key factors affecting bubble formation.
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