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碱度对球团还原膨胀性能的影响

Effect of basicity on reduction swelling property of pellets

  • 摘要: 在新时代"双碳"目标下, 中国钢铁行业进入了绿色化发展的攻坚期。高比例球团技术采用碱性球团矿取代烧结矿, 是中国高炉低碳冶炼的重要技术方向之一。然而, 碱性球团矿在还原过程中存在异常膨胀问题, 将引起炉况失常等重大生产事故。为此, 本文对自然碱度及碱度为0.2~1.2的球团开展了还原膨胀率试验, 结果表明, 随着碱度的提高, 球团的膨胀率呈升高趋势, 当碱度达到0.8时, 膨胀率达到最大值, 随着碱度的进一步提高, 膨胀率出现明显下降。采用X射线衍射分析及光学显微镜, 对碱度为0.8和1.2的球团在还原过程的矿相变化进行了分析研究, 结果表明, 碱度为0.8的球团主要黏结相为钙铁硅酸盐矿物, 其还原性能差, 还原速度低于赤铁矿, 还原时两者产生的内应力不一致, 导致球团发生异常膨胀; 而碱度为1.2的球团主要黏结相为铁酸钙(SFCA), 其还原速度与赤铁矿基本一致, 还原时两者产生的内应力基本一致, 不会产生异常膨胀。因此, 建议工业生产碱度为1.0以上球团, 以降低球团的膨胀率。

     

    Abstract: Under the "double carbon" targets in the new era, China's iron and steel industry has entered a critical stage of green development. The high-proportion pellet technology, which uses basic pellets to replace sintered ore, is one of the important technical directions for low-carbon blast furnace smelting in China. However, basic pellets have a major problem of abnormal swelling during the reduction process, which can cause major production accidents such as abnormal furnace conditions. To address this issue, this study conducted reduction swelling rate tests on pellets with natural basicity and basicity ranging from 0.2 to 1.2. Results show that the swelling rate of pellets increases with the increase of basicity, reaches the maximum value when the basicity is 0.8, and decreases significantly as the basicity further increases. X-ray diffraction (XRD) analysis and optical microscopy were used to analyze the mineral phase changes of pellets with basicity of 0.8 and 1.2 during the reduction process. Results indicate that the main binding phase of pellets with basicity of 0.8 is calcium iron silicate minerals, which have poor reducibility and a lower reduction rate than hematite. The inconsistent internal stress generated between the two during reduction leads to abnormal swelling of the pellets. In contrast, the main binding phase of pellets with basicity of 1.2 is calcium ferrite (SFCA), whose reduction rate is basically consistent with that of hematite. The internal stress generated between the two during reduction is basically uniform, thus avoiding abnormal swelling. Therefore, it is recommended that pellets with a basicity of more than 1.0 be produced in industrial production to reduce the swelling rate of pellets.

     

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