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高熵合金VIGA法气雾化熔体射流行为数值模拟

Numerical simulation of melt jet behavior in VIGA gas atomization of high-entropy alloys

  • 摘要: 采用Ansys Fluent仿真软件对真空感应熔炼惰性气体雾化法(VIGA)制备Al0.5CrFeNi2.5Six(x=0、0.25、0.50)高熵合金粉末的过程进行数值模拟, 分析相同Si含量下不同雾化压力、相同雾化压力下不同Si含量对粉末粒径分布的影响。分别采用流体体积法(VOF)多相流模型耦合标准k-epsilon湍流模型、VOF多相流模型耦合大涡模型(LES)、离散相模型(DPM)耦合泰勒类比破裂(TAB)模型, 对气雾化过程中的单相流场、一次雾化及二次雾化过程进行模拟, 并通过实际试验方法验证模拟结果。结果表明, 在单相气流场中, 雾化气压增大导致膨胀波面积逐渐扩大, 进而使马赫盘位置不断向下偏移。随着雾化压力由4 MPa逐渐升高至6 MPa, 气流速度持续增大, 最大速度分别为693、704、711 m/s。一次雾化中, 不同雾化压力(4、5、6 MPa)条件下, 随雾化压力增大, 气流对液膜的扰动强度显著增强、液膜的破碎频率明显提高, Al0.5CrFeNi2.5Si0.25高熵合金熔体液柱长度逐渐缩短; 当雾化压力恒定为5 MPa时, 随着Si含量逐步增加, 液膜更易从液柱剥离, 一次雾化破碎的效果更加显著, Al0.5CrFeNi2.5Six(x=0、0.25、0.50)熔体液柱长度也逐渐缩短。二次雾化中, 随雾化气压增大金属粉末中值粒径D50由35.30 μm减小至32.54 μm, 粒子下落时"伞"状范围没有明显变化; 相同雾化压力条件下, 随着Si含量增加, Al0.5CrFeNi2.5Six(x=0、0.25、0.50)合金粉末中值粒径D50由34.96 μm减小至31.77 μm, 粒子下落时"伞"状范围变化不大, 当Si质量分数由x=0.25时增加至x=0.50时, 中值粒径D50的下降幅度更为明显。数值模拟能够有效再现气雾化粉末制备过程, 且与实际结果相比误差较小, 能够为金属粉末制备工艺优化提供理论支撑。

     

    Abstract: Numerical simulations were conducted using Ansys Fluent software to model the preparation process of Al0.5CrFeNi2.5Six (x=0, 0.25, 0.50) high-entropy alloy powders via vacuum induction melting and inert gas atomization (VIGA method).The effects of different atomization pressures at the same silicon content and different silicon contents under the same atomization pressure on the powder particle size distribution were studied. The VOF multiphase flow model coupled with the standard k-epsilon turbulence model, the VOF multiphase flow model coupled with the LES (large eddy simulation) model, and the DPM (discrete phase model) coupled with the TAB (Taylor analogue breakup) model were employed to simulate the single-phase flow field, primary atomization, and secondary atomization processes during gas atomization, respectively. These simulation results were validated by actual experimental methods. The simulation results indicate that in the single-phase gas flow field, an increase atomization pressure causes the expansion wave area to gradually expand, which in turn shifts the Mach disk position continuously downward. As the atomization pressure gradually increases from 4 MPa to 6 MPa, the gas flow velocity continues to increase, with maximum speeds of 693, 704 and 711 m/s respectively. During primary atomization, under different atomization pressure conditions(4, 5, 6 MPa), the disturbance intensity of the gas flow on the liquid film is significantly enhanced and the fragmentation frequency of the liquid film increases remarkably with the increase of atomization pressure, leading to a gradual shortening of the liquid column length of the Al0.5CrFeNi2.5Si0.25 high-entropy alloy melt. When the atomization pressure is maintained at 5 MPa, the liquid film becomes more prone to detachment from the liquid column as the Si content gradually increases, resulting in more significant primary atomization fragmentation, and the liquid column length of the Al0.5CrFeNi2.5Six(x=0, 0.25, 0.50) melt also gradually shortens. During secondary atomization, the median particle size D50 of the metal powder decreases from 35.30 μm to 32.54 μm with the increase of atomization gas pressure while the umbrella-shaped range of particle descent shows no significant change. Under the same atomization pressure condition, the median particle size D50of Al0.5CrFeNi2.5Six(x=0, 0.25, 0.50) alloy powder decreases from 34.96 μm to 31.77 μm as the Si content increases, and the umbrella-shaped range of particle descent changes slightly. When the Si content increases from x=0.25 to x=0.50, the decrease in median particle size D50 is more significant. Numerical simulations can effectively reproduce the gas-atomized powder preparation process with a small deviation from the actual results, thus providing theoretical support for the optimization of metal powder preparation technology.

     

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