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短流程工艺下吉帕级汽车用钢的高温氧化行为

High-temperature oxidation behavior of Si-Mn GPa-grade automotive steel under short-process

  • 摘要: 为解决短流程硅锰系吉帕级汽车用钢在工业生产中出现的红锈缺陷问题, 以取自实际MCCR(多模式全连续铸轧)产线板坯的0.2C-1.5Si-2.3Mn体系汽车用钢为研究对象, 对其在900~1 250 ℃高温条件下的氧化行为进行系统研究, 重点探讨Si、Mn合金元素对氧化铁皮结构、界面形貌及元素迁移的影响机制。研究结果表明, 氧化行为呈现明显的温度依赖性。在1 000 ℃以下, 氧化皮主要由Fe3O4和Fe2O3构成, 氧化层/基体界面处形成SiO2与Fe2SiO4颗粒富集层, 基体内氧化程度较低; 温度升至1 150 ℃时, 界面Fe2SiO4发生部分液化, 内氧化层中出现弥散分布的SiO2-MnO复合氧化物; 当温度达到1 200 ℃以上时, Mn元素向外扩散显著, 形成致密且脆性的(Fe, Mn)3O4尖晶石固溶体, 同时界面橄榄石相转变为(Fe, Mn)2SiO4, 并与SiO2形成网状共晶结构, 该共晶相沿FeO晶界渗透至氧化皮内侧并钉扎于钢基体, 与脆性尖晶石共同作用, 加剧除鳞残留与轧制碎裂风险。通过提高连铸坯拉速、优化隧道炉出炉温度及改进除鳞喷嘴结构, 有效抑制了有害氧化物相的形成, 红锈缺陷发生率显著降低。本研究为短流程高硅高锰钢表面质量控制提供了理论依据。

     

    Abstract: To address the issue of red rust defects in GPa-grade automotive steel alloyed with Si and Mn during industrial production, the oxidation behavior of 0.2C-1.5Si-2.3Mn automotive steel was systematically investigated. Samples were obtained from actual slabs produced on a MCCR line and analyzed under high-temperature conditions ranging from 900 ℃ to 1 250 ℃. This study primarily aimed to explore the mechanisms by which Si and Mn influence the structure, interfacial morphology, and elemental migration of the oxide scale. The results reveal that the oxidation behavior is significantly dependent on temperature. Below 1 000 ℃, the oxide scale predominantly consists of Fe3O4 and Fe2O3, while a layer enriched with SiO2 and Fe2SiO4 forms at the interface between the oxide layer and the substrate, exhibiting lower oxidation levels within the matrix. As the temperature increases to 1 150 ℃, partial liquefaction of the interfacial Fe2SiO4 occurs, leading to the emergence of dispersed SiO2-MnO composite oxides within the inner oxide layer. At temperatures exceeding 1 200 ℃, the manganese element diffuses significantly outward, resulting in the formation of a dense and brittle (Fe, Mn)3O4 spinel solid solution. Concurrently, the olivine phase at the interface transforms into (Fe, Mn)2SiO4, creating a network eutectic structure with SiO2. This eutectic phase intrudes along the grain boundaries of FeO within the oxide scale, anchoring tightly to the steel matrix. Together with the brittle spinel phase, it exacerbates the risk of descaling residue and rolling fractures. Measures such as increasing the casting speed of continuous casting billets, optimizing the exit temperature of tunnel furnaces, and enhancing the design of descaling nozzles effectively suppressed the formation of harmful oxide phases, significantly reducing the incidence of red rust defects. This study provides a theoretical framework for improving surface quality control in short-process high-silicon, high-manganese steel production.

     

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